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1. 发明专利

JPH1112203A 9,9,10,10-TETRACHLORO-9,10-DIHYDROANTHRACENE COMPOUNDS AND THEIR PRODUCTION 失效
公开(公告)号：JPH1112203A
公开(公告)日：1999-01-19
申请号：JP16769197
申请日：1997-06-24
申请人： ASAHI GLASS CO LTD
发明人： TAKEBE YOKO , MUROFUSHI HIDENOBU , OKAZOE TAKASHI , KASHIWAGI KIMIAKI , TAMURA MASAYUKI
IPC分类号： C07C23/42 , C07C25/22 , C07C37/62 , C07C39/17 , C07C41/22 , C07C43/225
摘要： PROBLEM TO BE SOLVED: To obtain a new compound useful as an additive for functional materials or as the precursor of the additive. SOLUTION: A compound of formula I [R -R are each H, F, Cl, hydroxy, an alkoxy, an alkyl (a case wherein all of R -R are H, respectively, is excluded); R -R are each Cl]. For example, 1,2,3,4,5,6,7,8-octafluoro-9,9,10,10- tetrachloro-9,10-dihydroanthracene. The compound of formula I is obtained by reacting an anthracene compound of formula II (preferably 1,2,3,4,5,6,7,8- octafluoroanthraquinone) with phosphorus pentachloride and/or a compound of formula III (R is a monovalent organic group) at a temperature of 120-170 deg.C for 2-3 hr. The phosphorus pentachloride and the compound of formula III are used in amounts of 2-5 moles and 5-10 moles, respectively, per mole of the anthraquinone compound. The phosphorus pentachloride and the compound of formula III are preferably simultaneously used.

2. 发明专利

JPH04346989A FLUORINATED COMPOUND AND ITS PRODUCTION 失效
公开(公告)号：JPH04346989A
公开(公告)日：1992-12-02
申请号：JP14669391
申请日：1991-05-22
申请人： ASAHI GLASS CO LTD
发明人： MUROFUSHI HIDENOBU , KANEKO ISAMU
IPC分类号： C07D493/10 , C08F34/00 , C08F234/02 , C09D127/12
摘要： PURPOSE:To obtain a new fluorinated compound, having a cyclic structure in the main chain and capable of readily homopolymerizing or copolymerizing with other comonomers and providing an amorphous transparent fluorine- containing polymer soluble in solvents such as perfluoro(2-butyl-THF). CONSTITUTION:A fluorine-containing compound, e.g. perfluoro-(6-methyl1,4,7- trioxa-spiro[4,5]-2-decene expressed by formula I (x and Y are F, H or Cl; n is 2 or 3). The aforementioned compound is obtained by reacting a fluorine- containing compound expressed by formula II with a dehalongenating agent. Specifically, e.g. ethylene oxide expressed by formula TV is added to a compound expressed by formula III and the obtained product is then photochlorinated to provide a compound expressed by formula II (X and Y are Cl), which is subsequently dechlorinated with Zn and ZnCl2 in propanol.

3. 发明专利

JPH04255716A PRODUCTION OF PERFLUORINATED COPOLYMER 失效
公开(公告)号：JPH04255716A
公开(公告)日：1992-09-10
申请号：JP3675891
申请日：1991-02-06
申请人： ASAHI GLASS CO LTD
发明人： SUGIYAMA TOKUHIDE , MUROFUSHI HIDENOBU , NAKAMURA HIDE
IPC分类号： C08F214/18 , C08F14/18 , C08F16/32 , C08F34/00 , C08F216/12 , C08F234/02 , C08G61/00 , C08G61/12 , C08J5/18 , C08L45/00 , C08L65/00
摘要： PURPOSE:To easily polymerize a fluorine-containing amorphous polymer having arbitrary glass-transition temperature and refractive index. CONSTITUTION:The objective polymer is produced by the radical copolymerization of perfluoro(allyl vinyl ether) or perfluoro(butenyl vinyl ether) with perfluoro-2,2-dimethyl-1,3-dioxole.

4. 发明专利

JP2004093639A Optical fiber having sea-island structure 审中-公开
标题翻译：具有海岛结构的光纤
公开(公告)号：JP2004093639A
公开(公告)日：2004-03-25
申请号：JP2002251098
申请日：2002-08-29
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： MUROFUSHI HIDENOBU
IPC分类号： G02B6/00 , B29D11/00 , G02B6/02
CPC分类号： G02B6/02347 , B29D11/00663 , G02B6/02033 , G02B6/02042 , G02B6/02357 , G02B6/02361
摘要： PROBLEM TO BE SOLVED: To provide an optical transmitter with low transmission loss and broadband transmission performance. SOLUTION: An optical fiber is formed into a sea-island structure having the dispersion phase of a low-refractive-index component dispersed in the continuous phase of a high-refractive-index component. COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供具有低传输损耗和宽带传输性能的光发射机。解决方案：将光纤形成为具有分散在高折射率分量的连续相中的低折射率分量的分散相的海岛结构。版权所有（C）2004，JPO

5. 发明专利

JP2003073417A Recovery device and recovery method for fluorine- containing polymer 有权
标题翻译：含氟聚合物的恢复装置和恢复方法
公开(公告)号：JP2003073417A
公开(公告)日：2003-03-12
申请号：JP2001263596
申请日：2001-08-31
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： CHIBA KAZUNORI , MUROFUSHI HIDENOBU , HATANO HIROSHI
IPC分类号： B01D1/00 , C08F6/06
摘要： PROBLEM TO BE SOLVED: To provide a recovery device for obtaining a bulky fluorine-containing polymer by performing the operations to achieve a desired amount of a residual volatile component under a thermal stable evaporating condition in batch-wise way or continuously and draining directly or with other methods from a container after evaporating the component to a receiver, and to provide a recovery method.
SOLUTION: In the method for recovering the polymer from a fluorine- containing polymer solution, the component is heated at a temperature equal to or higher than a lowest temperature which the solution is subjected to a phase separation, equal to or higher than a boiling point and equal to or lower than a decomposition point of the component to remove by evaporating and the resulting bulky polymer is melted and drained to the receiver.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：提供一种用于通过在热稳定蒸发条件下以分批的方式进行操作以获得所需量的残留挥发性成分的操作或连续排出或直接排出或与将组分蒸发到接收器之后的容器中的其它方法，以及提供回收方法。解决方案：在从含氟聚合物溶液中回收聚合物的方法中，将组分在等于或高于溶液进行相分离的等于或高于沸点的最低温度的温度下加热并且等于或低于通过蒸发除去的组分的分解点，并将所得的大体积聚合物熔化并排出到接收器中。

6. 发明专利

JPH1112204A 9,10-DICHLOROANTHRACENE COMPOUNDS AND PRODUCTION OF 9,10-DIHALOANTHRACENE COMPOUNDS 失效
公开(公告)号：JPH1112204A
公开(公告)日：1999-01-19
申请号：JP16917097
申请日：1997-06-25
申请人： ASAHI GLASS CO LTD
发明人： TAKEBE YOKO , MUROFUSHI HIDENOBU , OKAZOE TAKASHI , KASHIWAGI KIMIAKI , TAMURA MASAYUKI
IPC分类号： C07C17/25 , C07C23/42 , C07C25/22 , C07C37/06 , C07C39/40 , C07C41/22 , C07C41/24 , C07C43/225 , C07C43/23
摘要： PROBLEM TO BE SOLVED: To obtain a new compound useful as an additive for functional materials or as the precursor of the additive. SOLUTION: A 9,10-dichloroanthracene compound of formula I [R -R are each H, F, Cl, hydroxy, an alkoxy, an alkyl (a case wherein all of R -R are H, respectively, is excluded); R -R are each Cl]. For example, 1,2,3,4,5,6,7,8- octafluoro-9,10-dichloroanthracene. The compound of formula I is obtained by reacting 1 mole of a 9,9,10,10-tetrachloro-9,10-dihydroanthracene compound of formula II (preferably 1,2,3,4,5,6,7,8-octafluoro-9,9,10,10-tetrachloro-9,10- dihydroanthraquinone) with 1-1.5 moles of a dechlorinating agent (preferably zinc) and 0.01-0.1 mole of a zinc-activating agent (preferably 1,2-dibromoethane) at 10 deg.C to the boiling point of a solvent in the solvent (preferably DMF).

7. 发明专利

JPH09316265A OPTICAL RESIN MATERIAL 失效
公开(公告)号：JPH09316265A
公开(公告)日：1997-12-09
申请号：JP13552196
申请日：1996-05-29
申请人： ASAHI GLASS CO LTD
发明人： SUGIYAMA TOKUHIDE , MUROFUSHI HIDENOBU , NARUTOMI MASAKI
IPC分类号： G02B6/00 , C08L27/12 , C08L57/00 , G02B1/04
摘要： PROBLEM TO BE SOLVED: To obtain the subject composition improved in transmission characteristics, heat resistance, etc., useful for various optical transmission materials, by irradiating a fluorine-containing polymer in a molten state with radiation. SOLUTION: This optical resin material is obtained by irradiating (A) a fluorine-containing polymer in a molten state with radiation. The component A does not substantially contain a C-H bond and is preferably an amorphous polymer, a polymer containing a cyclic structure in the main chain or a crystalline polymer. The irradiation with radiation is preferably carried out in the absence of oxygen and the dose is a value selected from a range of 0.1kGy to 10MGy.

8. 发明专利

JP2001139509A METHOD FOR PRODUCTION OF UNSATURATED COMPOUND BY THERMAL DECOMPOSITION REACTION 失效
公开(公告)号：JP2001139509A
公开(公告)日：2001-05-22
申请号：JP2000166773
申请日：2000-06-02
申请人： ASAHI GLASS CO LTD
发明人： OKAZOE TAKASHI , WATANABE KUNIO , TATEMATSU SHIN , SATO MASAKUNI , MUROFUSHI HIDENOBU
IPC分类号： C07C41/18 , C07B61/00 , C07C43/17 , C07C67/283 , C07C69/63 , C08F16/24 , C08F34/00
摘要： PROBLEM TO BE SOLVED: To produce an unsaturated compound useful as a fluoroplastic(s) raw material, etc., in a high yield in a short process. SOLUTION: A compound represented by formula (B) CF(OR2)=CR3R4, e.g. CF3CF2CF2OCF=CF2, etc., is obtained by the thermal decomposition reaction of a compound represented by formula (A) R1COOCF2CF(OR2)CXR3R4, e.g. CF3(CF3CF2CF2O)CFCOOCF2CF(OCF2CF2CF3)CF3, etc. (wherein R1, R2, R3 and R4 are each fluorine atom, a perfluoroalkyl group or a perfluoro (an ethereal oxygen-containing alkyl group); and X is a halogen atom).

9. 发明专利

JPH0625054A PURIFICATION OF FLUORINATED ETHYLENIC UNSATURATED COMPOUND 失效
公开(公告)号：JPH0625054A
公开(公告)日：1994-02-01
申请号：JP20447692
申请日：1992-07-08
申请人： ASAHI GLASS CO LTD
发明人： OHARU KAZUYA , MUROFUSHI HIDENOBU
IPC分类号： C07C41/34 , C07C43/17
摘要： PURPOSE:To efficiently purify a crude fluorinated ethylenic unsaturated compound containing its hydrogen fluoride adduct by subjecting the crude fluorinated ethylenic unsaturated compound to an extractive distillation in the presence of a specific water-soluble solvent and subsequently washing the distillation product with water. CONSTITUTION:A crude fluorinated ethylenic unsaturated compound containing the hydrogen fluoride adduct of the fluorinated ethylenic unsaturated compound and produced by the gas phase or liquid phase pyrolysis reaction of an acid fluoride is subjected to an extractive distillation in the presence of a solvent selected from alcohols (e.g. methanol, ethanol), ketones (e.g. acetone, methylethylketone) and ethers (e.g. THF, dioxane, ethylene glycol dimethyl ether), and the obtained azeotropic mixture is washed with water for the removal of the solvent to obtain the highly pure fluorinated ethylenic unsaturated compound. The method is especially suitable for the purification of fluorine- containing alpha,omega-dienic compounds giving perfectly amorphous polymers by their ring-closing polymerization.

10. 发明专利

JPH05339255A 失效
公开(公告)号：JPH05339255A
公开(公告)日：1993-12-21
申请号：JP17201292
申请日：1992-06-05
申请人： ASAHI GLASS CO LTD
发明人： OHARU KAZUYA , MUROFUSHI HIDENOBU
IPC分类号： C07D317/16
摘要： PURPOSE:To obtain a new compound useful a comonomer for synthesis of fluorine-containing polymer and a monomer for homopolymerization. CONSTITUTION:A compound of formula I (R and R are 1-7C polyfluoroalkyl or coupled 2-5C polyfluoroalkylene), e.g. perfluoro-2-methylene-4,5-dimethyl-1,3- dioxolan. The compound of formula I is obtained by subjecting a compound of formula II (X is F or OM; M is alkali metal) to vapor phase pyrolysis at 250-400 deg.C or subjecting a carboxylic acid alkali salt obtained by reacting the compound of formula II with an alkali hydroxide to pyrolysis at 150-300 deg.C. When the reaction temperature is low, the conversion efficiency becomes low and when the reaction temperature is high, the amounts of decomposition products are increased. An amorphous fluorine-containing polymer soluble in a specific solvent can be obtained by subjecting the compound of formula I to homopolymerization. A low reflective coat or thin film, etc., can be obtained by using the solution.

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