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    • 10. 发明公开
    • HOLLOW FIBER MEMBRANE AND HOLLOW FIBER MEMBRANE MODULE
    • HOHLFASERMEMBRAN UND HOHLFASERMEMBRANMODUL
    • EP3187249A4
    • 2017-08-16
    • EP15836260
    • 2015-08-21
    • MITSUBISHI CHEM CORP
    • SHIBATA NORITAKATAKAYANAGI KENJIRO
    • B01D69/08B01D63/02B01D69/02B01D69/10B01D69/12B01D71/24B01D71/26B01D71/28B01D71/40B01D71/44B01D71/80
    • B01D69/02B01D53/228B01D69/043B01D69/08B01D69/12B01D71/24B01D71/26B01D71/28B01D71/80B01D2325/22B01D2325/24C08L23/12C08L25/06C08L67/02C08L2207/04C08L2207/062
    • The invention provides a hollow fiber membrane exhibits favorable gas permeation performance and excellent heat resistance and in which the generation of pinholes are suppressed, and a hollow fiber membrane module using the same. The hollow fiber membrane having a gas permeable nonporous layer; and a porous supporting layer to support the nonporous layer formed of a thermoplastic elastomer having a DSC melting peak temperature of 130°C or higher and a rupture elongation prescribed in ISO 37 (2010) of 300% or more. The nonporous layer is formed of a composition containing a styrene-based thermoplastic elastomer (I) containing at least either of an ABA type styrene-based thermoplastic elastomer (±) having a polystyrene portion (A) and a poly-conjugated diene portion (B) or a hydrogenated product (±h) of the ABA type styrene-based thermoplastic elastomer (±) and a polyolefin (II), wherein the poly-conjugated diene portion (B) contains at least either of a 1,2-bonding unit or a 3,4-bonding unit, wherein a total amount of the 1,2-bonding unit and the 3,4-bonding unit is 50% by mole or more with respect to a total amount of the entire units constituting the poly-conjugated diene portion (B).
    • 本发明提供一种中空纤维膜和具有该中空纤维膜膜的中空纤维膜组件,该中空纤维膜呈现良好的气体渗透性能和优异的耐热性,并且其中抑制了针孔的产生。 该中空纤维膜具有气体可渗透的无孔层; 以及多孔性支撑层,用于支撑由DSC熔融峰值温度为130℃以上且ISO37(2010)中规定的断裂伸长率为300%以上的热塑性弹性体形成的无孔层。 无孔层由包含苯乙烯类热塑性弹性体(I)和苯乙烯类热塑性弹性体(I)的组合物形成,所述苯乙烯类热塑性弹性体(I)包含具有聚苯乙烯部分(A)和聚共轭二烯部分(B)的ABA型苯乙烯类热塑性弹性体(±) )或ABA型苯乙烯类热塑性弹性体(±)和聚烯烃(II)的氢化产物(±h),其中聚 - 共轭二烯部分(B)至少含有1,2-键合单元 或3,4-键合单元,其中所述1,2-键合单元和所述3,4-键合单元的总量相对于构成所述聚合物单元的全部单元的总量为50摩尔%以上, 共轭二烯部分(B)。