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    • 8. 发明公开
    • PESTICIDALLY ACTIVE SUBSTITUTED PYRIDYL CARBOXAMIDES
    • 杀菌剂替代吡啶甲酰胺
    • EP3119758A1
    • 2017-01-25
    • EP15710212.0
    • 2015-03-18
    • Syngenta Participations AG
    • JEANGUENAT, AndréEDMUNDS, AndrewHALL, Roger Graham
    • C07D401/14A01N43/40A01P7/04A01P7/02A01P5/00A01P9/00A01N43/56
    • C07D401/14A01N43/56A01N43/58A01N25/08
    • Compounds of formula (I) wherein m is 0 or 1; Z is methine or nitrogen; X is oxygen or sulfur, R1 is C1-C6-alkyl, halo-C1-C6-alkyl, C3-C6-cycloalkyl or C2-C6-alkynyl; R2 is C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, halo-C3-C6-cycloalkyl, fluoro, chloro or bromo; R3 is C1-C3-alkyl; R4 is hydrogen, C1-C6-alkyl, fluoro, chloro, bromo or cyano; Y is CN, COOR9 or CONHR6; n is 0, 1 or 2; R5 is hydrogen, fluoro, chloro or bromo; R6 is C1-C4-alkyl; R9 is C1-C4-alkyl; R10 and R11 are, independently from each other, hydrogen, C1-C3-alkyl or C1-C3-alkoxy; or R10 and R11 taken together form with the carbon atom to which they are bonded a C3-C6-carbocyclic ring; or R10 and R11 taken together form a ketone or a =NOR12 group; and RI2 is hydrogen or C1-C4-alkyl; and agrochemically acceptable salts and enantiomers of those compounds can be used as insecticides an can be prepared in a manner known per se.
    • 式(I)化合物,其中m为0或1; Z是次甲基或氮; X是氧或硫,R1是C1-C6-烷基,卤代-C1-C6-烷基,C3-C6-环烷基或C2-C6-炔基; R2是C1-C6-烷基,C1-C6-卤代烷基,C3-C6-环烷基,卤代-C3-C6-环烷基,氟,氯或溴; R3是C1-C3-烷基; R4是氢,C1-C6-烷基,氟,氯,溴或氰基; Y为CN,COOR9或CONHR6; n为0,1或2; R5是氢,氟,氯或溴; R6是C1-C4-烷基; R9是C1-C4-烷基; R 10和R 11彼此独立地为氢,C 1 -C 3 - 烷基或C 1 -C 3 - 烷氧基; 或者R 10和R 11与它们所连接的碳原子一起形成C 3 -C 6 - 碳环; 或R 10和R 11一起形成酮或= NOR12基团; 和R 2是氢或C 1 -C 4 - 烷基; 并且这些化合物的农业化学上可接受的盐和对映异构体可以用作杀虫剂,可以以本身已知的方式制备。