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    • 132. 发明专利
    • DEPHOSPHORIZING METHOD
    • JPS6082188A
    • 1985-05-10
    • JP18954783
    • 1983-10-11
    • KURITA WATER IND LTD
    • JIYOUKOU ISAOSAWADA SHIGEKIGOTOU CHIYUUICHI
    • C02F1/58
    • PURPOSE:To perform effective dephosphorizing treatment by bringing a dephosphorizing material on which a calcium phosphate crystal is precipitated into contact with an acidic soln. then lprecipitating again the calcium phosphate crystal on the surface of a carrier. CONSTITUTION:A carrier such as zeolite is first brought into contact with a soln. contg. phosphoric acid or the salt thereof to deposit phosphorus thereon and thereafter the carrier is brought into contact with a soln. contg. lime such as an aq. slaked lime soln. or the like to obtain a dephosphorizing material on which a calcium phosphate crystal is precipitated. Water contg. phosphoric acid is passed through the packed bed in which the above-described dephosphorizing material is packed, in the presence of calcium ion, to precipitate the phosphate ion on the dephosphorizing agent in the form of hydroxy apatite. The dephosphorizing agent of which the performance is deteriorated after the agent is subjected continuously to a dephosphorizing operation is brought into contact with the acidic soln. to dissolve away the calcium phosphate crystal precipitated on the carrier surface as best as possible.
    • 133. 发明专利
    • DEPHOSPHORIZATION
    • JPS6078692A
    • 1985-05-04
    • JP18786883
    • 1983-10-07
    • KURITA WATER IND LTD
    • JIYOUKOU ISAOKANENIWA HATSUMISAWADA SHIGEKIGOTOU CHIYUUICHI
    • C02F1/58
    • PURPOSE:To perform the dephosphorization of a phosphate-containing water with good efficiency, by passing phosphate-containing water through a packing layer of a deposphorization agent having a calcium phosphate crystal formed to the surface thereof in the presence of a Ca-ion under a condition of pH 6 or more. CONSTITUTION:Zeolite is brought into contact with an aqueous solution containing a calcium agent such as calcium chloride or calcium hydroxide and calcium is collected by zeolite by ion echange. In the next step, zeolite is separated and contacted with an aqueous solution containing phosphoric acid or a salt thereof to support phosphorus while the treated zeolite is brought into contact with a solution containing lime such as slaked lime to form a calcium phosphate crystal to the surface thereof to obtain a dephosphorization agent. Phosphate-containing water such as sewage is passed through a packing layer packed with the dephosphorization agent in the presence of a calcium ion and a phosphate ion is precipitated on the dephosphorization agent in a hydroxyapatite form to perform phosphorization.
    • 134. 发明专利
    • DEPHOSPHORIZING METHOD
    • JPS6075394A
    • 1985-04-27
    • JP18397083
    • 1983-09-30
    • KURITA WATER IND LTD
    • JIYOUKOU ISAOKANENIWA HATSUMISAWADA SHIGEKIGOTOU CHIYUUICHI
    • C02F1/58
    • PURPOSE:To permit easy production of a dephosphorizing agent and to perform effectively dephosphorizing treatment by bringing zeolite, etc. into contact with a lime soln. then bringing the same into contact with phosphoric acid and passing waste water contg. phosphate through the layer packed with the dephosphorizing agent formed by such contact. CONSTITUTION:A carrier consisting of zeolite or limestone is brought into contact with a soln. contg. lime of an aq. slaked lime soln. and is then separated from the soln. The soln. is then brought into contact with an aq. soln. of phosphoric acid or sodium phosphate to form the crystal of calcium phosphate. The resulted product thereof is packed as a dephosphorizing agent into the packed bed where waste water contg. phosphate is passed under the condition of >=6pH in the presence of Ca ion. The dephosphorizing agent having excellent dephosphorizing performance is stably produced with the simple operation by the above-mentioned method and the effective dephosphorizing treatment is accomplished by using such agent.
    • 135. 发明专利
    • Dephosphorization
    • 脱磷
    • JPS59203691A
    • 1984-11-17
    • JP7600783
    • 1983-04-28
    • Kurita Water Ind Ltd
    • JIYOUKOU ISAOSAWADA SHIGEKIKANENIWA HATSUMIGOTOU CHIYUUICHI
    • C02F1/58
    • PURPOSE: To perform efficient dephosphorization while easily regenerating a crystal seed, by supporting calcium phosphate-contg. powder on a calcium phosphate-contg. crystal seed whose capacity has been deteriorated by bringing it into contact with phosphate-contg. water to perform dephosphorization.
      CONSTITUTION: Phosphate-contg. water to be treated is brought into contact with a calcium phosphate-contg. crystal seed in the presence of calcium ion under the condition of a pH of 6 or higher, to perform the depohsphorization that phosphoric ion in the water to be treated is crystallized as calcium phosphate. Whe the crystal seed used for said dephosphorization has dephosphorizing power deteriorated by making its surface inactive with magnesium and organic substance in the water to be treated, calcium phosphate-contg. powder is supported on said crystal seed to easily reactivate the crystal seed. A phosphate mineral, boneblack, granular matter having a calcium phosphate crystal on its surface, etc. may be used as said crystal seed, while hydroxiapatite, fluoroapatite, trilime phosphate, a phosphate mineral, etc. may be properly used as said calcium phosphate-contg. powder.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过支持磷酸钙来进行有效的脱磷,同时容易地再生晶种。 磷酸钙上的粉末 通过使其与磷酸盐接触而使其能力劣化的晶种。 水进行脱磷。 组成:磷酸盐contg。 待处理的水与磷酸钙接触。 在pH6以上的条件下,在钙离子存在下进行晶体晶种化,进行待处理水中的磷离子作为磷酸钙的结晶化。 用于所述脱磷的晶种通过在待处理的水中使镁和有机物质表面无活性而具有劣化的脱磷功能,即磷酸钙。 粉末被支撑在所述晶种上以容易地重新激活晶种。 可以使用磷酸盐矿物,骨炭黑,其表面上具有磷酸钙晶体的粒状物等作为所述晶种,而羟磷灰石,氟磷灰石,磷酸三磷酸盐,磷酸盐矿物等可适当地用作所述磷酸钙 - contg。 粉末。
    • 136. 发明专利
    • Apparatus for treating phosphate-containing water
    • 用于处理含磷酸盐水的装置
    • JPS59183882A
    • 1984-10-19
    • JP5525583
    • 1983-04-01
    • Kurita Water Ind Ltd
    • GOTOU CHIYUUICHIJIYOUKOU ISAOSAWADA SHIGEKI
    • C02F1/28B01D15/02
    • PURPOSE: To remove phosphate in water in extremely good efficiency, by constituting contact layers each containing a phosphate adsorbent in one or more stages in the up-and-down direction in a vertical treating tower by water passable support plates while supplying water to the lower end in the treating tower to flow the same in an upwardly directed stream.
      CONSTITUTION: A phosphate adsorbent is continuously or intermittently replenished to the uppermost stage contact layer by a supply pipe 6 and raw water is supplied to the bottom part of a tower from a water supply pipe 7 by a pump to be flowed in an upwardly directed stream while treated water is flooded over a flooding weir 12 from the upper part of the uppermost stage contact layer. In this case, the water passing linear speed of water is set to 5W30m/hr and the adsorbents of the upper stage contact layers are inhibited from mutually falling to the lower stage contact layers through a non-angle-of-repose nozzle 5 by the water upwardly flowed through the non-angle-of-repose nozzle 5. By this method, the phosphate adsorbent of each stage contact layer is fluidized in a boisterous state by the upwardly directed water stream and efficiently contacted with water to remove the phosphate in water by adsorption.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:为了以极高的效率除去水中的磷酸盐,通过在垂直处理塔中通过水通过支撑板在上下方向上形成一个或多个上下方向的磷酸盐吸附剂的接触层,同时向下部供水 在处理塔中结束以将其以向上的流流动。 构成:通过供给管6将磷酸盐吸附剂连续地或间歇地补充到最上层的接触层,并且通过泵将原水从供水管7通过泵供给到塔的底部,以向上流动的流 同时处理的水从最上层接触层的上部溢流在溢流堰12上。 在这种情况下,水的通过线速度设定为5-30m / hr,并且通过非倾斜喷嘴5阻止上层接触层的吸附剂相互落入下层接触层 通过该水向上流过非止倾喷嘴5.通过这种方法,每个阶段接触层的磷酸盐吸附剂通过向上的水流在闷热状态下流动并且与水有效接触以除去磷酸盐 在水中通过吸附。
    • 137. 发明专利
    • Artificial dephosphorizing agent and dephosphorization
    • 人工脱磷剂和脱氢剂
    • JPS59156488A
    • 1984-09-05
    • JP3157983
    • 1983-02-26
    • Kurita Water Ind Ltd
    • JIYOUKOU ISAOKANENIWA HATSUMISAWADA SHIGEKI
    • C02F1/58
    • PURPOSE: To efficiently crystallizedly remove phosphates from water, by supporting powder containing calcium phosphate such as hydroxyapatite on a supporting body containing calcium carbonate such as a fossile coral to form the titled dephosphorizing agent.
      CONSTITUTION: The interior of a tank for manufacturing a dephosphorizing agent is packed with calcium carbonate-contg. particles to form a stationary bed. The liquid suspension of powder containing calcium phosphate is cyclically circulated, until most of suspended matter is eliminated. Hence, said powder is captured in the stationary bed of the supporting body. Thereafter, phosphate- contg. water is circulated in a series or cyclically under the condition of a pH above 6, so that said powder is supported on the supporting body to obtain the artificial dephosphorizing agent. This dephosphorizing agent is brought into contact with phosphate-contg. water at a pH above 6 in the presence of Ca ion, to crystallize phosphoric ion in the form of hydroxyapatite on the dephosphorizing agent. Thus, dephosphorization is performed.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过将含磷酸钙如羟基磷灰石的粉末支撑在含有碳酸钙的支撑体如化石珊瑚上,从而有效地结晶化除去磷酸盐,形成标题脱磷剂。 构成:用于制造脱磷剂的罐的内部装有碳酸钙。 颗粒形成固定床。 含有磷酸钙的粉末的液体悬浮液循环循环,直到大部分悬浮物质被除去。 因此,所述粉末被捕获在支撑体的固定床中。 此后,磷酸盐 水在pH高于6的条件下循环循环,使得所述粉末负载在支撑体上,得到人造脱磷剂。 使该脱磷剂与磷酸盐接触。 在Ca离子存在下,pH高于6的水,在脱磷剂上结晶成羟基磷灰石形式的磷酸离子。 因此,进行脱磷。
    • 138. 发明专利
    • Dephosphorizer
    • 脱磷剂
    • JPS59150597A
    • 1984-08-28
    • JP2445483
    • 1983-02-16
    • Kurita Water Ind Ltd
    • JIYOUKOU ISAOSAWADA SHIGEKIFUKASE TETSUROUOOI MASAOSHIBATA MASAHIDE
    • C02F1/58C02F3/30
    • PURPOSE: To maintain the concentration of phosphorus in treated water constant, by providing an anaerobic tank, an aeration tank for aerobic treatment, a biological dephosphorizer having a means for the solid-liquid separation of an aerated liquid and then a tank for a phosphorus adsorbent.
      CONSTITUTION: Raw water 5 and returned sludge 6 in state mixed with each other are introduced into an anaerobic tank 1 and gently agitated therein under a condition isolated from air to perform anaerobic treatment. An aeration tank 2 is constituted in a manner such that aerobic treatment can be performed by supplying air through a sparger pipe 7, and a solid-liquid separation tank 3 is constituted in a manner such that an aerated liquid can be separated into a liquid and solid matter by precipitation. The interior of a tank 4 for a phosphorus adsorbent is packed with a phosphorus adsorbent, e.g. activated alumina, a magnesia compound, a phosphate mineral or ion-exchange resin, to form the bed of the phosphorus adsorbent. A liquid having flowed out of the solid-liquid separation tank 3 is brought into contact with the fluidized or stationary bed to adsorb or discharge phosphorus in said liquid. Thus, the concentration of phosphorus is adjusted to a constant level.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:为了保持处理水中磷的浓度不变,通过提供厌氧池,用于需氧处理的曝气池,具有用于将充气液体固液分离的装置和磷吸附剂的生物脱磷装置 。 构成:将彼此混合的原水5和返回污泥6引入厌氧池1中,并在与空气分离的条件下轻轻搅拌,进行厌氧处理。 曝气池2以能够通过喷射管7供给空气进行需氧处理的方式构成,固液分离槽3以将充气液分离成液体的方式构成, 固体物质通过降水。 用于磷吸附剂的罐4的内部装有磷吸附剂,例如磷吸附剂。 活性氧化铝,氧化镁化合物,磷酸盐矿物或离子交换树脂,以形成磷吸附剂的床。 从固液分离槽3流出的液体与流化床或固定床接触,以吸附或排出所述液体中的磷。 因此,将磷的浓度调节至恒定水平。
    • 140. 发明专利
    • FLUIDIZED-BED TYPE SEWAGE TREATING DEVICE
    • JPS588585A
    • 1983-01-18
    • JP10621781
    • 1981-07-09
    • KURITA WATER IND LTD
    • SAWADA SHIGEKIWATANABE ATSUSHI
    • C02F3/08
    • PURPOSE:To speedily accomplish a steady operation at the time of starting, by a method wherein a starting tube into which air is blown at a part of an air diffuser is provided in the interior of a lower end part along one side of a main tube, and a slit or a guide tube is provided at the outside surface of the starting tube. CONSTITUTION:For starting, air is blown into the interiors of an upward flow passage 3 and the starting tube 9 by the air diffusers 8, 8' to achieve the same linear velocity of air in both the passage 3 and the tube 9. As a result, carrier particles located beneath the parts of a stacked layer 11 to which the tube 9 and a draft tube inside a downward flow passae are faced start to be circulated along with the local circulating flow of the blown air, so that the stack begins to crumble at these parts. When the crumbling of the stack reaches the lower end part of a partition wall 9', an upward circulating flow through the passage 3 is generated, then the particles stacked at the lower parts of the passage 3 and the downward flow passage start to be circulated together with the circulating flow, resulting in the steady operating condition.