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    • 12. 发明专利
    • DEFOAMING AGENT
    • JPH1015305A
    • 1998-01-20
    • JP17912496
    • 1996-07-09
    • NOF CORP
    • YOKOYAMA SHOICHIKUBO YOSHIFUMI
    • B01D19/04C11D1/722
    • PROBLEM TO BE SOLVED: To obtain a defoaming agent excellent in emulsion dispersibility and defoaming capacity by using a compd. prepared by adding an alkylene oxide to a fatty containing specific amt. of an unsaturated fatty acid as the defoaming agent. SOLUTION: As a defoaming agent, RCOO [(C2 H4 O)a (C3 H6 O)b ] (wherein RCO is an aliphatic acyl group characterized by that a wt. ratio of an oleoyl group and a rinoleoyl group is 4:6-6:4 and the sum total of the oleoyl group and the linoleoyl group is 50wt.% or more of the total aliphatic acyl group, a is 1-30, b is 5-150, the oxythylene group and oxypropylene group in [] are added in a block state and the addition order of then is not inquired) is used as a defoaming agent. This defoaming agent is safe and excellent in foam bursting and foaming suppressing effects regardless of the kind of the trouble caused by foaming and is used industrially.
    • 13. 发明专利
    • Gel electrolyte and a secondary battery
    • 凝胶电解质和二次电池
    • JP2006261024A
    • 2006-09-28
    • JP2005079288
    • 2005-03-18
    • Hitachi LtdNof Corp日本油脂株式会社株式会社日立製作所
    • OKUMURA SOUBUNNISHIMURA SHINIWAYASU NORIOKONO KAZUSHIGEYOKOYAMA SHOICHIMIZUTANI MASAHITOITO TETSUYA
    • H01B1/06H01M10/05H01M10/0565
    • H01M10/0565H01M2300/0085
    • PROBLEM TO BE SOLVED: To provide a gel electrolyte having high ion conductivity and stability at high temperature with a high compliance to a large current when used as a battery electrolyte, and a secondary battery. SOLUTION: The secondary battery comprises a gel electrolyte which is composed of a polymer matrix obtained by polymerizing boric acid ester having a polymeric functional group as expressed by a formula (1) at the end portion, an electrolyte salt, and a non-aqueous solvent. Herin, Z 1 , Z 2 , Z 3 are polymeric functional group or hydrocarbon group having carbon number 1-10, and out of three groups Z 1 , Z 2 , Z 3 , the hydrocarbon groups with the carbon number 1-10 are included 1.0-2.5 in mol average. AO is oxy-alkylene group having carbon number 2-4, and l, m, n are average repeating number of oxy-alkylene group and are each independently 0-100, and l+m+n is 1-300, and B is boron atom. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种具有高离子电导率和在高温下的稳定性的凝胶电解质,当用作电池电解质时,具有高的依赖于大电流的凝胶电解质和二次电池。 解决方案:二次电池包括凝胶电解质,该凝胶电解质由通过在端部聚合具有由式(1)表示的聚合官能团的硼酸酯获得的聚合物基质,电解质盐和非电解质 - 水溶剂。 Herin,Z 1 ,Z 2 ,Z 3 是聚合官能团或碳数为1-10的烃基, Z 1 ,Z 2 ,Z 3 ,碳数为1-10的烃基的摩尔含量为1.0-2.5。 AO是碳数为2-4的氧亚烷基,l,m,n为氧亚烷基的平均重复数,各自为0〜100,l + m + n为1-300,B为 硼原子。 版权所有(C)2006,JPO&NCIPI
    • 19. 发明专利
    • Method for producing urethane (meth)acrylate
    • 制备脲(甲基)丙烯酸酯的方法
    • JP2003286340A
    • 2003-10-10
    • JP2002093607
    • 2002-03-29
    • Nof Corp日本油脂株式会社
    • MIZUTANI MASAHITOYOKOYAMA SHOICHITANAKA SUSUMU
    • C08G65/48
    • PROBLEM TO BE SOLVED: To provide a method for producing a urethane (meth)acrylate which does not cause an increase in viscosity and gelling during the reaction, has a low odor and, simultaneously, excellent storage stability.
      SOLUTION: The method for producing a urethane (meth)acrylate to be represented by the formula (1): R
      1 -(NHCOR
      2 )
      a (wherein R
      1 is an a-valent deisocyanated residue of an isocyanate compound; a is an integer of 2-10; R
      2 is a dehydrated residue of a monool having a (meth)acryloyl group to be represented by the formula (2): [CH
      2 =C(R
      3 )COO]
      b-1 -X-OH) (wherein R
      3 is a H or CH
      3 ; X is a dehydroxylated residue of a b-valent polyhydric alcohol; and b is an integer of 2-6) comprises dehydrating the monool having a (meth) acryloyl group at 20-90°C before the reaction, then adding an isocyanate compound dropwise to effect reaction.
      COPYRIGHT: (C)2004,JPO
    • 待解决的问题:为了提供一种在反应中不引起粘度增加和凝胶化的氨基甲酸酯(甲基)丙烯酸酯的制造方法,具有低气味,同时优异的储存稳定性。 解决方案:用于制备由式(1)表示的氨基甲酸酯(甲基)丙烯酸酯的制备方法:R - (NHCOR 2 a (其中R 1 是异氰酸酯化合物的a价脱异氰基残基; a为2-10的整数; R 2为脱水残基 具有由式(2)表示的(甲基)丙烯酰基的一元醇:[CH 2 SB 2 = C(R 3 SP 3)COO] SB X-OH)(其中R 3是H或CH 3 SB; X是b价多元醇的脱羟基化残基; b是 2-6)的整数)包括在反应之前使20-90℃下具有(甲基)丙烯酰基的一元醇脱水,然后滴加异氰酸酯化合物进行反应。 版权所有(C)2004,JPO