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    • 84. 发明专利
    • Cathode material for lithium secondary battery and lithium secondary battery
    • 锂二次电池和锂二次电池的阴极材料
    • JP2005327552A
    • 2005-11-24
    • JP2004143683
    • 2004-05-13
    • Toyota Motor Corpトヨタ自動車株式会社
    • KAWAMOTO KOJI
    • H01M10/05H01M4/13H01M4/62H01M4/02H01M10/40
    • Y02E60/122
    • PROBLEM TO BE SOLVED: To enhance safety of a battery against abnormal situation like overcharge and over-discharge by enabling to exert a PTC property with high responsiveness against temperature increase in the battery.
      SOLUTION: The cathode material for the lithium secondary battery for forming a cathode activator layer on the surface of a current collector of the cathode of the lithium secondary battery includes a cathode activator, conductive agent, and binder. The conductive agent contains V
      2 O
      3 as a main component and a prescribed quantity of Cr, namely, the cathode material contains Cr-V
      2 O
      3 group conductive agent expressed by compositional formula (a); (V
      1-x Cr
      x )
      2 O
      3 , (wherein, 0.002≤x≤0.007). The Cr-V
      2 O
      3 group conductive agent shows PTC property in which, electric resistance sharply increases at a prescribed temperature in accordance with the increase of temperature. As the Cr-V
      2 O
      3 group conductive agent is contained in the cathode activator, an internal resistance of the battery can be increased by promptly responding to the increase of the internal temperature of the battery.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:通过使电池的温度升高能够发挥高反应性的PTC性能,提高电池的安全性,防止异常情况,如过充电和过放电。 解决方案:用于在锂二次电池的阴极的集电体的表面上形成阴极活化剂层的锂二次电池的阴极材料包括阴极活化剂,导电剂和粘合剂。 导电剂含有作为主要成分的V SB 2 O 3和SB规定量的Cr,即阴极材料含有Cr-V 2 由组成式(a)表示的组<! - SIPO - >导电剂; (其中,0.002≤x≤0.007),(其中,0.002≤x≤0.007),其中(V≤1≤x≤0.3) 根据温度的升高,Cr-V O 3 组导电剂显示PTC特性,其中电阻在规定温度急剧增加。 由于阴极活化剂中含有Cr-V 2 SB 3 O 3 / SB 3组导电剂,所以可以通过及时响应内部的增加来提高电池的内阻 电池的温度。 版权所有(C)2006,JPO&NCIPI
    • 87. 发明专利
    • NEGATIVE ELECTRODE FOR LITHIUM ION SECONDARY BATTERY
    • JP2000067865A
    • 2000-03-03
    • JP23386898
    • 1998-08-20
    • TOYOTA MOTOR CORP
    • KAWAMOTO KOJI
    • H01M4/62H01M4/02H01M4/36H01M4/485H01M4/587H01M10/05H01M10/40
    • PROBLEM TO BE SOLVED: To inhibit generation of SEI on the surface of a negative electrode active material and enhance a cycle characteristic by coating the surface of a negative electrode agent mainly containing a carbon with a coating film of LixSiyOz having a lithium ion-conductivity and specifying the ratio of silicon to lithium. SOLUTION: A coating film of LixSiyOz having a lithium ion-conductivity is applied on the surface of a negative electrode agent mainly containing a carbon for coating. A value of 100y/(x+y) being the ratio of silicon to lithium is preferably in the range of 10-80, more preferably in the range of 30-55 in order to enhance the maintaining rate of capacity after allowed to stand at a high temperature. When the value is in the range, the bond of LixSiyOz becomes one-dimensional, it is prevented that a film formed on the surface of the negative electrode agent becomes porous. Then, such deterioration that the lithium ion-conductivity is lowered, the resistance of the negative electrode becomes high and increased in IR drop is prevented. Regarding the coating amount on the surface of the negative electrode agent, LixSiyOz is desirably in the range of 0.01-10% to the negative electrode active material.
    • 90. 发明专利
    • MANUFACTURE OF LITHIUM ION SECONDARY BATTERY ELECTRODE
    • JPH1186849A
    • 1999-03-30
    • JP24691097
    • 1997-09-11
    • TOYOTA MOTOR CORP
    • KAWAMOTO KOJI
    • H01M4/62H01M4/13H01M4/139H01M10/05H01M4/04H01M4/02H01M10/40
    • PROBLEM TO BE SOLVED: To prevent the electrolyte density in an active material from being decreased to reduce a capacity, when the electrode temperature rises at the time of battery operation by connecting an active material and a current collector with a binder swollen due to a temperature rise, and impregnating it with a heated electrolyte. SOLUTION: An active material and a current collector are connected by a binder, such as PVDF, swollen by a temperature rise to obtain a lithium ion secondary battery electrode with the filling factor of 55-70%. The connected electrode is impregnated with an electrolyte heated to the temperature reached, when a battery is operated, e.g. about 60-120 deg.C. The binder is kept at the stable swollen state after the temperature is returned to the room temperature, the impregnation quantity of the electrolyte is increased, and the filling factor is set at 50-65%. As a result, the electrode which holds much electrolyte causes no lack of the electrolyte filling between active material grains, when the temperature rises and the binder is swollen during a battery operation and prevents reduction in the battery capacity caused by ion conductivity deterioration due to the electrolyte density reduction.