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    • 8. 发明公开
    • CURABLE ORGANOSILOXANE OLIGOMER COMPOSITIONS
    • 可固化的有机硅氧烷低聚物组合物
    • EP3090008A1
    • 2016-11-09
    • EP14876642.1
    • 2014-12-22
    • 3M Innovative Properties Company
    • KUMAR, KantaWOLTER, James T.
    • C08G77/24C08G77/08C08G77/42C08F283/12C08F299/08
    • C08G77/44C08G77/08C08G77/24C08K5/31C08K5/5399C08L83/00C08L83/08C09D183/10C09J7/401C09J2201/606C09J2483/005
    • A curable composition including (a) at least one organosiloxane compound, fluorinated organosiloxane compound, or combination thereof having reactive silane functionality including at least two hydroxysilyl moieties; (b) at least one organosiloxane oligomer, fluorinated organosiloxane oligomer, or combination thereof having reactive silane functionality including at least two hydrosilyl moieties; and (c) a catalyst composition including (1) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof, and (2) at least one Lewis acid. At least one of the components (a) and (b) has an average reactive silane functionality of at least three, and the composition is substantially free of organic solvent(s). An alkoxysilane compound may be optionally included in the curable composition. A process for coating the composition to prepare articles having the cross-linked composition on at least a portion of at least one major substrate surface is also disclosed.
    • 一种可固化组合物,其包含(a)至少一种有机硅氧烷化合物,氟化有机硅氧烷化合物或其组合,其具有包括至少两个羟基甲硅烷基部分的反应性硅烷官能团; (b)至少一种具有包括至少两个氢化甲硅烷基部分的反应性硅烷官能团的有机硅氧烷低聚物,氟化有机硅氧烷低聚物或其组合; 和(c)催化剂组合物,其包含(1)至少一种选自脒,胍,磷腈,环丙烷磷杂环庚烷及其组合的碱和(2)至少一种路易斯酸。 组分(a)和(b)中的至少一种具有至少三种平均反应性硅烷官能度,并且该组合物基本上不含有机溶剂。 烷氧基硅烷化合物可以任选地包含在可固化组合物中。 还公开了涂布组合物以制备在至少一个主要基材表面的至少一部分上具有交联组合物的制品的方法。