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11. 发明专利

JP2014205825A 架橋方法、並びにその架橋方法により得られる架橋高分子审中-公开
标题翻译：交联方法和交联聚合物交联方法获得的交联聚合物
公开(公告)号：JP2014205825A
公开(公告)日：2014-10-30
申请号：JP2014055151
申请日：2014-03-18
申请人：日本合成化学工業株式会社 , Nippon Synthetic Chem Ind Co Ltd:The
发明人： AOKI YASUHIRO
IPC分类号： C08J3/24 , C08K5/098 , C08L29/04 , C08L101/00
摘要：【課題】架橋高分子の形成に用いられる架橋方法を提供すること。特に、アセトアセチル基含有ポリビニルアルコール系樹脂を架橋高分子化する架橋方法として好適であり、耐水性に非常に優れた架橋高分子が得られる架橋高分子を提供すること。【解決手段】架橋剤と反応して架橋構造を形成しうる化合物(A)に、架橋剤として、グリオキシル酸のアルカリ金属塩(B1)及びグリオキシル酸のアルカリ土類金属塩(B2)を配合して該化合物(A)を架橋させることを特徴とする架橋方法。【選択図】なし
摘要翻译：要解决的问题：为了提供用于形成交联聚合物的交联方法，首先提供适合作为交联和聚合含乙酰乙酰基的聚乙烯醇树脂的交联方法的交联方法，并产生具有非常优异的交联聚合物耐水性。解决方案：在所提供的交联方法中，（B1）乙醛酸的碱金属盐和（B2）乙醛酸的碱土金属盐作为交联剂与（A）能够形成交联结构，由于与交联剂反应而使化合物（A）交联。

12. 发明专利

JP2014148750A Metal composite superfine particle and its manufacturing method 审中-公开
标题翻译：金属复合超细颗粒及其制造方法
公开(公告)号：JP2014148750A
公开(公告)日：2014-08-21
申请号：JP2014002218
申请日：2014-01-09
申请人： Nippon Synthetic Chem Ind Co Ltd:The , 日本合成化学工業株式会社
发明人： SATO HIROAKI
IPC分类号： B22F1/02 , B22F1/00 , B22F9/24 , H01B5/00 , H01B13/00
摘要： PROBLEM TO BE SOLVED: To provide a metal composite superfine particle excellent in reactivity and method of manufacturing the metal composite superfine particle manufacturing the particle in high efficiency.SOLUTION: Metal composite superfine particles are used having an average 1.2 or more of circularity of particles photographed by a transmission electron microscope and an average particle major axis of 1 to 200 nm. There is provided a method of manufacturing the metal composite superfine particle whose metal species are gold, silver and copper, by reacting inorganic metal salts and higher alcohols with heating and stirring the inorganic metal salts and the higher alcohols, including a process of stirring at 20 to 120°C for at least 5 minutes and a process of stirring at 120°C to 300°C for at least 5 minutes, and the stirring processes satisfy a condition represented by the formula (1). 0.05≤Δt/D≤0.8 (1), where D is a radius of a swirl on a surface of a liquid during stirring and Δt is difference of the lowest point and the highest point of the swirl.
摘要翻译：要解决的问题：提供一种反应性优异的金属复合超细颗粒和制造高效率的颗粒的金属复合超细颗粒的方法。解决方案：使用金属复合超细颗粒，其平均具有1.2或更多的圆形颗粒拍摄通过透射电子显微镜，平均粒子长轴为1〜200nm。提供了一种通过加热和搅拌无机金属盐和高级醇来制造金属种类为金，银和铜的金属复合超细颗粒的方法，包括在20℃下搅拌的过程至120℃至少5分钟，并在120℃至300℃下搅拌至少5分钟，并且搅拌过程满足由式（1）表示的条件。 0.05≤＆Dgr; t /D≤0.8（1）其中D是搅拌期间液体表面的漩涡半径，Dgr是最低点和最高点之间的差。

13. 发明专利

JP2014141659A Acrylic resin for heat-resistant adhesive film and adhesive agent composition using the same, adhesive agent, heat-resistant adhesive film and method for producing acrylic resin for heat-resistant adhesive film 有权
标题翻译：用于耐热胶粘剂的丙烯酸树脂和使用其的粘合剂组合物，粘合剂，耐热粘合膜和用于生产用于耐热粘合膜的丙烯酸树脂的方法
公开(公告)号：JP2014141659A
公开(公告)日：2014-08-07
申请号：JP2013268458
申请日：2013-12-26
申请人： Nippon Synthetic Chem Ind Co Ltd:The , 日本合成化学工業株式会社
发明人： TORISAKI RYOICHI , YAMABAYASHI AKIRA
IPC分类号： C09J133/00 , C08F2/44 , C08F6/08 , C08F220/10 , C08L33/04 , C09J7/00 , C09J11/06 , C09J133/04
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an acrylic resin for a heat-resistant adhesive film, which makes it possible to produce an acrylic acid resin having a reduced residual amount of a polymerization initiator.SOLUTION: There is provided a method for producing an acrylic resin by polymerizing a polymerization component [I] containing an alkyl (meth)acrylate-based monomer as a main component in the presence of a polymerization initiator, wherein, in a state where a concentration of the polymerization initiator contained in the reaction solution is 300 ppm or less, heating is carried out at a temperature higher than a ten-hour half-life temperature of the polymerization initiator for 2 hours or more.
摘要翻译：要解决的问题：提供一种用于生产耐热粘合剂膜的丙烯酸树脂的方法，其可以制备聚合引发剂残留量减少的丙烯酸树脂。解决方案：提供了一种用于通过在聚合引发剂的存在下聚合含有（甲基）丙烯酸烷基酯单体作为主要成分的聚合组分[I]制备丙烯酸树脂，其中在反应中所含的聚合引发剂的浓度溶液为300ppm以下，在高于聚合引发剂的十小时半衰期的温度下进行2小时以上的加热。

14. 发明专利

JP2014125523A Cross-linked polymer 有权
标题翻译：交联聚合物
公开(公告)号：JP2014125523A
公开(公告)日：2014-07-07
申请号：JP2012282711
申请日：2012-12-26
申请人： Nippon Synthetic Chem Ind Co Ltd:The , 日本合成化学工業株式会社
发明人： INOUE KAORU , ASANO IKUHIRO
IPC分类号： C08J3/24 , C08J3/28 , C08J7/04 , C09D5/00 , C09D7/12 , C09D129/04
摘要： PROBLEM TO BE SOLVED: To provide a PVA-based resin cross-linked polymer excellent in water resistance when being formed into a thin film.SOLUTION: A cross-linked polymer is obtained by cross-linking an acetoacetyl group-containing polyvinyl alcohol-based resin with glyoxylic acid salt, and then irradiation with ultraviolet rays with 10 to 1,000 mJ/cm.
摘要翻译：要解决的问题：提供当形成薄膜时耐水性优异的PVA类树脂交联聚合物。溶液：通过交联含乙酰乙酰基的聚乙烯醇系的交联聚合物用乙醛酸盐树脂，然后用10〜1000mJ / cm的紫外线照射。

15. 发明专利

JP2014113723A Method for producing plastic sheet, plastic sheet obtained thereby, and plastic substrate for display 有权
标题翻译：用于生产塑料片的方法，获得的塑料片和用于显示的塑料基材
公开(公告)号：JP2014113723A
公开(公告)日：2014-06-26
申请号：JP2012268379
申请日：2012-12-07
申请人： Nippon Synthetic Chem Ind Co Ltd:The , 日本合成化学工業株式会社
发明人： KUBOTA TETSUYA , MAEDA NORISHIGE , HAYAKAWA SEIICHIRO
IPC分类号： B29C39/44 , B29C39/02
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a plastic sheet which has excellent uniformity or flatness and excellent area large-sizeableness or mass productivity, and to provide the plastic sheet obtained by the producing method and a plastic substrate for display.SOLUTION: The method for producing the plastic sheet comprises: multi-stage ultraviolet light irradiation steps (D1, D2) at each of which a molding material packed in a molding die (W) is irradiated multiple times with the ultraviolet light from an ultraviolet lamp (L); and a direction changing step (J) of changing the conveying direction of the molding die by 90° so that the right-and-left ends of the molding die to be conveyed at the preceding ultraviolet light irradiation step (D1) becomes the back-and-forth ends of the molding die to be conveyed at the succeeding ultraviolet light irradiation step (D2).
摘要翻译：要解决的问题：提供一种具有优异的均匀性或平坦性和优异的面积大尺寸或质量生产率的塑料片的制造方法，并提供通过制造方法获得的塑料片和用于显示的塑料基板。制造该塑料片的方法包括：将紫外线灯（L）的紫外线照射多次紫外线照射步骤（D1，D2），将各成型模具（W）中填充的成型材料照射多次）; 以及将成型模具的输送方向改变90°的方向改变步骤（J），使得在前一个紫外线照射步骤（D1）中要输送的成型模具的左右两端成为背面，在随后的紫外线照射步骤（D2）中要输送的成型模具的前后端。

16. 发明专利

JP2014043100A Hose or storage container for high pressure gas 有权
标题翻译：用于高压气体的软管或储存容器
公开(公告)号：JP2014043100A
公开(公告)日：2014-03-13
申请号：JP2013161217
申请日：2013-08-02
申请人： Nippon Synthetic Chem Ind Co Ltd:The , 日本合成化学工業株式会社
发明人： SHIBUYA MITSUO , KANDA TAIJI , HIRANO YASUHIRO , INAKUMA AKIYOSHI
IPC分类号： B32B1/08 , B32B27/30 , C08L27/12 , C08L29/04 , F16L11/04 , F17C1/00
CPC分类号： Y02E60/321
摘要： PROBLEM TO BE SOLVED: To provide a hose or a storage container for high pressure gas, which has high gas barrier properties against hydrogen, in particular, and durability for maintaining excellent gas barrier properties for a long period.SOLUTION: The hose or the storage container for high pressure gas including at least one layer formed of resin composition which contains a side-chain 1,2-diol-containing polyvinyl alcohol resin (A) and a fluorine resin (B) having a polar functional group which is reactable or hydrogen-bondable with a hydroxyl group has excellent wettability at the interface between the component (A) and the component (B), resulting in high gas barrier properties against not only oxygen and air, but also against a small-molecule gas such as hydrogen, without causing blisters under high pressure.
摘要翻译：要解决的问题：提供一种用于高压气体的软管或储存容器，特别是对氢气具有高的阻气性，以及长期保持优异的阻气性的耐久性。解决方案：软管或储存包含由含有含有侧链1,2-二醇的聚乙烯醇树脂（A）和具有可反应的极性官能团的氟树脂（B）的树脂组合物形成的至少一层的高压气体容器，可与羟基键合在组分（A）和组分（B）之间的界面处具有优异的润湿性，导致不仅对氧气和空气有抵抗性，而且对于小分子气体如氢气，而不会在高压下引起水泡。

17. 发明专利

JP2014028936A Emulsion type adhesive composition, emulsion type adhesive and emulsion type detachable adhesive, and adhesive sheet using the same 有权
标题翻译：乳液型粘合剂组合物，乳液型粘合剂和乳液型可分离粘合剂以及使用其的粘合片
公开(公告)号：JP2014028936A
公开(公告)日：2014-02-13
申请号：JP2013133017
申请日：2013-06-25
申请人： Nippon Synthetic Chem Ind Co Ltd:The , 日本合成化学工業株式会社
发明人： UEDA MITSUNORI
IPC分类号： C09J133/06 , C09J7/00 , C09J11/06 , C09J11/08
摘要： PROBLEM TO BE SOLVED: To provide an emulsion type adhesive composition capable of laminating with high adhesive force to an adherend when an adhesive sheet (label) is produced by using a base material having relatively low strength (for example paper, nonwoven fabric, polyethylene and the like) and having good detachability to a polystylene plate and many other types of adherends.SOLUTION: An emulsion type adhesive composition is obtained by an emulsion polymerization of a monomer component (A) mainly containing a (meth)acrylic acid ester-based monomer, and contains a tackifier resin (B), a nonionic type emulsifier having 3 or more benzene rings (X) and an anionic type emulsifier (Y), and a weight ratio (X)/(Y) of contents of the nonionic type emulsifier having 3 or more benzene rings (X) and the anionic type emulsifier (Y) satisfies (X)/(Y)=0.2 to 10.
摘要翻译：要解决的问题：提供一种当通过使用具有较低强度的基材（例如纸，无纺布，聚乙烯等）制造粘合片（标签）时，能够将粘合力高的粘合剂层压到被粘物上的乳液型粘合剂组合物类似物），并且对聚苯乙烯板和许多其它类型的被粘物具有良好的可剥离性。溶液：通过主要含有（甲基）丙烯酸酯系单体的单体组分（A）的乳液聚合获得乳液型粘合剂组合物，并且含有增粘树脂（B），具有3个以上苯环（X）和阴离子型乳化剂（Y）的非离子型乳化剂和非离子型乳化剂的含量的重量比（X）/（Y）具有3个以上的苯环（X）和阴离子型乳化剂（Y）满足（X）/（Y）= 0.2〜10。

18. 发明专利

JP2014009346A Drilling fluid modifier 有权
标题翻译：钻井液改性剂
公开(公告)号：JP2014009346A
公开(公告)日：2014-01-20
申请号：JP2012149194
申请日：2012-07-03
申请人： Nippon Synthetic Chem Ind Co Ltd:The , 日本合成化学工業株式会社
发明人： SAITO MASAHIRO , ASAI AKIRA
IPC分类号： C09K8/12 , C08F226/04 , C09K8/24
摘要： PROBLEM TO BE SOLVED: To provide a modifier for a drilling fluid which is excellent in preventing swelling.SOLUTION: The drilling fluid modifier comprises a polyvinyl alcohol resin aqueous solution having a cationic structural unit represented by the specified general formula (1). (In the formula (1), Rand Reach represent a hydrogen atom or a C1-C3 alkyl group and can be identical or different; Rand Reach represent a C1-C3 alkylene group and can be identical or different; and Y represents a halogen.)
摘要翻译：要解决的问题：提供一种防止溶胀的钻井液的改性剂。解决方案：钻井液改性剂包括具有由特定通式（1）表示的阳离子结构单元的聚乙烯醇树脂水溶液。（式（1）中，Rand Reach代表氢原子或C1-C3烷基并且可以相同或不同; Rand Reach代表C1-C3亚烷基并且可以相同或不同; Y代表卤素。）

19. 发明专利

JP2013227551A Emulsion-type adhesive composition and adhesive sheet 审中-公开
标题翻译：乳液型胶粘组合物和粘合片
公开(公告)号：JP2013227551A
公开(公告)日：2013-11-07
申请号：JP2013068181
申请日：2013-03-28
申请人： Nippon Synthetic Chem Ind Co Ltd:The , 日本合成化学工業株式会社
发明人： MURASE NAOICHI , UEDA MITSUNORI
IPC分类号： C09J133/04 , B32B27/00 , B32B27/30 , C09J7/02 , C09J11/06
CPC分类号： C09J4/00
摘要： PROBLEM TO BE SOLVED: To provide an emulsion-type adhesive composition suitably used for screen printing or the like, which gives a smooth surface during printing, hardly causes foaming or cissing, and is excellent in the clearness of printed edges, drying performance and water resistance.SOLUTION: An emulsion-type adhesive composition includes an emulsion [II] obtained by emulsion polymerization of a monomer mixture [I] containing a (meth)acrylic acid ester monomer. The emulsion-type adhesive composition has a BH20 of 20,000 mPa s or greater and a thixotropy index (Ti) of less than 1.5 (where Ti=BH2/BH20, the BH20 is the viscosity value as measured at a liquid temperature of 25°C and a rotation speed of 20 rpm using a Brookfield viscometer, and the BH2 is the viscosity value as measured at a liquid temperature of 25°C and a rotation speed of 2 rpm using a Brookfield viscometer).
摘要翻译：要解决的问题：为了提供适用于丝网印刷等的乳液型粘合剂组合物，其在印刷过程中表面光滑，几乎不发生起泡或发丝，并且印刷边缘的清晰度，干燥性能和水分优异电阻。溶液：乳液型粘合剂组合物包括通过含有（甲基）丙烯酸酯单体的单体混合物[I]的乳液聚合获得的乳液[II]。乳液型粘合剂组合物的BH20为20,000mPa·s以上，触变性指数（Ti）小于1.5（其中，Ti = BH2 / BH20，BH20为在液温25℃下测定的粘度值使用Brookfield粘度计，旋转速度为20rpm，BH2是使用Brookfield粘度计在液温25℃，转速2rpm下测定的粘度值。

20. 发明专利

JP2013227436A Acrylic resin composition, acrylic adhesive, adhesive sheet, double-sided adhesive sheet, adhesive for transparent electrode, touch panel and image display device, and manufacturing method of laminate containing adhesive layer 有权
标题翻译：丙烯酸树脂组合物，丙烯酸粘合剂，粘合片，双面胶粘剂，用于透明电极的粘合剂，触摸屏和图像显示装置，以及包含粘合层的层压体的制造方法
公开(公告)号：JP2013227436A
公开(公告)日：2013-11-07
申请号：JP2012100762
申请日：2012-04-26
申请人： Nippon Synthetic Chem Ind Co Ltd:The , 日本合成化学工業株式会社
发明人： SUZUKI HIDEAKI
IPC分类号： C08L33/00 , B32B27/30 , C08F2/48 , C08K5/10 , C09J4/02 , C09J7/02 , C09J133/00
摘要： PROBLEM TO BE SOLVED: To provide an acrylic resin composition in which thick coating can be performed, an adhesive layer of a beautiful coating film surface can be obtained, and in addition that is used for manufacturing a solvent based acrylic adhesive of an active energy ray curing type excellent in level difference followability.SOLUTION: An acrylic resin composition includes: an acrylic resin (A); an organic solvent (B); and an ethylenically unsaturated compound (C) having one ethylenically unsaturated group, wherein a content ratio (weight ratio) of the acrylic resin (A) to the ethylenically unsaturated compound (C) having one ethylenically unsaturated group is (A):(C) =10:90-90:10. The acrylic resin composition is characterized in that [I] when a flash point (°C) of the organic solvent (B) is B, and a flash point (°C) of the ethylenically unsaturated compound (C) having one ethylenically unsaturated group is C, Cis higher than B, and a difference between Cand Bis at least 50°C, [II] the ethylenically unsaturated compound (C) having one ethylenically unsaturated group contains at least 50 wt.% of a (meth)acrylic acid alkyl ester compound (C1) in which a number of an alkyl group is at least 10.
摘要翻译：要解决的问题：为了提供可以进行厚涂层的丙烯酸树脂组合物，可以获得美丽的涂膜表面的粘合剂层，并且另外用于制造活性能量射线的溶剂型丙烯酸粘合剂固化型液位差跟随性优异。解决方案：丙烯酸树脂组合物包括：丙烯酸树脂（A）; 有机溶剂（B）; 和具有一个烯属不饱和基团的烯键式不饱和化合物（C），其中丙烯酸树脂（A）与具有一个烯属不饱和基团的烯键式不饱和化合物（C）的含量比（重量比）为（A）：（C） = 10：90-90：10。丙烯酸树脂组合物的特征在于，当有机溶剂（B）的闪点（℃）为B时，[I]和具有一个烯属不饱和基团的烯属不饱和化合物（C）的闪点（℃）是C，Cis高于B，Cand Bis至少为50℃之间的差异，[II]具有一个烯键式不饱和基团的烯键式不饱和化合物（C）含有至少50重量％的（甲基）丙烯酸烷基酯化合物（C1），其中烷基数为至少10。

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