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11. 发明专利

JPH0267230A PURIFICATION OF ORGANOMETALLIC COMPOUND 失效
公开(公告)号：JPH0267230A
公开(公告)日：1990-03-07
申请号：JP21628988
申请日：1988-09-02
申请人： TOYO STAUFFER CHEM CO
发明人： SAKAGOSHI TATSUO , OKAZAKI TAKASHI
IPC分类号： C07B47/00 , C07B63/02 , C07C395/00 , C07F1/02 , C07F3/02 , C07F3/06 , C07F3/08 , C07F5/00 , C07F5/06 , C07F7/00 , C07F7/30 , C07F11/00
摘要： PURPOSE:To obtain a purified organometallic compound suitable for the use in the field of precision chemicals by adding a reducing agent such as NaH to an organometallic compound containing traces of halogen-containing component and oxygen-containing component under stirring and subjecting the mixture to distillation or sublimation separation treatment. CONSTITUTION:An organometallic compound of formula I - formula IV (M1-M4 are 1-4 valent element, respectively; R1-R4 are alkyl, aryl, cycloalkadienyl or H) is added with 0.1-50wt.% (preferably 1-20wt.%) of a reducing agent (e.g. NaH, aluminum hydride or sodium diethylaluminum dihydride) and made to react with each other at 10-150 deg.C for 10min - 10hr. The organometallic compound free from impurities can be produced by carrying out the distillation or sublimation purification of the reaction mixture optionally after separating the mixture into the reaction product and the unreacted organometallic compound. The purification treatment may be performed in the form of a mixture with an organic solvent.

12. 发明专利

JPH01225775A FORMATION OF CERAMIC COATING FILM ON INNER SURFACE OF TUBULAR MATERIAL 失效
公开(公告)号：JPH01225775A
公开(公告)日：1989-09-08
申请号：JP5079088
申请日：1988-03-04
申请人： TOYO STAUFFER CHEM CO
发明人： YASUDA KAZUTO
IPC分类号： C23C16/50
摘要： PURPOSE:To form a ceramic film generated by the decomposition of a raw gas on the inner surface of a tubular material at low temp. by introducing the raw gas into the material, and supplying a high-frequency power. CONSTITUTION:The gaseous mixture of TiCl4 and NH3, TiCl4 and CH4, AlCl3 and BCl3, SiH4 and N2O, SiH4 and NH3, (CH3)3Al and N2O, etc., is introduced into the tubular material 1-5 from a raw gas feeder 1-4 with H2, Ar, N2, etc., as the carrier gas. A high-frequency power is simultaneously supplied from a high-frequency generator 1-1 through a waveguide 1-8 to produce plasma in the material, hence the raw gas is decomposed, and the thin film of the TiN, TiC, AlB, SiO2, Si3N4, Al2O3, etc., as the ceramic material is formed on the inner surface of the tubular material 1-5. In this case, when the tubular material 1-5 is made of a material transmitting a high-frequency power such as quartz, the outside of the material 1-5 is coated with a metal to reflect the high-frequency power. In addition, a magnetic field generator is provided on the outside or inside of the material 1-5 to control the plasma state, and the quality and thickness of the ceramic film can be controlled.

13. 发明专利

JPS63215504A CALCIUM HYDROGEN PHOSPHATE DIHYDRATE AND PRODUCTION THEREOF 失效
公开(公告)号：JPS63215504A
公开(公告)日：1988-09-08
申请号：JP4739387
申请日：1987-03-02
申请人： TOYO STAUFFER CHEM CO
发明人： TAKITANI MASARU , ICHIKAWA ATSUSHI
IPC分类号： C01B25/32 , A61K8/00 , A61K8/24 , A61Q11/00
摘要： PURPOSE:To obtain the titled compound having high cleaning performance and low abrasive action, exhibiting excellent tooth-whitening effect and suitable as an abrasive base for dentifrice, by neutralizing phosphoric acid with a Ca compound such as quick lime or CaCO3 in the presence of a specific habit modifier. CONSTITUTION:One or more kinds of Ca compounds selected from quick time, slaked lime and CaCO3 are added to water at a concentration of e.g. 50-200g/l (in terms of CaO) and stirred to obtain milk of lime consisting of a slurry of fine Ca(OH)2, etc. The lime of milk is added to an aqueous solution of phosphoric acid heated at , a specific surface area of 10-50m /g and an average particle diameter of 10-50mu and consisting of aggregates of primary particles having a particle diameter of 0.01-0.9mu.

14. 发明专利

JPS6340777B2 失效
公开(公告)号：JPS6340777B2
公开(公告)日：1988-08-12
申请号：JP3946484
申请日：1984-03-01
申请人： TOYO STAUFFER CHEM CO
发明人： DOBASHI GENICHI , SUZUKI KEISUKE
IPC分类号： C07C45/52 , A01N35/02 , B01J31/00 , B01J31/14 , C07B31/00 , C07B53/00 , C07B61/00 , C07C45/00 , C07C45/51 , C07C49/04 , C07C49/105 , C07C49/313 , C07C49/543 , C07C49/553 , C07C67/00 , C07C301/00 , C07C303/28 , C07C309/65

15. 发明专利

JPS6340776B2 失效
公开(公告)号：JPS6340776B2
公开(公告)日：1988-08-12
申请号：JP19548783
申请日：1983-10-19
申请人： TOYO STAUFFER CHEM CO
发明人： DOBASHI GENICHI , SUZUKI KEISUKE
IPC分类号： C07D307/46 , B01J31/00 , B01J31/14 , C07B31/00 , C07B53/00 , C07B61/00 , C07C45/00 , C07C45/51 , C07C45/52 , C07C45/54 , C07C49/215 , C07C49/217 , C07C49/225 , C07C49/255 , C07C49/782 , C07C49/784 , C07C67/00 , C07C301/00 , C07C303/28 , C07C309/64

16. 发明专利

JPS6310088B2 失效
公开(公告)号：JPS6310088B2
公开(公告)日：1988-03-03
申请号：JP9395883
申请日：1983-05-30
申请人： TOYO STAUFFER CHEM CO
发明人： KATO ATSUMI , ASADA KEIJI , ICHIKAWA ATSUSHI
IPC分类号： B01J2/30 , A23L29/00 , A61K8/00 , A61K8/24 , A61K47/02 , A61Q11/00 , C01B25/32

17. 发明专利

JPS62281882A METHOD FOR HYDROALUMINATION REACTION OF OLEFIN 失效
公开(公告)号：JPS62281882A
公开(公告)日：1987-12-07
申请号：JP12013786
申请日：1986-05-27
申请人： TOYO STAUFFER CHEM CO
发明人： YAMAMOTO TAKASHI , MARUOKA KEIJI , NAKAI SHUICHI
IPC分类号： C07F5/06 , B01J31/14 , C07B61/00 , C07C1/00 , C07C1/32 , C07C9/14 , C07C15/02 , C07C17/00 , C07C17/08 , C07C19/01 , C07C19/07 , C07C22/02 , C07C27/00 , C07C29/09 , C07C29/12 , C07C31/02 , C07C33/14 , C07C33/20 , C07C45/00 , C07C49/04 , C07C49/76 , C07C67/00 , C07C321/28 , C07F7/08
摘要： PURPOSE:To carry out hydroalumination reaction of olefin in high yield, by treating an olefin with an aluminum-containing metal hydrogenating agent by the use of an organic boron compound as a catalyst in a solvent. CONSTITUTION:An olefin is treated with an aluminum-containing metal hydrogenating agent (preferably dichloroaluminum hydride, dialkyl-aluminum hydride or aluminum trihydride) or the agent and an electrophilic agent in a solvent (preferably ether, THF, dichloromethane, dichloroethane, pentane, hexane, heptane, benzene, toluene or xylene) by the use of an organic boron compound [preferably phenylboric acid, monoalkylboric acid, dialklboric acid, trialkylboric acid, dialkyl boran, triakoxy boran, 9-borabicyclo(3,3,1)nonane] as a catalyst.

18. 发明专利

JPS6248961B2 失效
公开(公告)号：JPS6248961B2
公开(公告)日：1987-10-16
申请号：JP8985781
申请日：1981-06-11
申请人： TOYO STAUFFER CHEM CO
发明人： TAKITANI MASARU , TOMYASU SHIZUO , BABA KEIKICHI
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00

19. 发明专利

JPS61197417A PRODUCTION OF HIGH-PURITY MULLITE POWDER 失效
公开(公告)号：JPS61197417A
公开(公告)日：1986-09-01
申请号：JP2283485
申请日：1985-02-08
申请人： TOYO STAUFFER CHEM CO
发明人： NAKAMURA TAKESHI , TAKITANI MASARU
IPC分类号： C01B33/26 , C01B33/46 , C04B33/18
摘要： PURPOSE:To produce fine mullite powder having high purity and free from agglomeration, by mixing an alkyl aluminum compound of a specific formula with a silicon alkoxide at a ratio of the mullite composition, heating the mixture, hydrolyzing in a non-aqueous solvent and calcining the product. CONSTITUTION:An alkyl aluminum compound of formula R2AlR' (R is 1-20C alkyl; R' is 1-8C alkyl or H) (e.g. triethyl aluminum, etc.) is mixed with a silicon alkoxide of formula Si(OR)4 (R is 1-20C alkyl) (e.g. ethyl silicate) at a ratio of 5:2-1.5:1, and the mixture is heated at 80-200 deg.C, and hydrolyzed in a non-aqueous solvent such as toluene. The produced fine powder of aluminum silicate is separated, dried and calcined at about 700-1,300 deg.C.

20. 发明专利

JPS6087237A PRODUCTION OF OPTICALLY ACTIVE KETONE 失效
公开(公告)号：JPS6087237A
公开(公告)日：1985-05-16
申请号：JP19548783
申请日：1983-10-19
申请人： TOYO STAUFFER CHEM CO
发明人： DOBASHI GENICHI , SUZUKI KEISUKE
IPC分类号： C07D307/46 , B01J31/00 , B01J31/14 , C07B31/00 , C07B53/00 , C07B61/00 , C07C45/00 , C07C45/51 , C07C45/52 , C07C45/54 , C07C49/215 , C07C49/217 , C07C49/225 , C07C49/255 , C07C49/782 , C07C49/784 , C07C67/00 , C07C301/00 , C07C303/28 , C07C309/64
摘要： PURPOSE:To obtain an optically active ketone with high enanethio selectivity easily in high yield, by subjecting an optically active sulfonyloxy alcohol as a raw material to the pinacol rearrangement in the presence of an organoaluminum compound in a solvent. CONSTITUTION:An optically active vic-diol of formula1(R is 2-20C hydrocarbon group; R' is 1-20C hydrocarbon group; hydrocarbon groups R and R' may contain functional groups which will not affect the reaction; * is asymmetric carbon atom; R is a group having more improved electron donative property than R' including the case where R is the same as R') is sulfonylated with a compound of formula II (R'' is the same as R') to give an optically active sulfonyloxyalcohol of formula III, which is then subjected to the pinacol rearrangement reaction in the presence of an organoaluminum compound, e.g. a trialklaluminum, in a solvent at room temperature --80 deg.C for 0.05-5hr to afford the aimed compound, having [S] or [R] absolute configuration, which is an alarm pheromone of ants.

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