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    • 3. 发明公开
    • CONTAMINATION-PROOF ION GUIDE FOR MASS SPECTROMETRY
    • KONTAMINATIONSSICHEREIONENFÜHRUNGFÜRMASSENSPEKTROMETRIE
    • EP3032569A1
    • 2016-06-15
    • EP15195298.3
    • 2015-11-19
    • Bruker Daltonics, Inc.
    • Kaplan, Desmond AllenMuntean, FelicianZanon, Stephen
    • H01J49/06H01J49/42
    • H01J49/063H01J49/421
    • The invention relates to a radio frequency ion guide construction for use in mass spectrometry that minimizes contamination by allowing ions rejected by the RF confinement field to fly through and away from the ion guide electrodes and preventing them from hitting the sensitive electric potential defining surfaces of the ion guide electrodes. At the entrance end of the ion guide, each electrode of the plurality of electrodes has a front end that is forked or that contains a recessed feature facing an interior of the ion guide. For an electrode that is forked, the teeth of the forked end may have different shapes or tapers, and a conductive mesh may be used to cover a gap between the teeth. Similarly, for an electrode that has a recessed feature, a conductive mesh may cover the recessed feature.
    • 本发明涉及一种用于质谱分析的射频离子导向结构,其通过允许由RF限制场所排斥的离子飞过和离开离子导向电极并使其不受打击敏感电位限定表面的影响而使污染最小化 离子导向电极。 在离子导向器的入口端处,多个电极的每个电极具有分叉的前端或包含面向离子导向件内部的凹陷特征。 对于分叉的电极,叉形端部的齿可以具有不同的形状或锥度,并且可以使用导电网来覆盖齿之间的间隙。 类似地,对于具有凹陷特征的电极,导电网可以覆盖凹陷特征。
    • 6. 发明公开
    • MASS ANALYSIS DEVICE AND MASS SEPARATION DEVICE
    • MASSENANALYSEVORRICHTUNG MASSENENENYUNGSVORRICHTUNG
    • EP2924711A1
    • 2015-09-30
    • EP13840677.2
    • 2013-09-24
    • Sano, Yoshinori
    • Sano, Yoshinori
    • H01J49/06G01N27/62H01J49/26
    • H01J49/401G01N27/62H01J49/0086H01J49/061H01J49/067H01J49/408H01J49/421
    • Provided are a mass analysis device and a mass separation device which are each capable of repeatedly analyzing or extracting a plurality of ion species having different mass-to-charge ratios in a short time with less restriction on the design and performance of the device by problems arising from the principle of operation and with no limitation on the mass-to-charge ratio range that can be dealt with in principle. A mass analysis device (10) is configured from an ion source (1), an ion introduction unit (2), a mass separation unit (3), an ion detection unit (4), and the like. An ion group is introduced into a separation space (5) at a predetermined acceleration voltage as a pulse synchronized with the phase of a one-dimensional high-frequency electric field. In the separation space (5), ions fly by inertia in an incidence direction, and are displaced in a y-direction by force received from the one-dimensional high-frequency electric field that acts in the direction (y-direction) crossing the incidence direction. Ion species having different mass-to-charge ratios from each other are separated by the difference in displacement amount. At this time, the acceleration voltage and the period of the one-dimensional high-frequency electric field are set such that an ion species to be measured is emitted from the separation space (5) after being subjected to the action of the electric field for one period.
    • 提供一种质量分析装置和质量分离装置,它们能够在短时间内反复分析或提取具有不同质荷比的多种离子种类,同时通过问题对装置的设计和性能的限制较少 源于运作原则,而不限于原则上可以处理的质量比率范围。 质量分析装置(10)由离子源(1),离子引入单元(2),质量分离单元(3),离子检测单元(4)等构成。 离子组以与一维高频电场的相位同步的脉冲以预定的加速电压被引入到分离空间(5)中。 在分离空间(5)中,离子沿着入射方向通过惯性飞行,并且由从一维高频电场接收的力沿y方向移位,所述一维高频电场沿着与 发病方向。 具有彼此不同的质荷比的离子物质由位移量的差异分开。 此时,一维高频电场的加速电压和周期被设定为使得在经受电场作用后从分离空间(5)发射待测量的离子种类 一个时期