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    • 2. 发明公开
    • METHOD USING ADSORBENT
    • EP4286331A1
    • 2023-12-06
    • EP22746052.4
    • 2022-01-28
    • Mitsui Mining & Smelting Co., Ltd.
    • OSAKO TakaoKATO KazuhikoKOBAYASHI Yutaka
    • C01B33/152C01B33/157C02F1/28B01J20/22B01J20/28B01J20/34
    • An object of the present invention is to provide a novel method of recovering a metal and/or a metal ion from a liquid to be treated, by use of a monolith adsorbent, and a novel method of regenerating an adsorbent used in the method of recovering a metal and/or a metal ion from a liquid to be treated, and, in order to achieve the object, the present invention provides a method of recovering a metal and/or a metal ion, the method including the following steps of:
      (1) preparing for a solution containing a metal and/or a metal ion;
      (2) preparing for an adsorbent having a co-continuous structure formed by: a ceramic skeleton including mesopores; and macropores, wherein a surface of the ceramic skeleton is modified by a metal- and/or metal ion-adsorbable functional group, a most frequent pore diameter of the macropores before modification by the functional group is 0.20 µm or more and 4.0 µm or less, and a most frequent pore diameter of the mesopores before modification by the functional group is 2.0 nm or more and 50 nm or less;
      (3) contacting the solution and the adsorbent;
      (4) contacting the adsorbent subjected to step (3) and an acidic solution; and
      (5) recovering the metal and/or the metal ion from the acidic solution subjected to step (4).