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    • 8. 发明公开
    • TRICATIONIC DYES
    • TRICATIONIC染料
    • EP2029674A2
    • 2009-03-04
    • EP07729830.5
    • 2007-06-04
    • Ciba Holding Inc.
    • CREMER, ChristianWALLQUIST, OlofELIU, Victor PaulNIVALKAR, Kishor Ramachandra
    • C09B23/14C09B26/04C09B44/00C09B44/08C09B44/12C09B44/16C09B55/00C09B69/00A61K8/49A61Q5/10
    • A61Q5/10A61K8/49A61K8/4926A61K8/4946A61K8/4966C09B23/145C09B26/04C09B44/005C09B44/08C09B44/126C09B44/16C09B55/002C09B55/004C09B69/001
    • Disclosed are compounds of formula (I); wherein D is an aromatic or a cationic heteroaromatic group, which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, hydroxy-C1-C14alkyl, C3-C8cycloalkyl, -CN, NO2, -NR3R4, halogen, C6-C10aryl, which is optionally substituted or C1-C14alkyl, or by one or more groups Z; E1 and E2 independently from each other are =CH; or =N-; K is an aromatic or heteroaromatic group which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, NO2, -NR3R4, -N(R3)(CO)R4, -SO2NR1R2, -SONR1R2 or by one or more Z; or a radical of formula -NR1R2; R1 and R2 independently from each other are hydrogen; C1-C14alkyl; cyclo-C1-C14alkyl; C6- C10aryl; an aromatic or heteroaromatic group which is optionally substituted by C1- C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, -NR5R6, -N(R5)-(CO)R5 or by Z; Z is a group of the formula (1 a) *- X1-Y1-W1, wherein X1 is the direct bond; -NR7-; -0-; -NR7(C=O)-; -(CO)NR7-; -0(C=O)-; -(CO)O-; or -(C=O)-; Y1 is the direct bond; C1-C12alkylene, which is optionally interrupted by -0-, -NR8, -S-, -(C=O)-, -0(C=O)-, (C=O)O-, -NR7(C=O)-, -(C=O)NR7-, and which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, -NR9R10 or halogen; or C6-C10arylene, which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, amino or halogen; W1 is a cationic group; and R3, R4, R5, R6, R7, R8, R9 and R10 independently from each other are hydrogen; C1-C14alkyl; or Z; and An1-, An2- and An3- independently from each other are an anion. The compounds are useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, more preferably human hair.
    • 公开了式(I)的化合物; 其中D为任选被C 1 -C 14烷基,C 1 -C 14烷氧基,羟基-C 1 -C 14烷基,C 3 -C 8环烷基,-CN,NO 2,-NR 3 R 4,卤素,C 6 -C 10芳基取代的芳族或阳离子杂芳族基团, 任选取代的或C 1 -C 14烷基,或被一个或多个基团Z取代; E1和E2彼此独立地是= CH; 或= N-; K是任选被C1-C14烷基,C1-C14烷氧基,C3-C8环烷基,C6-C10芳基,卤素,羟基,NO2,-NR3R4,-N(R3)(CO)R4,-SO2NR1R2, -SONR1R2或一个或多个Z; 或式-NR 1 R 2的基团; R1和R2彼此独立地为氢; C1-C 1-4烷基; 环C1-C 1-4烷基; C 6 -C 10芳基; 任选被C 1 -C 14烷基,C 1 -C 14烷氧基,C 3 -C 8环烷基,C 6 -C 10芳基,卤素,羟基,-NR 5 R 6,-N(R 5) - (CO)R 5或被Z取代的芳族或杂芳族基团; Z是式(1a)* - X1-Y1-W1的基团,其中X1是直接键; -NR7-; -0-; -NR7(C = O) - ; - (CO)NR 7 - ; -O(C = O) - ; - (CO)O-; 或 - (C = O) - ; Y1是直接债券; (C = O) - , - O(C = O) - ,(C = O)O-,-NR 7(C = O) O) - , - (C = O)NR 7 - ,并且其可以被C 1 -C 14烷基,羟基-C 1 -C 14烷基,羟基,-NR 9 R 10或卤素取代; 或可被C1-C14烷基,羟基-C1-C14烷基,羟基,氨基或卤素取代的C6-C10亚芳基; W1是阳离子基团; 并且R3,R4,R5,R6,R7,R8,R9和R10彼此独立地为氢; C1-C 1-4烷基; 或Z; An1-,An2-和An3-彼此独立地是阴离子。 该化合物可用于染色有机材料,如含角蛋白的纤维,羊毛,皮革,丝,纤维素或聚酰胺,特别是含角蛋白的纤维,棉或尼龙,更优选人的头发。