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    • 3. 发明公开
    • A METHOD FOR CONTROLLING THE DEPOSITION OF STICKIES IN PULPING AND PAPERMAKING PROCESSES
    • 一种控制造纸和造纸过程中棒状物沉积的方法
    • EP3207175A1
    • 2017-08-23
    • EP15805108.6
    • 2015-10-15
    • Nopco Paper Technology GmbH
    • BLASING, BirgitFRIDRISCHAK, SiegmundNELLESSEN, BernhardSCHENKER, Achim
    • D21C5/02D21C9/08D21H17/13D21H17/59D21C3/00
    • D21C9/008D21C3/003D21C5/022D21C9/08D21H17/13D21H17/59Y02W30/648
    • A method for controlling the deposition of stickies in pulping and papermaking processes comprises adding to fibre pulp or stock an additive comprising an organo-modified siloxane comprising units of the formula: [R1aZbSiO(4-a-b)/2]n in which each R1 is independently selected from a hydrogen atom, an alkyl, aryl, alkenyl, aralkyl, alkaryl, alkoxy, alkanoyloxy, hydroxyl, ester or ether group, and each Z is independently selected from an alkyl group substituted with an amine, amide, carboxyl, ester, or epoxy group, or preferably at least one or more groups —R2—(OCpH2p)q(OCrH2r)S—R3; wherein n is an integer greater than 1; a and b are independently 0, 1, 2 or 3; R2 is an alkylene group or a direct bond; R3 is a group as defined for R1 or Z above; p and r are independently an integer from 1 to 6; q and s are independently 0 or an integer such that 1≦q+s≦400; and wherein each molecule of the organo-modified siloxane contains at least one group Z. The organo-modified siloxane is preferably a hydroxyl- or alkyl-endcapped linear polydimethylsiloxane, in which 5 to 18 mole percent of silicon atoms are substituted by Z groups of the formula —R2—(OCpH2p)q(OCrH2r)s—R3, in which p is 2, r is 3 and q and s are independently 10 to 20, R2 is an alkylene group having from 1 to 6 carbon atoms or a direct bond, and R3 is a hydrogen atom or a hydroxyl, alkoxy, ester or ether group.
    • 一种控制制浆和造纸过程中粘性物沉积的方法包括向纤维浆或浆中加入包含有机改性硅氧烷的添加剂,所述有机改性硅氧烷包含下式单元:[R1aZbSiO(4-ab)/ 2] n其中每个R1 烷基,芳基,烯基,芳烷基,烷芳基,烷氧基,烷酰氧基,羟基,酯或醚基,并且每个Z独立地选自被胺,酰胺,羧基,酯取代的烷基 ,或环氧基,或优选至少一个或多个基团-R2-(OCpH2p)q(OCrH2r)S-R3; 其中n是大于1的整数; a和b独立地为0,1,2或3; R2是亚烷基或直接键; R3是如上面R1或Z所定义的基团; p和r独立地为1至6的整数; q和s独立地为0或整数,使得1≤q+s≤400; 并且其中有机改性的硅氧烷的每个分子含有至少一个基团Z.有机改性的硅氧烷优选为羟基或烷基封端的线型聚二甲基硅氧烷,其中5-18摩尔%的硅原子被 其中p为2,r为3且q和s独立地为10至20,R 2为具有1至6个碳原子的亚烷基的式-R 2 - (OC p H 2p)q(OC r H 2r)s -R 3或直接 键,R3是氢原子或羟基,烷氧基,酯或醚基。