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    • 86. 发明专利
    • FORMATION OF PROCESS PATTERN
    • JPH10163084A
    • 1998-06-19
    • JP31743096
    • 1996-11-28
    • HITACHI LTD
    • YAMANAKA RYOKOTANAKA TOSHIHIKO
    • H01L21/302H01L21/027H01L21/3065
    • PROBLEM TO BE SOLVED: To solve problems both of light absorption and reflection by a method wherein a surface treatment is performed for protecting an active hydroxyl group of a film surface, energy rays are emitted on a desired spot of this film, a compound layer with an etching resistance is selectively formed on the surface of a nonexposure region or of an exposure region of a ground film for processing the film having a compound layer as an etching mask. SOLUTION: The surface of a substrate 2 with the formation of an aluminum film 1 is brought in cotact with a surface treatment agent 3 containing a light- absorbing group and a hydrophobic group, an active hydroxyl group on the surface of the aluminum film 1 is protected and a hydrophobic altered layer 4 is formed on this film surface 1. Next, far-ultraviolet radiation 5 is made through an exposure mask 6 for exposing a surface oxide film of an exposure part. Then, this substrate 2 is brought in contact with a solution of metasilicate 7 so as to form oxide silicon 8 only on the exposed part surface where a basic hydroxyl group is exposed and dry etching is performed having the oxide silicon as mask so as to form a minute wiring pattern 10. Thereby, minute processing can be performed without being subjected to a problem caused by alight absorption inside a resist or a substrate reflection.
    • 90. 发明专利
    • RESIST DEVELOPING METHOD
    • JPH07226358A
    • 1995-08-22
    • JP1610794
    • 1994-02-10
    • HITACHI LTD
    • TANAKA TOSHIHIKO
    • G03F7/32B81C99/00H01L21/027
    • PURPOSE:To effectively prevent a resist pattern from falling down without deteriorating it in shape by a method wherein fluid is replaced with liquid specified in specific gravity, surface tension, and solubility as the resist pattern is soaked in fluid. CONSTITUTION:Resist 2 is applied onto a board 1. Then, the resist 2 is irradiated with exposure light 3. Developing solution is applied to the wafer 1, and a resist pattern 2a is formed in the developing solution 4. Thereafter, the wafer 1 is rinsed enough with flowing ultra-pure water 5. Then, keeping the water 1 soaked in pure water, perfluoroalkyl polyether 6 is poured over the wafer 1 from above. Perfluoroalkyl polyether is larger than water in specific gravity and not mixed with water, and they repel each other, so that perfluoroalkyl polyether 6 stays tunder water 5. Then, water is completely drained out, perfluoroalkyl polyether left on the wafer 1 is evaporated, and thus the resist pattern 2a is formed.