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41. 发明专利

JPS58194821A Preparation of hydrocarbon having terminal double bond or its derivative 失效
标题翻译：具有终端双键或其衍生物的烃的制备
公开(公告)号：JPS58194821A
公开(公告)日：1983-11-12
申请号：JP7652482
申请日：1982-05-10
申请人： Shichiro Nojiri
发明人： NOJIRI SHICHIROU
IPC分类号： C07C67/343 , B01J27/00 , B01J27/08 , B01J27/16 , C07B31/00 , C07B37/04 , C07B61/00 , C07C1/00 , C07C2/88 , C07C11/00 , C07C17/00 , C07C17/26 , C07C17/263 , C07C67/00 , C07C253/00 , C07C255/07
CPC分类号： Y02P20/52
摘要： PURPOSE: To prepare an α-olefin or its derivative from a hydrocarbon or its derivative having smaller carbon number than the objective olefin by one, by taking advantage of the dehydrogenating activity of methylal.
CONSTITUTION: A hydrocarbon such as an aliphatic hydrocarbon, e.g. methane, ethane, propane, etc., or its derivative such as methyl acetate, acetonitrile, methyl chloride, etc., is made to react with methylal to obtain a hydrocarbon having larger carbon number than the raw material by one, and containing a double bond at the terminal or its derivative, e.g. ethylene, propylene, butene-1, methyl acrylate, acrylonitrile, vinyl chloride, etc. The methylal can be prepared easily by reacting 1mol of formaldehyde with 2mol of methanol in the presence of the acid catalyst.
EFFECT: The raw material can be obtained independent of petroleum.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：通过利用甲缩醛的脱氢活性，从碳原子数目少于目标烯烃的烃或其衍生物制备α-烯烃或其衍生物。构成：烃类如脂族烃，例如甲烷，乙烷，丙烷等，或其衍生物如乙酸甲酯，乙腈，甲基氯等与甲缩醛反应，得到碳原子数大于原料的烃，并含有双在终端或其衍生物上的键，例如乙烯，丙烯，丁烯-1，丙烯酸甲酯，丙烯腈，氯乙烯等。甲缩醛可以通过在酸催化剂存在下使1mol甲醛与2mol甲醇反应来制备。效果：原料可独立于石油获得。

42. 发明专利

JPS58188822A Catalytic conversion of oxygen-containing compound to hydrocarbon and device 失效
标题翻译：含氧化合物对烃类和器件的催化转化
公开(公告)号：JPS58188822A
公开(公告)日：1983-11-04
申请号：JP6105483
申请日：1983-04-08
申请人： Mobil Oil Corp
发明人： AMOSU ANDORUU ABIDAN , ANTONII YUKUUYUIN KAMU
IPC分类号： C10G3/00 , B01J20060101 , B01J29/00 , C01G20060101 , C07B61/00 , C07C20060101 , C07C1/00 , C07C1/20 , C07C11/00 , C07C11/02 , C07C67/00
CPC分类号： Y02P30/20

43. 发明专利

JPS58118523A OIL SYNTHESIZATION 失效
公开(公告)号：JPS58118523A
公开(公告)日：1983-07-14
申请号：JP21592481
申请日：1981-12-28
申请人： PHILLIPS PETROLEUM CO
发明人： RUISU FURETSUDO HETSUKERUSUBAA , SHIDONII SHIFU , UIRIAMU TOOMASU NERUSON , AANESUTO ADORUFU ZUETSUKU
IPC分类号： C10M105/04 , B01J23/00 , B01J23/36 , C07B61/00 , C07C1/00 , C07C2/02 , C07C2/08 , C07C5/03 , C07C6/04 , C07C9/22 , C07C11/00 , C07C11/02 , C07C67/00 , C10N70/00

44. 发明专利

JPS58110524A ISOMERIZATION OF LIGHT OLEFINIC HYDROCARBON 失效
公开(公告)号：JPS58110524A
公开(公告)日：1983-07-01
申请号：JP22221982
申请日：1982-12-20
申请人： UOP INC
发明人： DENISU JIYON WAADO
IPC分类号： C07C5/25 , B01J23/00 , C07B61/00 , C07C1/00 , C07C7/156 , C07C11/00 , C07C11/08 , C07C11/10 , C07C67/00

45. 发明专利

JPS5830037B2 失效
公开(公告)号：JPS5830037B2
公开(公告)日：1983-06-27
申请号：JP15747879
申请日：1979-12-06
申请人： LEPETIT SPA
发明人： KARORINA KORONERI , GURACHIA BERETSUTA , MARIA ROSA BARUDONE , FURANSESUKO PARENCHI
IPC分类号： C12P1/06 , A61K20060101 , A61K35/00 , A61K35/66 , A61K35/74 , A61K36/06 , A61K39/00 , A61P31/04 , C07C11/00 , C07G11/00 , C12P1/00 , C12P1/04 , C12P13/00 , C12R20060101 , C12R1/045

47. 发明专利

JPS57209822A INHIBITORY METHOD OF NITROGEN OXIDES FORMED AS BY- PRODUCT 失效
公开(公告)号：JPS57209822A
公开(公告)日：1982-12-23
申请号：JP9570781
申请日：1981-06-20
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： NAKAJIMA MASATO , YOSHIDA SHINICHI
IPC分类号： C01G3/00 , C07C1/00 , C07C7/152 , C07C7/156 , C07C11/00 , C07C67/00 , C07F1/08
摘要： PURPOSE:To carry out the recovery of copper nitrate with almost no loss in dispersing metallic copper into contact with a polar solvent containing dissolved copper nitrate, and bringing an unsaturated compound into contact with the dispersed copper to give a cuprous complex, by adding a specific additive to the reaction system. CONSTITUTION:Copper nitrate is dissolved in a polar solvent, and metallic copper at a molar ratio between the metallic copper and the copper nitrate of generally about 0.2-1.5 is added to the solution. An addition at a molar ratio between the additive and the copper ions of about >=0.01 is added thereto. At least one selected from urea, amidosulfuric acid, salt thereof, amidophosphoric acid, salt thereof, carbamic acid, salt thereof, ester thereof, alloxan and aniline is used as the additive. An organic compound having at least one carbon-carbon double bond, e.g. an unsaturated hydrocarbon, is brought into contact with the reaction system to give a cuprous complex. Nitric acid ions are stabilized to inhibit the release thereof as nitrogen oxide in recovering the ligand from the cuprous complex.

48. 发明专利

JPS5754126A Novel preparation of olefin compound 失效
标题翻译：空值
公开(公告)号：JPS5754126A
公开(公告)日：1982-03-31
申请号：JP12904980
申请日：1980-09-19
申请人： Hokko Chem Ind Co Ltd
发明人： KUMADA MAKOTO , HAYASHI TAMIO , HAMADA MITSUO
IPC分类号： C07C1/32 , B01J27/00 , B01J27/10 , B01J31/00 , B01J31/12 , C07B31/00 , C07B37/04 , C07B61/00 , C07C1/00 , C07C11/00 , C07C13/00 , C07C15/00 , C07C15/40 , C07C67/00 , C07F7/08
CPC分类号： Y02P20/52
摘要： PURPOSE: To obtain the titled compound having increased number of carbon atoms with a small amount of a catalyst easily in high yield, by coupling a silylenol ether with a Grignard reagent using a specific nickel salt, e.g., nickel bromide, etc. as a catalyst.
CONSTITUTION: The atmosphere in a reactor is replaced by N
2 gas, and a silylenol ether, e.g., 1-trimethylsiloxy-cyclohexane, etc., shown by the formula I (R
1 WR
3 are H, alkyl, aryl, etc., R
1 and R
2 form ring) is coupled with a Grignard reagent, e.g., diethyl ether of magnesium methyl bromide, etc., shown by the formula II (R
4 is alkyl, aryl, trimethysilyl, etc.; X is halogen) in a solvent in the presence of a nickel salt catalyst, e.g., nickel acetylacetonate, nickel bromide, etc. shown by the formula III [Y is (CH
3 CO)
2 CH, (C
6 H
5 CO)
2 CH, (t-C
4 H
9 CO)
2 CH, Br, Cl, or I] at room temperature to give an olefin compound shown by the formula IV.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：通过使用特定的镍盐（例如溴化镍等）作为催化剂，通过使甲硅烷醇醚与格氏试剂偶联来获得具有少量催化剂的标准化合物，其中少量的催化剂容易以高产率获得。构成：反应器中的气氛被N 2气体代替，并且由式I表示的甲硅烷醇醚，例如1-三甲基甲硅烷氧基 - 环己烷等（R1-R3是H，烷基，芳基等，R1和 R2形式的环）与Grignard试剂（例如甲基溴化镁的二乙醚等）偶合，如式II所示（R4是烷基，芳基，三甲基甲硅烷基等; X是卤素）在溶剂中存在下的镍盐催化剂，例如式III所示的乙酰丙酮镍，溴化镍等：室温下[Y是（CH 3 CO）2 CH，（C 6 H 5 CO）2 CH，（t-C 4 H 9 CO）2 CH，Br，Cl或I] 温度以得到式IV所示的烯烃化合物。

49. 发明专利

JPS5713335B2 JPS5713335B2 - 失效
公开(公告)号：JPS5713335B2
公开(公告)日：1982-03-16
申请号：JP7710476
申请日：1976-07-01
IPC分类号： B01J23/86 , C07B61/00 , C07C1/00 , C07C5/32 , C07C5/333 , C07C11/00 , C07C15/44 , C07C15/46 , C07C67/00
CPC分类号： C07C5/321 , B01J23/864 , C07C5/3332 , C07C15/46

50. 发明专利

JPS5718634A ANTIBIOTIC SUBSTANCE, CANDIPLANECIN, AND ITS PREPARATION 失效
公开(公告)号：JPS5718634A
公开(公告)日：1982-01-30
申请号：JP9312680
申请日：1980-07-08
申请人： SANKYO CO
发明人： ARAI MAMORU , HAISHI TATSUO , TORIGATA AKIO , ITOU YASUHIRO
IPC分类号： A01N63/02 , A61K35/74 , C07C11/00 , C07G11/00 , C12P1/06 , C12R1/01
摘要： NEW MATERIAL:Antibiotic substance, candiplanecin. It is an acidic pale yellow oily substance having the following characteristics: elemental analysis: C 59.29%, H 7.3%; [alpha]D =+26.3 deg. (c=0.85, CHCl3); solubility, soluble in benzene, chloroform, ethyl acetate, acetone, and methanol; hardly soluble in wateri color reaction, positive to iodine, potassium permanganate, and sulfuric acid, negative to ninhydrin; exhibiting antifungal activity against fungi and yeasts including Candida albicans, Saccharomyces cerevisiae, and Aspergillus oryzae. USE:Medicine. It can be used for the prevention and remedy of the diseases of man, animal and vegetable caused by fungi or yeasts. PROCESS:Candiplanecin-producing fungi belonging to Ampullariella genus, e.g. Ampullariella sp. No.43871 (FERM-P No.5646), etc. is cultured by the conventional method for the cultivation of actinomycetes, and the produced candiplanecin is separated and collected using an adsorbent, etc.

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