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    • 83. 发明专利
    • Method and device for producing semiconductor device
    • 用于生产半导体器件的方法和装置
    • JP2003022985A
    • 2003-01-24
    • JP2001209127
    • 2001-07-10
    • Matsushita Electric Ind Co Ltd松下電器産業株式会社
    • ABE HIROMITSUKISHIDA TAKENOBUHINOMURA TORUHARADA TSUYOSHI
    • C23C16/14C23C16/34H01L21/28H01L21/285H01L21/768
    • PROBLEM TO BE SOLVED: To provide a production method for semiconductor device with which the embedding defect of W does not occur when forming a TiN film in the contact hole of a high aspect ratio by a CVD method using organometallic materials.
      SOLUTION: A Ti film 15 for covering the inside of a contact hole 14 formed on an insulating film 13 on a Si wafer 11 is deposited and a TiN film 16 is deposited on the Ti film by the CVD method using organic titanium materials. After the quality of the TiN film is improved by exposing the surface of the TiN film under plasma, a W film 113 is deposited by a CVD method using WF
      6 and SiH
      4 . The thickness of a titanium-nitride film to be deposited at once is made equal to or less than the value with which the moisture to be taken in when exposed to the atmosphere can be suppressed, and the desired thickness can be obtained by a plurality of process cycles. Otherwise, WF
      6 is supplied before SiH
      4 or flow ratio of WF
      6 /SiH
      4 is made into 1.2 to 1.8 and the initialcore of W is formed tight.
      COPYRIGHT: (C)2003,JPO
    • 要解决的问题:提供一种通过使用有机金属材料的CVD法在高纵横比的接触孔中形成TiN膜时不发生W的埋入缺陷的半导体器件的制造方法。 解决方案:沉积用于覆盖形成在Si晶片11上的绝缘膜13上的接触孔14的内部的Ti膜15,并且通过使用有机钛材料的CVD法将TiN膜16沉积在Ti膜上。 在通过在等离子体下暴露TiN膜的表面来改善TiN膜的质量之后,通过使用WF6和SiH4的CVD法沉积W膜113。 使氮化钛膜的一次成膜的厚度成为能够抑制暴露在大气中时吸收的水分的值以下,能够通过多个 过程周期。 否则,在SiH4之前提供WF6,或者将WF6 / SiH4的流量比设为1.2〜1.8,W的初始核心紧密地形成。