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    • 41. 发明专利
    • Exhaust gas-purifying catalyst and method for regenerating the same
    • 排气净化催化剂及其再生方法
    • JP2007260564A
    • 2007-10-11
    • JP2006089120
    • 2006-03-28
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • HATANAKA YOSHIOTANABE TOSHITAKANAGAI YASUTAKAYAMAMOTO TOSHIODOMAE KAZUHIKOTAKAGI NOBUYUKI
    • B01J23/89B01D53/86B01D53/94B01J23/96B01J38/18F01N3/10F01N3/20
    • Y02T10/47
    • PROBLEM TO BE SOLVED: To provide an exhaust gas-purifying catalyst capable of sufficiently suppressing a coagulation of noble metal particles even if they are exposed to a high-temperature exhaust gas for a long period of time to sufficiently suppress a grain growth of a noble metal for a long period of time, thereby enabling the system to sufficiently suppress the deterioration of a catalytic activity, easily regenerating the catalytic activity by re-dispersing the noble metal that is grain grown when in use, and easily regenerating the catalyst even if the catalyst is mounted on an exhaust system of an internal engine, and to provide a method for regenerating the exhaust gas-purifying catalyst. SOLUTION: The exhaust gas-purifying catalyst having a carrier containing a composite oxide with at least one element selected from a group consisting of zirconia and/or alumina, alkali earth metal element, rare earth element and IIIA group element, a noble metal that is supported in the carrier, and iron that is supported in the carrier, wherein a supported amount of the noble metal should be in a scope of 0.05 to 2 mass% to the mass of the catalyst, and a supported amount of iron should be in a scope of 0.8 to 12 that is mole ratio (amount of iron/amount of noble metal) to the mass of the noble metal in metal conversion. COPYRIGHT: (C)2008,JPO&INPIT
    • 解决的问题:提供一种能够充分抑制贵金属粒子的凝固的排气净化催化剂,即使它们长时间暴露于高温废气以充分抑制晶粒生长 的贵金属,从而使系统能够充分抑制催化活性的劣化,容易再生分解使用时晶粒生长的贵金属,并容易再生催化剂的催化活性 即使将催化剂安装在内燃机的排气系统上,也可以提供再生废气净化用催化剂的方法。 解决方案:具有载体的废气净化催化剂,该载体含有选自氧化锆和/或氧化铝,碱土金属元素,稀土元素和IIIA族元素中的至少一种元素的复合氧化物,贵金属 负载在载体中的金属和负载在载体中的铁,其中贵金属的负载量相对于催化剂的质量应为0.05〜2质量%的范围,并且负载量的铁应该 在金属转化中摩尔比(贵金属的量/贵金属的量)与贵金属的质量的摩尔比为0.8〜12的范围。 版权所有(C)2008,JPO&INPIT
    • 44. 发明专利
    • Catalyst for purifying exhaust gas, its manufacturing method and its regenerating method
    • 用于净化排气的催化剂及其制备方法及其再生方法
    • JP2008023483A
    • 2008-02-07
    • JP2006200843
    • 2006-07-24
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YAMAMOTO TOSHIONAGAI YASUTAKATANABE TOSHITAKAHATANAKA YOSHIODOMAE KAZUHIKOTAKAGI NOBUYUKIMIURA MASAHIDEIKEDA YASUO
    • B01J23/58B01J23/96B01J38/18
    • PROBLEM TO BE SOLVED: To provide a catalyst for purifying exhaust gas, the deterioration of whose activity can be restrained by restraining the grain growth of a noble metal even if the catalyst for purifying exhaust gas is exposed in high-temperature exhaust gas for a long time and which can be regenerated by breaking up the grain-grown noble metal again into satisfactorily minute particles. SOLUTION: The catalyst for purifying exhaust gas comprises: a compound oxide particle A which consists of a metal oxide containing alumina at least and a first basic oxide, that is deposited on the surface of the metal oxide and contains at least one element selected from the group consisting of alkaline-earth metallic elements, rare earth elements and 3A group elements, and in which the amount of the first basic oxide to be deposited on the metal oxide is 0.1-30 mass%; another compound oxide particle B consisting of zirconia and a second basic oxide containing at least one element selected from the group consisting of alkaline-earth metallic elements, rare earth elements and 3A group elements; an additional component which is deposited on the compound oxide particle B and contains at least one element selected from the group consisting of alkaline-earth metallic elements, rare earth elements and 3A group elements; and the noble metal deposited on the compound oxide particle B at least. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供一种用于净化废气的催化剂,即使在废气净化用催化剂暴露于高温废气中的情况下,也可以通过抑制贵金属的晶粒生长来抑制其活性的劣化 长时间并且可以通过将晶粒生长的贵金属再次分解成令人满意的微小颗粒而再生。 解决方案:用于净化废气的催化剂包括:复合氧化物颗粒A,其由至少含有氧化铝的金属氧化物和第一碱性氧化物组成,其沉积在金属氧化物的表面上并且含有至少一种元素 选自碱土金属元素,稀土元素和3A族元素,其中沉积在金属氧化物上的第一碱性氧化物的量为0.1-30质量%; 由氧化锆和含有选自碱土金属元素,稀土元素和3A族元素中的至少一种元素的第二碱性氧化物构成的复合氧化物粒子B; 沉积在复合氧化物颗粒B上并含有选自碱土金属元素,稀土元素和3A族元素中的至少一种元素的附加成分; 以及至少沉积在复合氧化物粒子B上的贵金属。 版权所有(C)2008,JPO&INPIT
    • 48. 发明专利
    • Catalyst for controlling exhaust gas and its regenerating method
    • 用于控制排气的催化剂及其再生方法
    • JP2007260568A
    • 2007-10-11
    • JP2006089190
    • 2006-03-28
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • TANABE TOSHITAKANAGAI YASUTAKAHATANAKA YOSHIODOMAE KAZUHIKOYAMAMOTO TOSHIOTAKAGI NOBUYUKIIKEDA YASUO
    • B01J23/63B01D53/94B01D53/96B01J23/96B01J38/12F01N3/10F01N3/28
    • PROBLEM TO BE SOLVED: To provide a catalyst for controlling exhaust gas, the activity of which can be recovered by redistributing a platinum particle, which is exposed to high-temperature exhaust gas for a long time and the grain of which is grown, into minute platinum particles in a short time even in a comparatively low temperature range and to provide a method for regenerating the catalyst for controlling exhaust gas. SOLUTION: The catalyst for controlling exhaust gas is provided with: a first catalyst layer comprising a first carrier containing a first multiple oxide of zirconia and/or alumina and at least one element, which is selected from the group consisting of alkaline-earth metal elements, rare earth elements and group 3A elements and contains cerium, and platinum deposited on the first carrier; and a second catalyst layer which comprises a second carrier containing a second multiple oxide of zirconia and/or alumina and at least one element selected from the group consisting of alkaline-earth metal elements, rare earth elements other than cerium and group 3A elements, and platinum deposited on the second carrier and which is arranged on the surface layer side of the first catalyst layer. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种用于控制废气的催化剂,其活性可以通过重新分配长时间暴露于高温废气并且其晶粒生长的铂颗粒来回收 即使在相当低的温度范围内也能在短时间内变成微小的铂颗粒,并且提供一种用于再生用于控制废气的催化剂的方法。 解决方案:用于控制废气的催化剂具有:第一催化剂层,其包含含有氧化锆和/或氧化铝的第一多重氧化物和/或氧化铝的第一载体和至少一种元素,所述第一载体选自碱 - 土金属元素,稀土元素和3A族元素,并含有铈,铂沉积在第一载体上; 以及第二催化剂层,其包含含有氧化锆和/或氧化铝的第二多重氧化物的第二载体和选自碱土金属元素,除铈和3A族元素之外的稀土元素中的至少一种元素,以及 铂沉积在第二载体上并且布置在第一催化剂层的表面层侧。 版权所有(C)2008,JPO&INPIT
    • 49. 发明专利
    • Catalyst for purifying exhaust gas and its regenerating method
    • 用于净化排气的催化剂及其再生方法
    • JP2007260567A
    • 2007-10-11
    • JP2006089177
    • 2006-03-28
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YAMAMOTO TOSHIONAGAI YASUTAKATANABE TOSHITAKAHATANAKA YOSHIODOMAE KAZUHIKOTAKAGI NOBUYUKIMIURA MASAHIDEIKEDA YASUO
    • B01J23/56B01D53/94B01D53/96B01J23/89B01J23/96B01J38/12F01N3/10F01N3/20
    • Y02T10/47
    • PROBLEM TO BE SOLVED: To provide a catalyst for purifying exhaust gas, in which a noble metal particle is restrained from being agglomerated even when the catalyst is exposed to high-temperature exhaust gas for a long time, in the grain-grown one of which a noble metal is dispersed again in a short time in a low temperature range to regenerate the grain-grown catalyst and which can be regenerated in such a state that the catalyst is mounted in an exhaust gas system of an internal-combustion engine and to provide a method for regenerating the catalyst. SOLUTION: The catalyst for purifying exhaust gas is provided with: a carrier containing a multiple oxide of zirconia and/or alumina and at least one element selected from the group consisting of alkaline-earth metal elements, rare earth elements and group 3A elements; a noble metal deposited on the carrier; and an additional component which is deposited on the carrier and contains at least one element selected from the group consisting of alkaline-earth metal elements, rare earth elements and group 3A elements. The catalyst for controlling exhaust gas is characterized in that the amount of the noble metal to be deposited is within 0.05-2 mass% of the catalyst and the molar ratio of (the amount of the additional component to be deposited)/(the amount of the noble metal to be deposited) in terms of metals is within 0.5-20. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供即使当催化剂长时间暴露于高温废气时也抑制贵金属颗粒聚集的废气净化催化剂,在谷物生长中 其中一种贵金属在短时间内再次分散在低温范围内以再生晶粒生长的催化剂,并且可以在催化剂安装在内燃机的排气系统中的状态下再生 并提供催化剂再生的方法。 解决方案:用于净化废气的催化剂具有:含有氧化锆和/或氧化铝的多重氧化物的载体和选自碱土金属元素,稀土元素和3A族中的至少一种元素 要素; 沉积在载体上的贵金属; 以及另外的成分,其沉积在载体上并含有选自碱土金属元素,稀土元素和3A族元素中的至少一种元素。 用于控制废气的催化剂的特征在于,待沉积的贵金属的量在催化剂的0.05-2质量%内,(待附加成分的添加量)/(催化剂的添加量 要沉积的贵金属)在0.5-20以内。 版权所有(C)2008,JPO&INPIT