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31. 发明专利

JP2004277590A Base material for microchemical process and method for producing the same 有权
公开(公告)号：JP2004277590A
公开(公告)日：2004-10-07
申请号：JP2003071769
申请日：2003-03-17
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： HARAGUCHI KAZUTOSHI
IPC分类号： G01N35/08 , C08K3/00 , C08L101/00 , C12M1/00 , G01N37/00
摘要： PROBLEM TO BE SOLVED: To provide a base material for a microchemical process, having a fine complicated outer shape, surface ruggedness, inner passages, inner voids or the like, and providing improved functionality and treatability; and to provide a method for producing the base material.
SOLUTION: The base material for the microchemical process comprises a polymer gel containing a water-swellable clay mineral, includes the passages in the interior, and/or has the ruggedness on the surface. The base material is produced by pouring an aqueous solution containing a water-soluble organic monomer and the finely dispersed water-swellable clay mineral in a mold, polymerizing the water-soluble organic monomer to provide the polymer gel, and removing the polymer gel from the mold.
COPYRIGHT: (C)2005,JPO&NCIPI

32. 发明专利

JP2004262976A Polymer gel composite and production method therefor 有权
标题翻译：聚合物凝胶复合材料及其生产方法
公开(公告)号：JP2004262976A
公开(公告)日：2004-09-24
申请号：JP2003038046
申请日：2003-02-17
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： HARAGUCHI KAZUTOSHI , TAKEHISA KAN
IPC分类号： C08J3/075 , B29C55/00 , C08K3/32 , C08K3/34 , C08L101/00
摘要： PROBLEM TO BE SOLVED: To provide a polymer gel composite having a swellability controlled low, a high elastic modulus or strengths, and an excellent biocompatibility, and a production method therefor. SOLUTION: The polymer gel composite comprises hydroxyapatite and a polymer gel consisting of a water-swellable clay mineral and a polymer prepared from a water-soluble organic monomer. The production method for the polymer gel composite is characterized in that the hydroxyapatite is formed in the polymer gel consisting of the water-swellable clay mineral and the polymer prepared from the water-soluble organic monomer, by impregnating the polymer gel with an aqueous alkali-metal phosphate solution and with an aqueous calcium salt solution, alternately each at least once. COPYRIGHT: (C)2004,JPO&NCIPI
摘要翻译：解决的问题：提供具有低膨胀性，高弹性模量或强度以及优异的生物相容性的聚合物凝胶复合材料及其制备方法。解决方案：聚合物凝胶复合材料包含羟基磷灰石和由水溶胀性粘土矿物和由水溶性有机单体制备的聚合物组成的聚合物凝胶。聚合物凝胶复合体的制造方法的特征在于，在由水溶胀性粘土矿物和由水溶性有机单体制备的聚合物组成的聚合物凝胶中形成羟基磷灰石，通过用碱溶性水溶液浸渍聚合物凝胶，金属磷酸盐溶液和钙盐水溶液，各自至少一次。版权所有（C）2004，JPO＆NCIPI

33. 发明专利

JP2004043712A Aromatic resin composition, molded article and gel-like material 审中-公开
公开(公告)号：JP2004043712A
公开(公告)日：2004-02-12
申请号：JP2002205438
申请日：2002-07-15
申请人： Dainippon Ink & Chem Inc , Kawamura Inst Of Chem Res , 大日本インキ化学工業株式会社 , 財団法人川村理化学研究所
发明人： SEKINE NOBUHIRO , MURATA KAZUTAKA , HARAGUCHI KAZUTOSHI
IPC分类号： C08J5/00 , C08G63/672 , C08L67/03 , C08L101/06
摘要： PROBLEM TO BE SOLVED: To provide a resin composition containing an aromatic polymer, a molded article such as a film molded from the resin composition and a gel-like material composed of the resin composition and a solvent.
SOLUTION: The resin composition comprises a polymer in which the main chain is composed of an aromatic polymer and at least a part of an aromatic ring in the main chain has a side chain having a terminal group represented by structural formula (wherein R
1 is an alkylene group in which average carbon number is 2-3; n is an integer of 1-5; R
2 is an alkyl group or an alkylcarbonyl group) in an amount of ≥60 wt.%.
COPYRIGHT: (C)2004,JPO

34. 发明专利

JP2011001481A Method for bonding polymer gel 有权
标题翻译：粘合聚合物凝胶的方法
公开(公告)号：JP2011001481A
公开(公告)日：2011-01-06
申请号：JP2009146330
申请日：2009-06-19
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： HARAGUCHI KAZUTOSHI
IPC分类号： C08J5/12 , C09J5/02 , C09J5/06 , C09J11/04 , C09J157/00 , C09J201/00
摘要： PROBLEM TO BE SOLVED: To provide a simple and effective method for bonding a polymer gel.SOLUTION: The method for obtaining the polymer gel, whose stuck surfaces bond together firmly, comprises cutting an organic polymer/clay composite polymer gel comprised of a polymer obtained from a water soluble organic monomer and a water-swellable clay mineral and having a three dimensional network, then sticking together the cut surfaces or sticking a cut surface with non-cut surface, and, if necessary, performing heating, pressurization, ultrasonic irradiation, coating of a water soluble polymer, etc. Using the method, the organic polymer/clay composite polymer gel can be processed to be molded in an arbitrary shape, and an organic gel, having complicated shapes and excellent in mechanical physical properties, swelling property, and functionality, is prepared easily.
摘要翻译：要解决的问题：提供一种用于粘合聚合物凝胶的简单且有效的方法。解决方案：将粘合表面牢固地结合在一起的聚合物凝胶的获得方法包括切割由获得的聚合物组成的有机聚合物/粘土复合聚合物凝胶从水溶性有机单体和水溶胀性粘土矿物中提取三维网络，然后将切割面粘合在一起，或者用非切割面粘贴切割面，如果需要，进行加热，加压，超声波照射，水溶性聚合物的涂布等。使用该方法，有机聚合物/粘土复合聚合物凝胶可以加工成任意形状的成型体，具有复杂形状，机械物理性能，溶胀性，和功能，容易准备。

35. 发明专利

JP2010254800A Organic/inorganic composite 审中-公开
标题翻译：有机/无机复合材料
公开(公告)号：JP2010254800A
公开(公告)日：2010-11-11
申请号：JP2009106314
申请日：2009-04-24
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： MURATA KAZUTAKA , HARAGUCHI KAZUTOSHI , OBAYASHI AKIRA , TAKEHISA KAN , TAKADA TETSUO
IPC分类号： C08L33/14 , C08F2/44 , C08F20/28 , C08F290/06 , C08K3/34 , C08L55/00
摘要： PROBLEM TO BE SOLVED: To provide an organic/inorganic composite having high water absorptivity, excellent mechanical properties when absorbing water, and high flexibility. SOLUTION: The organic/inorganic composite comprises a polymer of radical polymerizable monomers (A) and a water-swellable clay mineral (B). The polymer is obtained by polymerizing radical polymerizable monomers (A) containing a monomer (A1) expressed by structural formula (1). The mass proportion of the water-swellable clay mineral (B) in the organic/inorganic composite ä(mass of the water-swellable clay mineral (B))÷(mass of the water-swellable clay mineral (B)+mass of the polymer of the radical polymerizable monomers (A))×100%} ranges from 1 to 20 mass%. In formula (1), R 1 represents a hydrogen atom or a methyl group; R 2 represents a methyl group or an ethyl group; and n represents an integer of 2 to 100. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种吸水率高的有机/无机复合材料，吸水时的机械性能优异，柔软性高。解决方案：有机/无机复合材料包含可自由基聚合的单体（A）和水溶胀性粘土矿物（B）的聚合物。聚合物通过聚合含有由结构式（1）表示的单体（A1）的自由基可聚合单体（A）而获得。有机/无机复合材料中水溶胀性粘土矿物（B）的质量比例ä（水溶胀性粘土矿物（B）的质量）÷（水溶胀性粘土矿物质量（B）+质量）自由基聚合性单体（A）的聚合物）×100％}为1〜20质量％。在式（1）中，R“SP”表示氢原子或甲基; R SP 2表示甲基或乙基; 并且n表示2〜100的整数。版权所有（C）2011，JPO＆INPIT

36. 发明专利

JP2010095586A Method for forming organic-inorganic composite hydrogel 有权
标题翻译：形成有机无机复合水凝胶的方法
公开(公告)号：JP2010095586A
公开(公告)日：2010-04-30
申请号：JP2008266227
申请日：2008-10-15
申请人： Dic Corp , Dic株式会社 , Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： HARAGUCHI KAZUTOSHI , KUROKI KATSUHITO
IPC分类号： C08L101/14 , B32B27/30 , C08J3/075 , C08K3/34 , C08L33/26
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an organic-inorganic composite hydrogel, being a simple method capable of forming the organic-inorganic composite hydrogel with a desired thickness, area, and shape, and enabling to retain high strength and high extensibility, distinctive properties of the organic-inorganic composite hydrogel, even after the forming. SOLUTION: The method for forming the organic-inorganic composite hydrogel includes carrying out a drying process or a heating process while maintaining the transformed state obtained by a pressurizing, depressurizing, or stretching process of the organic-inorganic composite hydrogel having three-dimensional network, formed by the compounding of a water-soluble organic polymer and a delaminated clay mineral. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供一种制备有机 - 无机复合水凝胶的方法，其是能够形成具有所需厚度，面积和形状的有机 - 无机复合水凝胶的简单方法，并且能够保持高强度有机 - 无机复合水凝胶的高延展性，独特性能，甚至在成型后。解决方案：形成有机 - 无机复合水凝胶的方法包括进行干燥过程或加热过程，同时保持通过加压，减压或拉伸过程获得的转化状态，所述有机 - 无机复合水凝胶具有三维通过配合水溶性有机聚合物和分层粘土矿物形成的三维网络。版权所有（C）2010，JPO＆INPIT

37. 发明专利

JP2009270048A Method for producing organic-inorganic composite hydrogel having carboxylate structure group or carboxy anion structure group 有权
标题翻译：生产有机无机复合水凝胶的方法，该组合物含有羧酸酯结构基团或羧基结构基团
公开(公告)号：JP2009270048A
公开(公告)日：2009-11-19
申请号：JP2008123257
申请日：2008-05-09
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： OBAYASHI AKIRA , HARAGUCHI KAZUTOSHI
IPC分类号： C08L33/02 , C08F2/44 , C08F8/12 , C08K3/34
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a novel organic-inorganic composite hydrogel having high water swelling properties. SOLUTION: In the method for producing the organic-inorganic composite hydrogel, wherein an organic polymer (A) having a carboxylate structure group or a carboxy anion structure group and a water swelling clay material (B) form a three-dimensional network, the organic-inorganic composite hydrogel prepared by polymerizing monomers including (meth)acrylic amide or (meth)acrylic acid ester having hydrolyzability is hydrolyzed by a caustic alkali under coexistence of the water swelling clay material (B), so that at least a part of an amide group or an ester group in the organic polymer (A) is converted to the carboxylate structure group or the carboxy anion structure group. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供一种具有高溶胀性的新型有机 - 无机复合水凝胶的制造方法。解决方案：在具有羧酸盐结构基团或羧基阴离子结构基团的有机聚合物（A）和水溶性粘土材料（B）的有机 - 无机复合水凝胶的制造方法中，形成三维网状结构通过聚合包含（甲基）丙烯酰胺或具有水解性的（甲基）丙烯酸酯）的单体制备的有机 - 无机复合水凝胶在水溶性粘土材料（B）的共存下被苛性碱水解，使得至少一部分的有机聚合物（A）中的酰胺基或酯基转化为羧酸根结构基团或羧基阴离子结构基团。版权所有（C）2010，JPO＆INPIT

38. 发明专利

JP2009138047A Method for preparing organic-inorganic composite emulsion 审中-公开
标题翻译：制备有机无机复合乳液的方法
公开(公告)号：JP2009138047A
公开(公告)日：2009-06-25
申请号：JP2007313388
申请日：2007-12-04
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： OBAYASHI AKIRA , HARAGUCHI KAZUTOSHI
IPC分类号： C08F2/44 , B32B27/18 , C08K3/34 , C08L33/08 , C08L43/04 , C08L47/00 , C08L63/00
摘要： PROBLEM TO BE SOLVED: To provide a new organic-inorganic composite film having excellent mechanical characteristics and gas barrier property, and to provide a method for preparing an organic-inorganic composite emulsion from which the above film can be manufactured.
SOLUTION: The method for preparing an organic-inorganic composite emulsion comprises emulsion polymerization of hydrophobic polymerizable vinyl monomers in a water dispersion liquid of water-swellable clay mineral by using a surfactant, wherein the surfactant is an anionic surfactant, and the hydrophobic polymerizable vinyl monomer contains butadiene, isoprene or an acrylic acid ester.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异的机械特性和阻气性的新的有机 - 无机复合膜，并提供制备可以制造上述膜的有机 - 无机复合乳液的方法。解决方案：制备有机 - 无机复合乳液的方法包括使用表面活性剂在水溶胀性粘土矿物的水分散液中的疏水性可聚合乙烯基单体的乳液聚合，其中表面活性剂是阴离子表面活性剂，并且疏水性可聚合乙烯基单体含有丁二烯，异戊二烯或丙烯酸酯。版权所有（C）2009，JPO＆INPIT

39. 发明专利

JP2009127035A Method for production of organic and inorganic composite hydrogel 有权
标题翻译：有机和无机复合水凝胶的生产方法
公开(公告)号：JP2009127035A
公开(公告)日：2009-06-11
申请号：JP2007307243
申请日：2007-11-28
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： OBAYASHI AKIRA , HARAGUCHI KAZUTOSHI
IPC分类号： C08F2/44 , C08K9/02 , C08L33/26
摘要： PROBLEM TO BE SOLVED: To provide a method for production of a novel organic and inorganic composite hydrogel not only having high mechanical properties but also having high water swelling property and proton conductivity. SOLUTION: After preparing a homogeneous solution including (meth)acrylamide or its derivative, a water-swelling clay mineral (B) including sodium pyrophosphate and water (C), polymerizable monomers bearing sulfonic acid group or carbonic acid group is added thereto with polymerization initiator at the same time or after the initiator is added to co-polymerize the (meth)acrylamide or its derivatives and the monomers bearing sulfonic acid group, to prepare an organic polymer (A). The production method of the organic and inorganic composite hydrogel in which the organic polymer (A) and the water-swelling clay mineral (B) form a three-dimensional network is provided. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种新的有机和无机复合水凝胶的制造方法，不仅具有高机械性能，而且具有高的水溶胀性质和质子传导性。解决方案：在制备包含（甲基）丙烯酰胺或其衍生物的均匀溶液之后，向其中加入包含焦磷酸钠和水（C）的水溶性粘土矿物（B），带有磺酸基或碳酸基团的可聚合单体与聚合引发剂同时或引发剂加入共聚（甲基）丙烯酰胺或其衍生物和带有磺酸基的单体后，制备有机聚合物（A）。提供其中有机聚合物（A）和水溶性粘土矿物（B）形成三维网络的有机和无机复合水凝胶的生产方法。版权所有（C）2009，JPO＆INPIT

40. 发明专利

JP2009067892A Method for producing organic-inorganic complex emulsion 审中-公开
标题翻译：生产有机无机复合乳液的方法
公开(公告)号：JP2009067892A
公开(公告)日：2009-04-02
申请号：JP2007237860
申请日：2007-09-13
申请人： Kawamura Inst Of Chem Res , 財団法人川村理化学研究所
发明人： OBAYASHI AKIRA , HARAGUCHI KAZUTOSHI
IPC分类号： C08F2/44 , B32B27/20 , C08F2/24 , C08F292/00
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a new organic-inorganic complex emulsion excellent in gas barrier property, rupture strength and heat resistance and to provide a gas barrier property lamination film using the organic-inorganic complex emulsion.
SOLUTION: In the method for producing the organic-inorganic complex emulsion, a nonionic surfactant is added to an aqueous dispersion of a water expansive clay mineral so that the nonionic surfactant is adsorbed to the surface and between the layers of the water expansive clay mineral, and then, a hydrophobic polymerizable vinyl monomer (i) is added to be localized to the surface, the vicinities of the surface, and between the layers of the clay mineral wherein the surfactant exist for performing radical polymerization.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种制备阻气性，断裂强度和耐热性优异的新的有机 - 无机复合体乳液的方法，并提供使用有机 - 无机复合乳液的阻气性层压膜。解决方案：在制备有机 - 无机复合乳液的方法中，将非离子表面活性剂加入到水膨胀性粘土矿物的水性分散体中，使得非离子表面活性剂被吸附在表面上和水层之间膨胀粘土矿物，然后加入疏水性可聚合乙烯基单体（i），定位于表面附近以及表面活性剂存在进行自由基聚合的粘土矿物层之间。版权所有（C）2009，JPO＆INPIT

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