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    • 3. 发明公开
    • POLYMERIC HAIR DYES
    • 高分子染发剂
    • EP2235115A1
    • 2010-10-06
    • EP09702426.9
    • 2009-01-07
    • BASF SE
    • MARQUAIS-BIENEWALD, SophieCREMER, ChristianWALLQUIST, OlofFRÖHLING, Beate
    • C09B69/10A61K8/72A61Q5/00
    • C09B69/106A61K8/8152A61K8/817A61K8/84A61K2800/4322A61Q5/065C09B69/107
    • Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from -C1-C30alkylene- or -C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one -S-, -N-, -N=-, -N(R5)-, -S(O)-, -SO2-, -(CH2CH2-O)1-5-, -(CH2CH2CH2-O)1-5-, -C(O)-, -C(O)O-, -OCO-, (II), -CON(R1)-, -C(NR1R2)2-, -(R1)NC(O)-, -C(S)R1-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1- C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a
    • 4. 发明公开
    • STYRYL SULFIDE DYES
    • STYRYL SULFIDE染料
    • EP3041904A1
    • 2016-07-13
    • EP14755839.9
    • 2014-08-28
    • BASF SE
    • BACHMANN, FrankCREMER, ChristianKNOBLOCH, MarkusFRÖHLING, BeateSPECKER, Werner
    • C09B23/14A61Q5/10A61K8/49
    • C09B23/145A61K8/4926A61Q5/10C07D213/56C07D401/14
    • Disclosed are styryl dyes of formula wherein R1, R2, R3, R′1, R′2 and R′3 independently of each other are hydrogen; —NH(CO)—C1-C5alkyl; —N(C1-C5alkyl)(C1-C5alkyl-CN); C1-C6alkoxy; a heterocyclic radical; or R1 and R2 or R′1 and R′2 together form a 5- to 10-membered, monocyclic, carbocyclic or heterocyclic ring; wherein at least one of R1, R2, R3, R′1, R′2 and R′3 is different from hydrogen; Q and Q′ independently from each other are the direct bond; *—C(O)—*; *—C(O)O—*; *—OCO—*; *—N(R4)—*; *—C(O)N(R6)—*; or *—(R6)NC(O)—*; and R4, R5 and R6 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C12aryl; C6-C12aryl-C1-C10alkyl; or C1-C10alkyl(C5-C12aryl); X and X′ are *—(CH2)m—*; Y1 and Y2 independently from each other are C1-C10alkylene; C6-C10cycloalkylene; C5-C12arylene; or C6-C12arylene-(C1-C10alkylene); An− is an anion; m is a number from 1 to 8; n is 0, or 1; and p is 0, or 1.
    • 公开了式(1)的苯乙烯基染料,其中R 1,R 2,R 3,R'1,R'2和R'3彼此独立地为氢; -NH(CO)-C 1 -C 5烷基; -N(C 1 -C 5烷基)(C 1 -C 5烷基-CN); C 1 -C 6烷氧基; 杂环基团; 或R 1和R 2或R'1和R'2一起形成5至10元单环碳环或杂环; 其中R 1,R 2,R 3,R'1,R'2和R'3中的至少一个不同于氢; Q和Q'彼此独立的是直接债券; * -C(O) - *; * -C(O)O- *; * -OCO- *; * -N(R 4) - *; (AA); * -C(O)N(R 6) - *; 或* - (R 6)NC(O) - *; 并且R 4,R 5和R 6彼此独立地为氢; C 1 -C 14烷基; C 2 -C 14链烯基; C 6 -C 12芳基; C 6 -C 12芳基-C 1 -C 10烷基; 或C 1 -C 10烷基(C 5 -C 12芳基); X和X'是* - (CH 2)m- *; Y 1和Y 2彼此独立地为C 1 -C 10亚烷基; C 5 -C 10亚环烷基; C 5 -C 12亚芳基; 或C 5 -C 12亚芳基 - (C 1 -C 10亚烷基); An - 是一个阴离子; m是1至8的数字; n是0或1; 并且p是0或1。
    • 8. 发明授权
    • SULFIDE DYES
    • 硫化染料
    • EP1893694B1
    • 2010-11-17
    • EP06777319.2
    • 2006-06-14
    • BASF SE
    • CREMER, ChristianWALLQUIST, Olof
    • C09B1/00
    • C09B1/002A61K8/355A61K8/46A61K8/4946A61Q5/065C09B1/207
    • Disclosed are compounds of formula. Method of dyeing keratin-containing fibers comprising treating the fiber with at least one sulfide dye of formula (1), their salts, isomers, hydrates and other solvates, wherein R1, R2, R3 and R4 independently from each other are hydrogen; C1-C20alkyl; C1-C20alkoxy; C3-C6cycloalkyl; halogen; NO2; OH; SH; or a radical of formula (1a) wherein R5 is hydrogen; or C1-C20alkyl; R6, R7 and R8 independently from each other are hydrogen, C1-C20alkyl, C4-C12cycloalkyl, C6-C13aralkyl; phenyl- C1-C5alkyl; or R6 and R7 together with the linking nitrogen atom form a C4-C12-membered heterocyclic ring which may be interrupted by one or more than one- O- or -NH- goups; Y1 is C1-C10alkylene; C5-C10cycloalkylene; C5-C10arylene; or C5-C10arylene-( C1-C10alkylene); T1 is a radical of formula (1b); or -O-(X3)s; Q1 is a cationic biradical of a saturated, aromatic or heteroaromatic group; or a radical of formula (1c); Z1 is -C(O)-; -(CH2CH2-O)1-5-; -C(O)O-; -OCO-; CON(R9)-; -X4-CON(R9)-; -(R9)NC(O)-; - O-; -S-; -S(O)-; or -S(O)2-; R9, R10 and R11 each independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl- C1-C10alkyl; or C1-C10alkyl(C5-C10aryl); X1, X2, X3 and X4 independently from each other are C1-C18alkylene; -(CO)- C1-C18alkylene, C1-C18arylene; C6-C18arylene- C1-C12alkylene; or -(OCH2CH2)n-O-; n is a number from 1 to 5; p, r, s, t and u independently from each other are a 0 or 1; m is 1; or 2; U is hydrogen, if m is 1; and U is the direct bond, if m is 2. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair. The dyes are distinguished by deep dying having good fastness properties with respect to washing, light, shampooing and rubbing.