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21. 发明专利

JPH07215985A PRODUCTION OF TRIMETHYLSILYLDIETHYLAMINE 失效
公开(公告)号：JPH07215985A
公开(公告)日：1995-08-15
申请号：JP2734094
申请日：1994-01-31
申请人： SHINETSU CHEMICAL CO
发明人： SHINOHARA NORIO , KUDO MUNEO , MATSUMURA KAZUYUKI
IPC分类号： C07F7/10
摘要： PURPOSE:To obtain high-purity trimethylsilyldiethylamine capable of reutilizing a reactional by-product as a starting raw material without containing an impurity such as chlorine at a low cost by reacting diethylamine with a specific N, O-bis (trimethylsilyl) acrylamide. CONSTITUTION:This method for producing the objective trimethylsilyldiethylamine is to place N,O-bis(trimethylsilyl)acrylamide expressed by the formula in a four neck flask equipped with a stirrer, a reflux condenser, a dropping funnel and a thermometer, drop diethylamine from the dropping funnel thereto for 1 hr, react the compounds at 20-30 deg.C, keep the reactional mixture at 60-70 deg.C temperature after completing the dropping of the diethylamine, age the reactional mixture at the temperature for 2 hr, then perform the vacuum distillation and provide the objective compound as a fraction having 53 deg.C boiling point under 60mmHg pressure. The resultant compound is useful as an electronics material, etc., such as a primer for photoresists. Furthermore, N-trimethylsilylacrylamide which is a by-product can be trimethylsilylated and readily converted into the N,O-bis(trimethylsilyl)acrylamide which is a raw material.

22. 发明专利

JPH06247988A PRODUCTION OF P-T-BUTOXY-ALPHA OR BETA-TRIALKOXYSILYLETHYLBENZENE 失效
公开(公告)号：JPH06247988A
公开(公告)日：1994-09-06
申请号：JP3189593
申请日：1993-02-22
申请人： SHINETSU CHEMICAL CO , HOKKO CHEM IND CO
发明人： SHINOHARA NORIO , KUDO MUNEO , KUMAMOTO NOBUMITSU , UMENO MASAYUKI
IPC分类号： B01J31/22 , C07B61/00 , C07F7/18
摘要： PURPOSE:To obtain the subject compound suitable for a finely processing material of semiconductor, etc., and to improve yield of beta-isomer by reacting a trialkoxysilane with p-t-butosyxtyrene under a specific condition. CONSTITUTION:A trialkoxysilane of the formula HSiR3 (R is alkoxy) (e.g. trimethoxysilane) is reacted with p-t-butoxystyrene of formula I in the presence of polymerization inhibitor (e.g. hydroquinone) by using a rhodium-tri organic phosphorus complex (e.g. tris (triphenylphosphine) rhodium (I) chloride) as a catalyst to give the objective compound of formula II (A and A2 are H or SiR3). This reaction is preferably carried out at 70-150 deg.C for 1-30 hours by making the molecular ratio of the trialkoxysilane to the compound of formula I of 1-1.5 and by using 500ppm-15wt.% of the polymerization inhibitor 1 and 1X10 to 1X10 mol of the catalyst respectively based on 1mol of the compound of formula I.

23. 发明专利

JPH0532604A PRODUCTION OF ACETONITRILE 失效
公开(公告)号：JPH0532604A
公开(公告)日：1993-02-09
申请号：JP21313091
申请日：1991-07-31
申请人： SHINETSU CHEMICAL CO
发明人： SHINOHARA NORIO , KUDO MUNEO
IPC分类号： B01J27/128 , B01J27/138 , C07B61/00 , C07C253/20 , C07C255/03
摘要： PURPOSE:To readily produce acetonitrile in high yield by thermally decomposing N,O-bis(trimethylsilyl)acetamide which is a highly active silylating agent as a raw material in the presence of a metallic halide catalyst and then distilling the resultant product. CONSTITUTION:Inexpensive N,0-bis(trimethylsilyl)acetamide is heated at 20-100 deg.C, preferably 40-60 deg.C in the presence of a metallic halide catalyst (especially iron chloride, zinc chloride, aluminum chloride, palladium chloride, cobalt bromide or nickel bromide), decomposed and then distilled to afford acetonitrile. Furthermore, the catalyst is used in an amount of preferably about 0.01-1mol% based on the amount of the 0bis(trimethylsilyl)acetamide.

24. 发明专利

JPH0466588A PRODUCTION OF THEXYLTRICHLOROSILANE 失效
公开(公告)号：JPH0466588A
公开(公告)日：1992-03-02
申请号：JP17244990
申请日：1990-06-29
申请人： SHINETSU CHEMICAL CO
发明人： SHINOHARA NORIO , KUDO MUNEO , IWABUCHI MOTOAKI
IPC分类号： C07F7/12 , B01J31/02 , C07B61/00 , C07F7/14
摘要： PURPOSE:To obtain the title compound useful as a raw material for silicone resin, a surface treating agent of inorganic substance and an additive for complex catalyst in high yield, by reacting trichlorosilane with dimethylbutene in the presence of a specific azo compound as a catalyst. CONSTITUTION:Trichlorosilane is reacted with 2,3-dimethyl-2-butene in the presence of an azo compound [e.g. 2,2'-azobis(isobutyronitrile)] shown by the formula R-N=N-R (R is alkyl, alkylcyano, alkyl ether cyano or cyclic alkylcyano) as a catalyst preferably at 30-110 deg.C to give the objective compound.

25. 发明专利

JP2002329581A ELECTRO-LUMINESCENCE ELEMENT 失效
公开(公告)号：JP2002329581A
公开(公告)日：2002-11-15
申请号：JP2001133984
申请日：2001-05-01
申请人： SHINETSU CHEMICAL CO
发明人： KUDO MUNEO , YAMATANI MASAAKI
IPC分类号： H05B33/20 , C08L83/08 , C09K11/00 , C09K11/02 , H05B33/10 , H05B33/22
摘要： PROBLEM TO BE SOLVED: To provide an electro-luminescence element characterized by high luminance, small change of luminance by temperature, small degradation in luminance at a long-term lighting, excellent impact-resistant, excellent flexibility, high thermal decomposition temperature and excellent heat resistance, by dispersing granular particles having electroluminescent properties in high dielectric addition type curable binder composition characterized by a high dielectric constant and a low adsorption quantity. SOLUTION: This electro-luminescence element is comprised of a dielectric formed lamellarly as a luminous layer. The dielectric contains granular particles having electroluminescent properties. The dielectric is composed of (a) an organo polysiloxane which contains a cyanoalkyl group and a monovalent hydrocarbon having an aliphatic unsaturated bond, (b) an organohydrogen polysiloxane which contains a cyanoalkyl group and (c) a cured high dielectric addition type curable binder composition which contains a platinum group metal-based catalyst. Therefore, the electro-luminescence element has industrial advantage not only for applying to the backlights of the various liquid crystal displays but also for applying broadly as the surface emitting bodies.

26. 发明专利

JP2002116571A ELECTROPHOTOGRAPHIC PHOTORECEPTOR 失效
公开(公告)号：JP2002116571A
公开(公告)日：2002-04-19
申请号：JP2000305220
申请日：2000-10-04
申请人： SHINETSU CHEMICAL CO
发明人： KUDO MUNEO
IPC分类号： G03G5/147
摘要： PROBLEM TO BE SOLVED: To provide an electrophotographic photoreceptor or more particularly an organic photoreceptor which is further improved in durability by lowering the coefficient of friction on the surface of the uppermost layer of the photoreceptor, is improved in cleaning characteristics and makes it possible to stably obtain high-density and bright images at all times. SOLUTION: The uppermost layer of this electrophotographic photoreceptor contains spherical hydrophobic silica particulates which satisfy the following conditions (i) and (ii) and are 0.01 to 5 μm in the average grain size of the primary particles. (i) The silica particulates disperse uniformly into an organic compound which is liquid at room temperature and has a dielectric constant of 1 to 40 F/m when this organic compound and the silica particulates are mixed at a weight ratio of 5:1 and are shaken. (ii) The ratio of the quantity of the primary particles remaining as primary particles to the quantity of the initially existing primary particles is >=20% when the dispersion prepared by dispersing the silica particulates into methanol is held for two hours at 100 deg.C after the methanol is distilled away under heating in an evaporator.

27. 发明专利

JP2001305804A COATING AGENT FOR CARRIER FOR DEVELOPING ELECTROSTATIC IMAGE AND CARRIER FOR DEVELOPING ELECTROSTATIC IMAGE THEREOF 失效
公开(公告)号：JP2001305804A
公开(公告)日：2001-11-02
申请号：JP2000119105
申请日：2000-04-20
申请人： SHINETSU CHEMICAL CO
发明人： KUDO MUNEO , TANAKA MASAKI
IPC分类号： G03G9/113
摘要： PROBLEM TO BE SOLVED: To provide a method for realizing a improved carrier for electrophotography which resists destruction such as wear, peeling, crack, and rarely suffers from a spent phenomenon, so it excels in long-term durability and electrostatic stability. SOLUTION: The present invention provides a coating agent for the carrier which is characteristically composed of spherical hydrophobic fine silica particles having primary particles having an average particle diameter of from 0.01 to 5. μm and an organic resin. Those fine silica particles fulfill the following conditions (i) and (ii). (i) When an organic compound which is liquid at room temperature and has a dielectric constant of from 1 to 40 F/m and fine silica particles are mixed in a weight ratio of 5:1 and shaken, the fine silica particles disperse uniformly in the organic compound. (ii) The quantity of primary particles remaining as primary particles when methanol is evaporated under heating by means of an evaporator from a dispersion prepared by dispersing the fine silica particles in methanol and thereafter the particles are held at 100 deg.C for 2 hours, represents at least 20% of the quantity of primary particles originally present.

28. 发明专利

JP2001194824A ELECTROSTATIC CHARGE IMAGE DEVELOPING TONER EXTERNAL ADDITIVE 失效
公开(公告)号：JP2001194824A
公开(公告)日：2001-07-19
申请号：JP2000001083
申请日：2000-01-06
申请人： SHINETSU CHEMICAL CO
发明人： KUDO MUNEO , TANAKA MASAKI
IPC分类号： G03G9/08
摘要： PROBLEM TO BE SOLVED: To provide an external additive for toner which causes no reaction and no interaction with an organic photoreceptor and consequently causes no deterioration and no crack of the photoreceptor, and which has excellent flowability and consequently causes no sticking of the toner to the photoreceptor and consists of fine silica particles. SOLUTION: The electrostatic charge image developing toner external additive is distinguished by being consisting of spherical hydrophobia fine silica particle which is obtained by introducing a R13SiO1/2 unit (in which R1 is univalent hydrocarbon group of 1-6C having substituents of the same kinds or different kinds or having no substituent) on a surface of a hydrophilic fine silica particle constituted of SiO2 unit, which satisfies conditions (i) and (ii) described below, of which average grain size of primary particles is 0.01 to 5 μm. (i) When the fine silica particles are blended with an organic compound which is liquid at room temperature and has 1 to 40 F/m dielectric constant at 5:1 weight ratio and are shaked, the fine silica particles uniformly disperse in the organic compound. (ii) When the fine silica particles are kept at 100 deg.C for 2 hours after evaporating methanol by an evaporator under heating from a dispersion obtained by dispersing the fine silica particles into methanol, ratio of primary particle quantity left as the primary particle to primary particle quantity present at first is >=20%.

29. 发明专利

JP2000109529A PRODUCTION OF POLYURETHANE FOAM 失效
公开(公告)号：JP2000109529A
公开(公告)日：2000-04-18
申请号：JP28681298
申请日：1998-10-08
申请人： SHINETSU CHEMICAL CO
发明人： KUDO MUNEO , ASAMI ATSUSHI , ICHINOHE SEIJI , ASAI MITSUO
IPC分类号： C08J9/02 , C01B33/146 , C01B33/18 , C08G18/00 , C08G101/00 , C08K3/36 , C08K9/02 , C08L75/04
摘要： PROBLEM TO BE SOLVED: To obtain a polyurethane foam having excellent dimensional stability by foaming and curing a polyurethane foam composition containing a polyisocyanate and a mixture prepared by adding hydrophobic silica-based particles to a resin premix which comprises a polyol, or the like, and has excellent storage stability. SOLUTION: This polyurethane foam is obtained by foaming and curing a polyurethane foam composition containing (C) a polyisocyanate and a mixture prepared by adding (B) hydrophobic silica-based particles which preferably have a particle diameter of 0.1-1 μm and preferably contain 1-30 mol.% of R13SiO1/2 units (R1 is a 1-6C monovalent hydrocarbon group), 0.1-20 mol.% of R2SiO3/2 units (R2 is a 1-20C monovalent hydrocarbon) and 70-99 mol.% of SiO2 units to (A) a resin premix comprising a polyol (for example, polyethylene glycol), water, a catalyst (for example, tetramethylhexmethylene diamine), and a surfactant.

30. 发明专利

JPH09255941A WATER-REPELLENT TREATMENT AND PREPARATION THEREOF 失效
公开(公告)号：JPH09255941A
公开(公告)日：1997-09-30
申请号：JP6950796
申请日：1996-03-26
申请人： NIPPON SHEET GLASS CO LTD , SHINETSU CHEMICAL CO
发明人： YAMAMOTO HIROAKI , MITANI KAZUISHI , SUZUKI KOICHI , TERANISHI TOYOYUKI , KUDO MUNEO , ASAI MITSUO
IPC分类号： C09K3/18 , C03C17/30
摘要： PROBLEM TO BE SOLVED: To provide a water-repellent treatment capable of giving excellent water repellency and stainproofing properties, and excellent in water-repellent treatment workability in a short treatment time. SOLUTION: This water-repellent treatment contains an organosilicon compd. having an alkoxy group or an acyloxy group and/or its hydrolyzate, and an org. solvent. The concn. of the organosilicon compd. and/or its hydrolyzate is 0.01 to 0.1wt.%. The org. solvent contains 50-99.95wt.% nonpolar solvent.

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