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1. 发明授权

EP1037932B1 OLEFIN POLYMERIZATION CATALYST COMPOSITION COMPRISING REDUCED OXIDATION STATE TRANSITION METAL COMPOUNDS 有权
标题翻译：烯烃聚合催化剂，IN LOW氧化水平的过渡金属化合物CONTAINS
公开(公告)号：EP1037932B1
公开(公告)日：2006-07-26
申请号：EP98956576.7
申请日：1998-11-03
申请人： ExxonMobil Chemical Patents, Inc.
发明人： MATSUNAGA, Phillip, T. , SCHIFFINO, Rinaldo, S.
IPC分类号： C08F10/00 , C08F4/645
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2500/04 , C08F210/14 , C08F2500/10 , C08F4/64113 , C08F4/68284 , C08F4/69284
摘要： This invention is directed to reduced oxidation state Group 4-6 metal compounds, preferably the first row metals in those groups, suitable for activation as polymerization catalysts and characterized by comprising a substituted hydrotris(pyrazolyl)borate ancillary ligand and a plurality of single or multidentate uninegative ligands, excluding cyclopentadienyl ligands. The invention includes a polymerisation process characterized by comprising contacting one or more monomers polymerizable by coordination or insertion polymerization under suitable polymerization conditions with theses catalyst compositions.

2. 发明公开

EP1117670A1 POLYMERISATION CATALYSTS 有权
公开(公告)号：EP1117670A1
公开(公告)日：2001-07-25
申请号：EP99947656.7
申请日：1999-09-22
申请人： BP Chemicals Limited
发明人： GIBSON, Vernon, Charles , KIMBERLEY, Brian, Stephen , SOLAN, Gregory, Adam
IPC分类号： C07F19/00 , C07F15/02 , C07F15/06 , C07F7/00 , C08F10/00 , C07F9/00
CPC分类号： C08F10/00 , C07F7/006 , C07F9/005 , C07F11/005 , C07F15/025 , C07F15/065 , C08F110/02 , C08F4/68284 , C08F4/025 , C08F4/69224 , C08F4/64089 , C08F2500/04 , C08F4/7042 , C08F4/7054 , C08F4/7044
摘要： A complex suitable for the polymerisation of 1-olefins is disclosed, having formula (A) wherein M is a transition metal, lanthanide or actinide; X represents an atom or group covalently or ionically bonded to the transition metal M; b is the valency of the atom or group X; Z1 is N or P; Z2 is N, P, N?-, P- or NR5; Z3¿ is one of N, P, O, S, NHR?3, NR3R4¿, OH, OR3, SH, SR?3, PHR3, PR3R4, (NR3)-, O-, S-, (PR3)-, P(R3R4)O, NR3 or PR3¿, subject to the proviso that one of Z?2 and Z3¿ is anionic; T is the oxidation state of the transition metal M when both Z?2 and Z3¿ are neutral, and (1) less than the oxidation state of M when one of Z2 or Z3 is anionic; A and B are independently hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, and may together with Z2 form part of a heterocyclic substituent; B may be joined to Z3 by either a single or a double bond; R1 to R5 are each independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted hetrohydrocarbyl, and any two or more of R1 to R5 when hydrocarbyl may be joined together to form a ring; L is a solvate molecule, and n is from 0 to 5.

3. 发明公开

EP1925620A1 Polymerisation of ethylene and alpha olefins with single site catalysts having an anionic scorpion-like ligand 审中-公开
标题翻译：乙烯和α-烯烃的聚合用“单中心”催化剂，其含有阴离子蝎样配体
公开(公告)号：EP1925620A1
公开(公告)日：2008-05-28
申请号：EP06124706.0
申请日：2006-11-24
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY
发明人： Michaud, Guillaume , Hillairet, Caroline , Sirol, Sabine
IPC分类号： C07F7/00 , C07F11/00 , C07C251/16 , C07D213/53 , C07D215/12 , C08F4/70 , C08F10/00 , C08F4/622
CPC分类号： C07F7/006 , B01J31/1815 , B01J2231/122 , B01J2531/0238 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/62 , C07C251/16 , C07D213/53 , C07D215/12 , C07F11/005 , C08F10/00 , C08F110/02 , C08F2500/20 , C08F4/64113 , C08F4/69284 , C08F4/7054 , C08F4/69301 , C08F4/68284 , C08F4/6412
摘要： The present invention discloses single site catalyst systems having anionic scorpion-like three dimensional structure, that are suitable for oligomerising or polymerising ethylene and alpha-olefins.
摘要翻译：具有阴离子蝎状三维结构的本发明的盘少单中心催化剂体系，没有适合于低聚或聚合物伊辛乙烯和α-烯烃。

4. 发明授权

EP1084152B1 TRIDENTATE LIGAND-CONTAINING METAL CATALYST COMPLEXES FOR OLEFIN POLYMERIZATION 有权
标题翻译：三价配体含METALLCOMPLEXKATALYSATOREN烯烃
公开(公告)号：EP1084152B1
公开(公告)日：2002-12-11
申请号：EP99920143.7
申请日：1999-04-29
申请人： ExxonMobil Chemical Patents Inc.
发明人： MATSUNAGA, Phillip, T.
IPC分类号： C08F4/62 , C08F10/00
CPC分类号： C08F10/00 , C07F7/006 , C07F9/005 , C07F11/005 , C07F13/005 , C07F15/025 , C07F15/065 , C08F4/61908 , C08F4/61912 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F4/619 , C08F2500/03 , C08F2500/04 , C08F232/00 , C08F2500/25 , C08F210/14 , C08F4/68284 , C08F4/69284 , C08F4/64113

5. 发明公开

EP2089399A1 POLYMERISATION OF ETHYLENE AND ALPHA OLEFINS WITH SINGLE SITE CATALYSTS HAVING AN ANIONIC SCORPION-LIKE LIGAND 有权
标题翻译：聚合使用与阴离子SKORPIONARTIGEM配体的单中心催化剂ETHLYEN和α-烯烃
公开(公告)号：EP2089399A1
公开(公告)日：2009-08-19
申请号：EP07857204.7
申请日：2007-11-09
申请人： Total Petrochemicals Research Feluy
发明人： MICHAUD, Guillaume , HILLAIRET, Caroline , SIROL, Sabine
IPC分类号： C07F7/00 , C07F11/00 , C07C251/16 , C07D213/53 , C07D215/12 , C08F4/70 , C08F10/00 , C08F4/622
CPC分类号： C07F7/006 , B01J31/1815 , B01J2231/122 , B01J2531/0238 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/62 , C07C251/16 , C07D213/53 , C07D215/12 , C07F11/005 , C08F10/00 , C08F110/02 , C08F2500/20 , C08F4/64113 , C08F4/69284 , C08F4/7054 , C08F4/69301 , C08F4/68284 , C08F4/6412
摘要： The present invention discloses single site catalyst systems having anionic scorpion-like three dimensional structure, that are suitable for oligomerising or polymerising ethylene and alpha-olefins.

6. 发明公开

EP1037932A1 REDUCED OXIDATION STATE TRANSITION METAL COMPOUNDS USEFUL AS OLEFIN POLYMERIZATION CATALYSTS 有权
标题翻译：烯烃聚合催化剂，IN LOW氧化水平的过渡金属化合物CONTAINS
公开(公告)号：EP1037932A1
公开(公告)日：2000-09-27
申请号：EP98956576.7
申请日：1998-11-03
申请人： EXXON CHEMICAL PATENTS INC.
发明人： MATSUNAGA, Phillip, T. , SCHIFFINO, Rinaldo, S.
IPC分类号： C08F10/00 , C08F4/645
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2500/04 , C08F210/14 , C08F2500/10 , C08F4/64113 , C08F4/68284 , C08F4/69284
摘要： This invention is directed to reduced oxidation state Group 4-6 metal compounds, preferably the first row metals in those groups, suitable for activation as polymerization catalysts and characterized by comprising a substituted hydrotris(pyrazolyl)borate ancillary ligand and a plurality of single or multidentate uninegative ligands, excluding cyclopentadienyl ligands. The invention includes a polymerisation process characterized by comprising contacting one or more monomers polymerizable by coordination or insertion polymerization under suitable polymerization conditions with theses catalyst compositions.

7. 发明授权

EP2089399B1 POLYMERISATION OF ETHYLENE AND ALPHA OLEFINS WITH SINGLE SITE CATALYSTS HAVING AN ANIONIC SCORPION-LIKE LIGAND 有权
标题翻译：聚合使用与阴离子SKORPIONARTIGEM配体的单中心催化剂ETHLYEN和α-烯烃
公开(公告)号：EP2089399B1
公开(公告)日：2012-08-08
申请号：EP07857204.7
申请日：2007-11-09
申请人： Total Petrochemicals Research Feluy
发明人： MICHAUD, Guillaume , HILLAIRET, Caroline , SIROL, Sabine
IPC分类号： C07F7/00 , C07F11/00 , C07C251/16 , C07D213/53 , C07D215/12 , C08F4/70 , C08F10/00 , C08F4/622
CPC分类号： C07F7/006 , B01J31/1815 , B01J2231/122 , B01J2531/0238 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/62 , C07C251/16 , C07D213/53 , C07D215/12 , C07F11/005 , C08F10/00 , C08F110/02 , C08F2500/20 , C08F4/64113 , C08F4/69284 , C08F4/7054 , C08F4/69301 , C08F4/68284 , C08F4/6412
摘要： The present invention discloses single site catalyst systems having anionic scorpion-like three dimensional structure, that are suitable for oligomerising or polymerising ethylene and alpha-olefins.

8. 发明授权

EP1117670B1 POLYMERISATION CATALYSTS 有权
标题翻译：聚合催化剂
公开(公告)号：EP1117670B1
公开(公告)日：2003-01-02
申请号：EP99947656.7
申请日：1999-09-22
申请人： BP Chemicals Limited
发明人： GIBSON, Vernon, Charles , KIMBERLEY, Brian, Stephen , SOLAN, Gregory, Adam
IPC分类号： C07F19/00 , C07F15/02 , C07F15/06 , C07F7/00 , C08F10/00 , C07F9/00
CPC分类号： C08F10/00 , C07F7/006 , C07F9/005 , C07F11/005 , C07F15/025 , C07F15/065 , C08F110/02 , C08F4/68284 , C08F4/025 , C08F4/69224 , C08F4/64089 , C08F2500/04 , C08F4/7042 , C08F4/7054 , C08F4/7044
摘要： A complex suitable for the polymerisation of 1-olefins is disclosed, having formula (A) wherein M is a transition metal, lanthanide or actinide; X represents an atom or group covalently or ionically bonded to the transition metal M; b is the valency of the atom or group X; Z1 is N or P; Z2 is N, P, N?-, P- or NR5; Z3¿ is one of N, P, O, S, NHR?3, NR3R4¿, OH, OR3, SH, SR?3, PHR3, PR3R4, (NR3)-, O-, S-, (PR3)-, P(R3R4)O, NR3 or PR3¿, subject to the proviso that one of Z?2 and Z3¿ is anionic; T is the oxidation state of the transition metal M when both Z?2 and Z3¿ are neutral, and (1) less than the oxidation state of M when one of Z2 or Z3 is anionic; A and B are independently hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, and may together with Z2 form part of a heterocyclic substituent; B may be joined to Z3 by either a single or a double bond; R1 to R5 are each independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted hetrohydrocarbyl, and any two or more of R1 to R5 when hydrocarbyl may be joined together to form a ring; L is a solvate molecule, and n is from 0 to 5.
摘要翻译：公开了一种适用于1-烯烃聚合的配合物，其具有式（A），其中M是过渡金属，镧系元素或act系元素; X表示与过渡金属M共价或离子键合的原子或基团; b是原子或基团X的化合价; Z1是N或P; Z2是N，P，N - ， - P-或NR5; Z3是N，P，O，S，NHR3，NR3R4，OH，OR3，SH，SR3，PHR3，PR3R4，（NR3） - ，O-，S-，（PR3） - ， P（R3R4）O，NR3或PR3，条件是Z2和Z3中的一个是阴离子; T是当Z 2和Z 3都是中性时过渡金属M的氧化态，和（1）当Z 2或Z 3之一是阴离子时M低于M的氧化态; A和B独立地为烃基，取代的烃基，杂烃基或取代的杂烃基，并且可以与Z 2一起形成杂环取代基的一部分; B可以通过单键或双键与Z3连接; 当烃基可以连接在一起形成环时，R 1至R 5各自独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基，以及R 1至R 5中的任何两个或更多个; L是溶剂合物分子，n是0-5。

9. 发明公开

EP1084152A1 TRIDENTATE LIGAND-CONTAINING METAL CATALYST COMPLEXES FOR OLEFIN POLYMERIZATION 有权
标题翻译：三价配体含有烯烃聚合金属配合物催化剂
公开(公告)号：EP1084152A1
公开(公告)日：2001-03-21
申请号：EP99920143.7
申请日：1999-04-29
申请人： EXXON CHEMICAL PATENTS INC.
发明人： MATSUNAGA, Phillip, T.
IPC分类号： C08F4/60 , C08F10/00
CPC分类号： C08F10/00 , C07F7/006 , C07F9/005 , C07F11/005 , C07F13/005 , C07F15/025 , C07F15/065 , C08F4/61908 , C08F4/61912 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F4/619 , C08F2500/03 , C08F2500/04 , C08F232/00 , C08F2500/25 , C08F210/14 , C08F4/68284 , C08F4/69284 , C08F4/64113
摘要： An activated tridentate-, monoanionic-ligand-based transition metal catalyst in a reduced oxidation state for olefin polymerization is disclosed. Transition metal catalyst precursors for these catalysts have formulae (A), (B), in which M is a transition metal from Groups 4-9 in a reduced oxidation state, X is a monoanionic, ligand, L is a neutral donor group, E is a neutral donor group from Groups 15 and 16, E' is a monoanionic donor group from Group 15, T is a bridging group, n is 1-3 as needed to balance the charge on M, p is 0-3 and q is 1-2. Olefin polymerization is exemplified.

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