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    • 22. 发明专利
    • Composite target for x-ray tube rotating anode
    • 用于X射线管旋转阳极的复合材料目标
    • JPS59207552A
    • 1984-11-24
    • JP8335083
    • 1983-05-12
    • Hitachi LtdHitachi Medical Corp
    • YAMADA TSUNEOKOYAMA TETSUOBABA NOBORUSUWA MASATERUNAKAGAWA YUUSAKU
    • H01J9/14H01J35/10
    • H01J35/108
    • PURPOSE:To increase breakng strength by decreasing graphite occupying ratio in the surface layer, which is in contact with metal, of a graphite substrate than that in the inner layer when a composite target is formed by bonding a graphite substrate with a metal alloy. CONSTITUTION:A graphite substrate 1 that graphite occupying ratio in its surface layer is less than 1.8/2.2 and that in its inner layer is 1.8/2.2 or more is obtained by heating graphite in an atmosphere of gas containing oxygen at 600 deg.C or more, then quenching it in water. W-Re alloy 2 is placed thereon with Zr- 31Mo weld alloy 3 interposed, and they are heated in a vacuum under static pressure to bond them. By this process, a composite target for X-ray tube rotating anode is formed. Since weld alloy 3 and W-Re alloy penetrate in the surface layer in which graphite occupying ratio is low, strength is remarkably increased. Therefore, this process makes it possible to produce a large diameter target.
    • 目的:通过将石墨基板与金属合金接合来形成复合靶时,通过降低与金属接触的表面层中的石墨基材比石墨基板的石墨占据比例来提高断裂强度。 构成:通过在600℃的含氧气体气氛中加热石墨,得到表面层中的石墨占有率小于1.8 / 2.2,其内层的石墨基体1为1.8 / 2.2以上的石墨基板1,或 然后再在水中淬火。 将W-Re合金2放置在其上,并插入Zr-31Mo焊接合金3,并将它们在静态压力下在真空中加热以使它们结合。 通过该工艺,形成用于X射线管旋转阳极的复合靶。 由于焊接合金3和W-Re合金在石墨占有率低的表层渗透,因此强度显着增加。 因此,该方法使得可以生产大直径目标。
    • 25. 发明专利
    • SODIUM-SULFUR BATTERY
    • JPH1131524A
    • 1999-02-02
    • JP18346897
    • 1997-07-09
    • HITACHI LTD
    • ANPO KATSUOHATOU HISAMITSUKOBAYASHI MINORUKOYAMA TETSUOABE KAZUHIKO
    • H01M2/26H01M10/39
    • PROBLEM TO BE SOLVED: To significantly lower electric resistance by nickel-plating the surface of an iron-base alloy-made vessel, sandwiching a copper plate between the same and an aluminum-made collecting terminal adhesion face, and forming a nickel-copper-aluminum alloy through heating so as to fuse. SOLUTION: As a connection example of an aluminum-made negative electrode terminal 10 and an iron alloy-made negative electrode lid 4, the connection portion of the iron alloy-made negative electrode lid 4 is electroplated to form a nickel-plated layer 11, and a copper plate 12 is inserted between the same and the jointing negative electrode terminal 10. A nickel-plating layer 11 with a thickness of 2 to 20 microns is suitable, but practically five to 10 microns is suitable. Although a copper plate 12 thickness of 5 to 200 microns is suitable, practically 10 to 20 microns is sufficient. The negative electrode terminal 10 of 2 mm in thickness 20 mm in width and 20 mm in adhesion length is set on a copper plate 12 face, so that its adhesion face sticks closely and is lightly pressed. Thereafter, the same is heated at 550 to 650 deg.C in an inert gas.
    • 26. 发明专利
    • SODIUM-SULFUR BATTERY
    • JPH10228926A
    • 1998-08-25
    • JP3169797
    • 1997-02-17
    • HITACHI LTD
    • ANPO KATSUOKOYAMA TETSUOHATOU HISAMITSUKOBAYASHI MINORUKUSAKABE KOJIMADOKORO MANABUMITSUYOSHI TADAHIKOKAMO YUICHI
    • H01M4/62H01M10/39
    • PROBLEM TO BE SOLVED: To reduce the unevenness of internal resistance of a battery, and improve the charging and discharging performance, and lower the cost of the positive electrode conductive material by pinching a graphite mat between a solid electrolyte and a positive electrode container so as to prevent the sedimentation of the mixture of graphite powder and sulfur in the condition that it is divided to a specified number in the axial direction of the battery, and filling each space between the graphite mat with graphite powder. SOLUTION: In this sodium-sulfur battery, a positive electrode conductive material 5, which is impregnated with sulfur 6 as the positive electrode active material, is filled in a cylindrical positive electrode container 1 made of metal and having a bottom. A cylindrical solid electrolyte tube 2 made of ceramics and having a bottom is arranged inside thereof, and sodium 7 as the negative electrode active material and a negative electrode conductive bar 8 for electrically connecting the sodium 7 and a negative electrode lid 4 to each other are provided. The positive electrode container 1 and the solid electrolyte tube 2 are air-tightly sealed by an upper insulating ring 3 made of ceramic and the negative electrode lid 4 made of metal. A graphite mat 9 is inserted into the positive electrode conductive material 5, and divided into 2-10 pieces.
    • 30. 发明专利
    • SODIUM SULFUR BATTERY MODULE
    • JPH1040951A
    • 1998-02-13
    • JP19178496
    • 1996-07-22
    • HITACHI LTD
    • MITSUYOSHI TADAHIKOKOYAMA TETSUOHATOU HISAMITSUMADOKORO MANABU
    • H01M2/02H01M10/39
    • PROBLEM TO BE SOLVED: To provide a sodium sulfur battery module by which the degradation of a joining part and the corrosive degradation of a positive electrode vessel are hardly caused and high output operation can be performed. SOLUTION: In an Na sulfur battery module by connecting plural Na sulfur batteries containing a negative electrode vessel 2 to house Na, a positive electrode vessel 5 to house a positive electrode mold composed of sulfur or an Na polysulfide and carbon fiber, a solid electrolyte tube 1 to separate a negative electrode and a positive electrode from each other and an insulating member 7 which is connected to the solid electrolyte tube 1 and is joined to the negative electrode vessel 2 and the positive electrode vessel 5, the positive electrode vessel 5 contains a joining body of a cylinder part 51 and a flange part 52, and in a material of the cylinder part 51, a corrosive layer is arranged on a surface of Al or Al allay, and the cylinder part 51 is connected to Al or Al alloy-made bus bar, and in the flange part 52, the flange part 52 and the insulating member 7 are joined together by using stainless steel.