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1. 发明授权

EP2933286B1 PHENOLIC RESIN FOAM AND METHOD FOR PRODUCING SAME 有权
公开(公告)号：EP2933286B1
公开(公告)日：2018-07-11
申请号：EP13861717.0
申请日：2013-12-10
申请人： Asahi Kasei Construction Materials Corporation
发明人： MUKAIYAMA Shigemi
IPC分类号： C08J9/14
CPC分类号： C08J9/141 , C08G8/10 , C08J9/0061 , C08J2203/14 , C08J2203/182 , C08J2205/052 , C08J2361/10
摘要： A purpose of the present invention is to provide a phenolic resin foam having low initial thermal conductivity and retaining low thermal conductivity for a long period. The present invention is a phenolic resin foam including a hydrocarbon having a carbon number of 6 or less and a density of the phenolic resin foam is 10 kg/m 3 or more and 150 kg/m 3 or less, in which, in the phenolic resin foam, the hydrocarbon having a carbon number of 6 or less includes 40 mol % to 90 mol % of cyclopentane and 60 mol % to 10 mol % of one or two or more types selected from hydrocarbons having a boiling point of -50°C to 5°C; and the average boiling point X of the hydrocarbon having a carbon number of 6 or less is 5°C to 44°C and the content Y of the hydrocarbon having a carbon number of 6 or less in the phenolic resin foam is 0.25 mol to 0.9 mol per of 22.4×10 -3 m 3 space volume in the phenolic resin foam.

2. 发明公开

EP3126435A1 CONDENSED TANNIN-BASED FOAMS 审中-公开
标题翻译：凝结的以鞣剂为基础的泡沫
公开(公告)号：EP3126435A1
公开(公告)日：2017-02-08
申请号：EP15715635.7
申请日：2015-03-31
申请人： E. I. du Pont de Nemours and Company
发明人： SUNKARA, Hari Babu , POLADI, Raja Hari
IPC分类号： C08J9/14 , C08J9/00 , B32B5/18
CPC分类号： C08J9/141 , C08J9/0061 , C08J9/145 , C08J9/149 , C08J2203/14 , C08J2203/142 , C08J2203/182 , C08J2205/052 , C08J2205/10 , C08J2361/10 , C08J2397/00 , C08L97/00
摘要： Disclosed are condensed tannin-based foams comprising a formaldehyde-free polymeric phase defining a plurality of open cells and a plurality of closed cells, wherein the formaldehyde-free polymeric phase comprises an acid catalyzed tannin-based resin derived from a surface-active condensed tannin, a formaldehyde-free tannin-reactive monomer, a saturated or an unsaturated organic anhydride, a polyamine, an ethoxylated castor oil, and an optional plasticizer. Also disclosed are mixed tannin-phenolic foams and methods of making thereof.
摘要翻译：公开了包含限定多个开孔和多个闭孔的不含甲醛的聚合相的缩合单宁基泡沫，其中所述不含甲醛的聚合相包含酸催化的单宁基树脂，所述单宁基树脂衍生自表面活性缩合单宁，不含甲醛的单宁反应性单体，饱和或不饱和有机酸酐，多胺，乙氧基化蓖麻油和任选的增塑剂。还公开了混合丹宁 - 酚醛泡沫体及其制造方法。

3. 发明公开

EP2963081A4 PHENOLIC RESIN FOAM BOARD, AND METHOD FOR MANUFACTURING SAME 有权
标题翻译：酚醛泡沫板及其生产方法
公开(公告)号：EP2963081A4
公开(公告)日：2016-12-07
申请号：EP14757793
申请日：2014-02-26
申请人： ASAHI KASEI CONSTRUCTION MAT CORP
发明人： KURODA TAKAYUKI , MIHORI HISASHI , KITAGAWA TAKATOSHI
IPC分类号： C08J9/12 , B05B1/20 , B05B7/32 , B29C44/30 , B29C44/46 , B29C44/56 , C08J9/14 , C08J9/36
CPC分类号： C08J9/141 , B05B1/20 , B05B7/32 , B29C44/30 , B29C44/461 , B29C44/5654 , B29K2065/00 , B29K2995/0063 , C08J9/36 , C08J2201/026 , C08J2203/14 , C08J2203/142 , C08J2203/182 , C08J2205/052 , C08J2361/02 , C08J2361/10
摘要： The present invention provides a phenolic resin foam board, which exhibits sufficient compression strength and heat conductivity for practical use even if a product has an increased thickness, and has excellent dimensional stability as compared with a conventional product. The present invention is a phenolic resin foam board having a thickness of 40 mm or more to 300 mm or less, when the phenolic resin foam board is sliced, from one main surface of the phenolic resin foam board, along the main surface into n pieces (n ‰¥ 5) at approximately equal intervals of 8 mm or more to 10 mm or less in a thickness direction, a density of an n-th specimen is d n , an average density of n pieces of specimens is d ave , a lowest density among the densities of n pieces of specimens is d min , 0 ‰¤ (d ave - d min ) / d ave ‰¤ 0.12 is established, and when values for D i = (d i + d (i + 1) ) / 2 are calculated [in which i represents an integer of 1 to (n-1)], D i values are plotted in order of a numerical value of i (in which a horizontal axis indicates i values and a vertical axis indicates D i values), and points corresponding to the D i values are connected, resulting in a density distribution curve, no straight line parallel to the horizontal axis intersects the density distribution curve at four points.
摘要翻译：本发明提供了一种酚醛树脂发泡板，即使产品具有增加的厚度，其表现出足够的压缩强度和导热性，与常规产品相比具有优异的尺寸稳定性。本发明是将酚醛树脂泡沫板从酚醛树脂发泡板的一个主面沿着主表面切割成n个片，将厚度为40mm以上且300mm以下的酚醛树脂发泡体板（n‰¥5），在厚度方向上大致相等的间隔为8mm以上至10mm以下，第n个试样的密度为dn，n个试样的平均密度为d ave，最低 n个样本密度的密度为d min，建立了0‰¤（d ave - d min）/ d‰‰0.12，当D i =（di + d（i + 1））/ 2（其中i表示1到（n-1）的整数]，D i值以i的数值的顺序绘制（其中横轴表示i值，纵轴表示D i值），并且与D i值相对应的点被连接，导致密度分布曲线，不平行于水平轴的直线相交密度分布曲线在四点。

4. 发明公开

EP2994503A4 FOAM COMPOSITES 有权
标题翻译：复合泡沫塑料
公开(公告)号：EP2994503A4
公开(公告)日：2016-09-28
申请号：EP14794867
申请日：2014-05-07
申请人： XFLAM PTY LTD
发明人： BRACEGIRDLE WREN , MONTI MICHAEL , SMYTH GORDON , CLARKE STEPHEN , MCMILLAN STEPHEN , GLYNN JULIAN , ORPIN MURRAY
IPC分类号： C08J9/236 , B29C44/04 , C08J9/32 , C08J9/35 , C08L25/06 , C08L61/10
CPC分类号： C08J9/0061 , C08G8/10 , C08J9/0066 , C08J9/009 , C08J9/232 , C08J9/236 , C08J9/32 , C08J9/35 , C08J2203/22 , C08J2300/22 , C08J2325/06 , C08J2327/06 , C08J2327/08 , C08J2333/04 , C08J2333/20 , C08J2339/08 , C08J2361/10 , C08J2371/10 , C08J2425/06 , C08J2461/10 , C08L25/06 , C08L61/06 , C09K21/14
摘要： Polystyrene-phenolic foam composites and precursor compositions are disclosed. The composites exhibit excellent flame resistance properties and may be suitably prepared in standard expanded polystyrene processing equipment.

5. 发明授权

EP2743312B1 FOAMABLE RESOL-TYPE PHENOL RESIN MOLDING MATERIAL AND PHENOL RESIN FOAM 有权
标题翻译：膨胀形式的材料的可熔型酚醛树脂和酚醛泡沫
公开(公告)号：EP2743312B1
公开(公告)日：2016-06-15
申请号：EP12821863.3
申请日：2012-08-07
申请人： ASAHI YUKIZAI CORPORATION
发明人： YAMADA, Shuji , UEDA, Yasuhiro
IPC分类号： C08J9/14 , C08J9/00 , C08L61/06 , C08L83/04 , C08K5/5419 , C08K5/34
CPC分类号： C08J9/0061 , B32B5/022 , B32B5/245 , B32B13/045 , B32B15/046 , B32B21/047 , B32B2266/0285 , B32B2266/08 , B32B2307/304 , B32B2307/3065 , B32B2307/50 , B32B2307/714 , B32B2307/726 , B32B2307/734 , C08J9/0023 , C08J9/0028 , C08J9/0033 , C08J9/0042 , C08J9/0066 , C08J9/0095 , C08J9/145 , C08J2201/022 , C08J2201/026 , C08J2203/142 , C08J2205/046 , C08J2205/052 , C08J2361/10 , C08J2483/04 , C08K5/3477 , C08L61/06 , C08L83/04 , C08L61/12
摘要： Providing a foamable resol-type phenolic resin forming material that gives a phenolic resin foam product which is excellent in flame retardancy, fireproofness, and long-term stability of thermal insulation property, suffers from a reduced amount of dimensional change during its formation, has an improved strength and improved brittleness, absorbs less water and has a higher pH than conventional foam products, thereby exhibiting an excellent property of preventing corrosion of a contact member. Also providing the phenolic resin foam product having such properties. The foamable resol-type phenolic resin forming material comprises at least a liquid resol-type phenolic resin, a blowing agent, and an acid curing agent, further comprises a nitrogen-containing bridged cyclic compound and a silicone oil as additives, and the blowing agent is a chloropropane.

6. 发明公开

EP0677380A3 Fireproof panel and a method for its manufacture 失效
标题翻译：耐火板和它们的制备方法。
公开(公告)号：EP0677380A3
公开(公告)日：1996-01-24
申请号：EP94202814.3
申请日：1994-09-29
申请人： EUROCOMPOSITI S.r.l.
发明人： Lusardi, Adriano
IPC分类号： C08J5/04 , C08J5/24 , B32B27/04 , B32B27/42 , B32B3/12 , B32B5/28 , B32B15/20
CPC分类号： B32B15/14 , B32B3/12 , B32B5/26 , B32B15/20 , B32B17/04 , B32B17/067 , B32B17/10055 , B32B27/04 , B32B2038/0076 , B32B2260/021 , B32B2260/046 , B32B2262/101 , B32B2262/105 , B32B2307/3065 , B32B2307/718 , B32B2309/022 , B32B2309/025 , C08J5/043 , C08J2361/10 , E04B1/942 , Y10S428/92 , Y10S428/921
摘要： A fireproof panel is described which comprises at least one sheet including a layer of glass fibres impregnated with at least one fireproof resin free from solvent. A method for the manufacture of this panel is also described and includes the successive steps of distributing a fireproof resin in the form of a powder free from solvents on a layer of glass fibres, subjecting the latter to a first compression and heating step to soften the resin and to a second compression and heating step to cross-link the resin and form the said sheet.

7. 发明授权

EP0084681B1 Process for producing particulate novolac resins and aqueous dispersions 失效
标题翻译：生产颗粒状NOVOLAC树脂和水性分散体的方法
公开(公告)号：EP0084681B1
公开(公告)日：1985-10-23
申请号：EP82112071.4
申请日：1982-12-28
申请人： UNION CARBIDE CORPORATION
发明人： Kopf, Peter William
IPC分类号： C08G8/10 , C08L61/10 , C08J3/02
CPC分类号： C08J3/16 , C08G8/04 , C08J2361/10

8. 发明授权

EP2898005B1 PHENOLIC FOAM 有权
标题翻译：酚醛泡沫
公开(公告)号：EP2898005B1
公开(公告)日：2017-11-01
申请号：EP13762869.9
申请日：2013-09-18
申请人： Kingspan Holdings (IRL) Limited
发明人： ROCHEFORT, Malcolm , RIPLEY, Lynne , HOLLAND, Philip , COPPOCK, Vincent
IPC分类号： C08J9/00 , C08J9/14
CPC分类号： C08J9/148 , C08J9/0066 , C08J9/141 , C08J9/149 , C08J2201/022 , C08J2201/026 , C08J2203/14 , C08J2203/142 , C08J2203/144 , C08J2203/182 , C08J2203/202 , C08J2205/052 , C08J2361/10 , C08J2373/00
摘要： Phenolic closed-cell foam comprises a hydrocarbon blowing agent and includes an alkali metal silicate in an amount of at least 1% by weight. The foam has an aged thermal conductivity as determined by the procedures of EN13166:2008 of less than 0.025 W/m·K. The foam is formed from a phenolic resole resin mixture having a water content of greater than 15% by weight but less than 24% by weight.

9. 发明公开

EP3159375A1 PHENOL RESIN FOAM AND METHOD FOR MANUFACTURING SAME 审中-公开
标题翻译：酚醛树脂泡沫及其制造方法
公开(公告)号：EP3159375A1
公开(公告)日：2017-04-26
申请号：EP15809786.5
申请日：2015-06-17
申请人： Asahi Kasei Construction Materials Corporation
发明人： MUKAIYAMA, Shigemi , IHARA, Ken , HAMAJIMA, Masato
IPC分类号： C08J9/14
CPC分类号： C08J9/141 , B29B7/88 , B29C44/10 , B29K2105/046 , B29L2007/002 , C08J9/0038 , C08J9/0066 , C08J9/146 , C08J9/149 , C08J9/228 , C08J2201/02 , C08J2201/026 , C08J2203/14 , C08J2203/162 , C08J2203/182 , C08J2203/202 , C08J2205/044 , C08J2205/052 , C08J2207/00 , C08J2361/04 , C08J2361/10
摘要： Provided is a phenol resin foam that has low initial thermal conductivity and that retains low thermal conductivity for a long period of time. The present phenol resin foam may contain a cyclopentane and a high-boiling hydrocarbon with a boiling point of from 120 °C to 550 °C and may have a density of from 10 kg/m 3 to 150 kg/m 3 . The content of the cyclopentane in the phenol resin foam per 22.4 × 10 -3 m 3 space volume in the phenol resin foam is from 0.25 mol to 0.85 mol.
摘要翻译：本发明提供一种初始导热系数低，长时间保持低导热系数的酚醛树脂发泡体。本发明的酚醛树脂发泡体可以包含环戊烷和沸点为120-550℃的高沸点烃，并且可以具有10kg / m 3至150kg / m 3的密度。酚醛树脂发泡体中的每22.4×10 -3 m 3空间体积中的酚醛树脂发泡体中的环戊烷的含量为0.25摩尔〜0.85摩尔。

10. 发明公开

EP3055374A1 COLLES À BOIS POUR LA PRÉPARATION DE PANNEAUX DE PARTICULES 审中-公开
标题翻译： HOLZKLEBSTOFFE ZUR HERSTELLUNG VON PARTIKELPLATTEN
公开(公告)号：EP3055374A1
公开(公告)日：2016-08-17
申请号：EP14786363.3
申请日：2014-10-07
申请人： SYRAL Belgium NV , Université de Lorraine
发明人： PIZZI, Antonio , LAGEL, Marie-Christine , REDL, Andreas
IPC分类号： C09J161/06 , C09J189/00 , C08L61/06 , C08L89/00 , C08G8/28 , B27N3/02 , B27N3/04 , C09J11/06
CPC分类号： C09J161/06 , B27N3/002 , B27N3/02 , B27N3/04 , C08H1/00 , C08J9/0061 , C08J2205/10 , C08J2361/10 , C08J2489/00 , C08K5/103 , C08K5/175 , C08L61/06 , C08L89/00 , C08L97/02 , C09J189/00
摘要： The present invention relates to a composition based on phenolic resin comprising at least one phenolic resin, a vegetable protein hydrolysate, preferentially a wheat gluten hydrolysate, and an agent for accelerating curing, and also to the process for the production thereof.
摘要翻译：一种基于酚醛树脂的组合物，其包含至少一种酚醛树脂，植物蛋白水解产物，优选小麦谷蛋白水解产物和用于加速固化的试剂，以及其生产方法。

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