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    • 3. 发明公开
    • POLYMERIC HAIR DYES
    • 高分子染发剂
    • EP2235115A1
    • 2010-10-06
    • EP09702426.9
    • 2009-01-07
    • BASF SE
    • MARQUAIS-BIENEWALD, SophieCREMER, ChristianWALLQUIST, OlofFRÖHLING, Beate
    • C09B69/10A61K8/72A61Q5/00
    • C09B69/106A61K8/8152A61K8/817A61K8/84A61K2800/4322A61Q5/065C09B69/107
    • Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from -C1-C30alkylene- or -C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one -S-, -N-, -N=-, -N(R5)-, -S(O)-, -SO2-, -(CH2CH2-O)1-5-, -(CH2CH2CH2-O)1-5-, -C(O)-, -C(O)O-, -OCO-, (II), -CON(R1)-, -C(NR1R2)2-, -(R1)NC(O)-, -C(S)R1-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1- C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a
    • 9. 发明公开
    • STYRYL SULFIDE DYES
    • STYRYL SULFIDE染料
    • EP3041904A1
    • 2016-07-13
    • EP14755839.9
    • 2014-08-28
    • BASF SE
    • BACHMANN, FrankCREMER, ChristianKNOBLOCH, MarkusFRÖHLING, BeateSPECKER, Werner
    • C09B23/14A61Q5/10A61K8/49
    • C09B23/145A61K8/4926A61Q5/10C07D213/56C07D401/14
    • Disclosed are styryl dyes of formula wherein R1, R2, R3, R′1, R′2 and R′3 independently of each other are hydrogen; —NH(CO)—C1-C5alkyl; —N(C1-C5alkyl)(C1-C5alkyl-CN); C1-C6alkoxy; a heterocyclic radical; or R1 and R2 or R′1 and R′2 together form a 5- to 10-membered, monocyclic, carbocyclic or heterocyclic ring; wherein at least one of R1, R2, R3, R′1, R′2 and R′3 is different from hydrogen; Q and Q′ independently from each other are the direct bond; *—C(O)—*; *—C(O)O—*; *—OCO—*; *—N(R4)—*; *—C(O)N(R6)—*; or *—(R6)NC(O)—*; and R4, R5 and R6 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C12aryl; C6-C12aryl-C1-C10alkyl; or C1-C10alkyl(C5-C12aryl); X and X′ are *—(CH2)m—*; Y1 and Y2 independently from each other are C1-C10alkylene; C6-C10cycloalkylene; C5-C12arylene; or C6-C12arylene-(C1-C10alkylene); An− is an anion; m is a number from 1 to 8; n is 0, or 1; and p is 0, or 1.
    • 公开了式(1)的苯乙烯基染料,其中R 1,R 2,R 3,R'1,R'2和R'3彼此独立地为氢; -NH(CO)-C 1 -C 5烷基; -N(C 1 -C 5烷基)(C 1 -C 5烷基-CN); C 1 -C 6烷氧基; 杂环基团; 或R 1和R 2或R'1和R'2一起形成5至10元单环碳环或杂环; 其中R 1,R 2,R 3,R'1,R'2和R'3中的至少一个不同于氢; Q和Q'彼此独立的是直接债券; * -C(O) - *; * -C(O)O- *; * -OCO- *; * -N(R 4) - *; (AA); * -C(O)N(R 6) - *; 或* - (R 6)NC(O) - *; 并且R 4,R 5和R 6彼此独立地为氢; C 1 -C 14烷基; C 2 -C 14链烯基; C 6 -C 12芳基; C 6 -C 12芳基-C 1 -C 10烷基; 或C 1 -C 10烷基(C 5 -C 12芳基); X和X'是* - (CH 2)m- *; Y 1和Y 2彼此独立地为C 1 -C 10亚烷基; C 5 -C 10亚环烷基; C 5 -C 12亚芳基; 或C 5 -C 12亚芳基 - (C 1 -C 10亚烷基); An - 是一个阴离子; m是1至8的数字; n是0或1; 并且p是0或1。