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    • 21. 发明专利
    • SOLAR CELL
    • JPH06283744A
    • 1994-10-07
    • JP8690992
    • 1992-04-08
    • HITACHI CABLE
    • UNNO TSUNEHIRONAKAZONO RYUICHI
    • H01L31/04
    • PURPOSE:To enhance the photoelectric conversion efficiency of the title solar cell by a method wherein a recombination-preventing layer is provided with a band-gap energy grade in such a way that the grade is large on the side away from a p-n junction and that the grade is small on the side close to the p-n junction. CONSTITUTION:An action region layer 12 composed of n-type GaAs, an action region layer 13 composed of p-type GaAs and a window layer 14 as a recrystallization-preventing layer composed of p-type GaAlAs are formed sequentially on a substrate 11 composed of n-type GaAs. An antireflection film 15 is formed on the surface of the window layer 14, the window layer 14 is passed in a part of the antireflection film, and a p-side electrode 16 is formed. Band-gap energy becomes suddenly large on the surface side, and it becomes small in a p-n junction part. As a result, electrons excited by incident light are influenced by an electric field existing inside the window layer 14, and they are moved smoothly toward the side of the action region layer 13. Thereby, generated electrons are prevented from being recombined and lost, and the photoelectric conversion efficiency of the title solar cell can be enhanced.
    • 23. 发明专利
    • JPH05235410A
    • 1993-09-10
    • JP3914192
    • 1992-02-26
    • HITACHI CABLE
    • UNNO TSUNEHIRO
    • H01L31/10H01L33/00H01L33/10H01L33/14H01L33/30H01L33/44H04B10/00H04B10/40H04B10/43H04B10/50H04B10/60H04B10/02H04B10/24
    • PURPOSE:To reduce loss by equalizing size and price in a reception exclusive module or a transmission exclusive module. CONSTITUTION:Only one single-wavelength photo-detector having structure close to a GaAs/GaAlAs group DH junction LED is used as an optical semiconductor element 7 for transmission and reception, and the photo-detector is given both functions of light reception and emission. When forward voltage operating the element 7 as a light-emitting device is applied to the element 7 from a power circuit 8 for changing over transmission and reception, the element 7 functions as the light-emitting device. When a signal for transmission is applied to the element 7 from a signal processing circuit 9 for transmission, the signal is converted into light, and output to a fiber 1. When reverse voltage operating the element 7 as a photo-detector is applied to the element 7 from the power circuit 8, the element 7 functions as the photo-detector. The signal output from the fiber 1 is converted into an electric signal by the photo-detector. The received signal is input to a signal processing circuit 10 for reception and processed. Accordingly, single-wavelength light-reception-emission is enabled in the single element.
    • 25. 发明专利
    • LIGHT EMITTING DIODE
    • JPH04280481A
    • 1992-10-06
    • JP4323591
    • 1991-03-08
    • HITACHI CABLE
    • UNNO TSUNEHIRO
    • H01L33/14H01L33/30
    • PURPOSE:To provide high output and high reliability by providing a current blocking layer which is installed between a semiconductor substrate and a clad layer, and makes pn junction with the clad layer based on conduction type opposite to the clad layer and gets reverse biases when switched on. CONSTITUTION:An n-type GaAlAs current blocking layer 10 is formed on a p-type GaAs substrate 5 which has formed a ring-shaped mesa section 9 in such a fashion that it may be slightly lower than the tip of the ring-shaped mesa section 9, Then, a p-type GaAlAs clad layer 4, a p-type GaAlAs active layer, and an n-type GaAlAs window layer 2 are successively formed. A p-type whole surface electrode 6 is formed on this substrate 5. The current blocking layer 10 forces the pn junction formed on the interface between the current blocking layer 10 and the clad layer 4 when a light emitting diode is switched on to get reversely biassed, thereby forming a depletion layer. This construction makes it possible to block the flow of carriers by resultant higher resistivity.
    • 29. 发明专利
    • LIQUID EPITAXIAL GROWTH PROCESS
    • JPS6461385A
    • 1989-03-08
    • JP21805387
    • 1987-09-02
    • HITACHI CABLE
    • UNNO TSUNEHIROWAJIMA MINEOTATE HISAFUMIKONNO TAIICHIROSUGIMOTO HIROSHI
    • C30B29/42C30B19/00C30B29/40H01L21/208
    • PURPOSE:To improve uniformity and reproducibility of film thickness and obtain an epitaxially grown layer in high mass-productivity and accuracy, by transferring a solution for growth to a specific intermediate solution reservoir in a vertical epitaxial growth process, adjusting the solution to a supersaturated state with uniform temperature gradient and contacting the solution with a substrate. CONSTITUTION:An intermediate liquid reservoir 5 having plural narrow spaces 5b having a thickness of 1-10mm and partitioned with plural partition walls 5a is placed between a growth solution reservoir 2 holding a growth solution 8 and a substrate holding part 4 placed above the reservoir 2 and holding plural substrates 7 with respective holding tools 4a in vertical state. In the above vertical epitaxial growth apparatus, polycrystalline GaAs is dissolved in Ga held in the growth solution reservoir 2 to saturated state and the obtained growth solution 8 is dispensed to each space 5b by pushing a reciprocative piston 3 and slowly cooled to uniformize the temperature distribution and to get supersaturated state. The piston 3 is further pushed forward to contact the solution with plural substrates 7 such as GaAs held vertically with the substrate holding part 4 to start the epitaxial growth. A multiple-layered epitaxial growth wafer having uniform film thickness can be produced by this process.