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1. 发明公开

EP1926759A2 POLYMERISATION CATALYSTS 审中-公开
标题翻译： POLYMERISIERUNGSKATALYSATOREN
公开(公告)号：EP1926759A2
公开(公告)日：2008-06-04
申请号：EP06779442.0
申请日：2006-09-15
申请人： INEOS EUROPE LIMITED
发明人： GIBSON, Vernon, Charles , OAKES, Daniel, Charles, Howard
IPC分类号： C08F10/00 , C08F4/64 , C07F7/28
CPC分类号： C07F7/006 , C08F10/00 , C08F210/16 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F4/64075
摘要： A complex compound comprising the skeletal unit (A), wherein the ring C(R1) -A1-A2-(A3)X-C(R2) -C- has delocalised unsaturation and is optionally substituted via one or more of A1, A2 and A3 by hydrogen, alkyl, aryl, halogen, or heterocyclic groups containing at least one N, S or O in a carbon ring; A1, A2 and A3 are carbon, nitrogen and, oxygen, R1 and R2 are hydrocarbyl, chlorine, bromine and iodine at least one of R1 and R2 being chlorine, bromine or iodine; x is zero or 1, 0 is oxygen, E is nitrogen, phosphorus or arsenic, Q is a divalent bridging group comprising one or more Group 14 atoms; X is a monovalent atom or group covalently or ionically bonded to M; L is a mono- or bidentate molecule datively bound to M, y satisfies the valency of M and z is from 0 to 5. The complex can be used to polymerise olefins optionally with organo-Al or - B compounds as activator.

2. 发明授权

EP0950667B1 Olefin polymerization catalyst and polymerization process 有权
标题翻译：烯烃聚合催化剂和聚合
公开(公告)号：EP0950667B1
公开(公告)日：2005-08-10
申请号：EP99106268.8
申请日：1999-04-15
申请人： MITSUI CHEMICALS, INC.
发明人： Matsui, Shigekazu , Tsuru, Kazutaka , Nitabaru, Masatoshi , Fujita, Terunori , Mitani, Makoto , Takagi, Yukihiro , Nakano, Takashi
IPC分类号： C08F4/00 , C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , C08F110/02 , C08F4/64048 , C08F2500/17 , C08F4/64044 , C08F4/64051 , C08F4/64075

3. 发明公开

EP0953571A1 Catalysts for olefin polymerisation 审中-公开
标题翻译：聚乙烯聚合物
公开(公告)号：EP0953571A1
公开(公告)日：1999-11-03
申请号：EP99303176.4
申请日：1999-04-23
申请人： BP Chemicals Limited
发明人： Gibson, Vernon Charles , Kimberley, Brian Stephen
IPC分类号： C07F5/00 , C07F7/00 , C07F9/00 , C08F10/00 , C08F4/60
CPC分类号： C07F7/006 , C08F10/00 , C08F2410/03 , C08F4/64075 , C08F4/64013
摘要： Novel compounds are disclosed comprising the skeletal unit depicted in Formula (I)
wherein O is oxygen, N is nitrogen, Q represents a divalent organic group or a group based on a Group 14 atom; R 1 is hydrogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; M is scandium yttrium, or a Group IV or Group V metal or a lanthanide or actinide; T is the oxidation state of M and is II or greater; X represents a monodentate atom or group covalently or ionically bonded to M; L is a mono- or bidentate molecule datively bound to M, and n is from 0 to 5. These compounds may be used as polymerisation catalysts for 1-olefins.
摘要翻译：公开了包含式（I）所示骨架单元的新型化合物，其中O为氧，N为氮，Q为二价有机基团或基于第14族原子的基团; R 1是氢，烃基，取代的烃基，杂烃基或取代的杂烃基; M是钪钇，或IV族或V族金属或镧系元素或锕系元素; T是M的氧化态，为II或更大; X表示与M共价或离子键合的单齿原子或基团; L是与M直接结合的单齿或双齿分子，n为0至5.这些化合物可用作1-烯烃的聚合催化剂。

4. 发明公开

EP1558593A1 BERGANGSMETALLKATALYSATOREN F R (CO)POLYMERISATION VON OLEFINISCHEN MONOMEREN 有权
标题翻译：过渡金属催化剂用于烯烃单体的（共）聚合
公开(公告)号：EP1558593A1
公开(公告)日：2005-08-03
申请号：EP03779830.3
申请日：2003-11-03
申请人： BASF AKTIENGESELLSCHAFT
发明人： PREISHUBER-PFLÜGL, Peter , OKUDA, Jun , REIMER, Valentine , KRISTEN, Marc Oliver
IPC分类号： C07D277/82 , C07D277/42 , C07F7/00 , B01J31/00 , C08F10/00 , C08F4/64 , C08F4/62
CPC分类号： B01J31/2243 , B01J31/143 , B01J31/1616 , B01J31/1815 , B01J31/2204 , B01J31/2295 , B01J2231/12 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07D277/42 , C07D277/82 , C07F7/006 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F4/64075 , C08F4/64141
摘要： The invention relates to metal complexes composed of a transition metal and of at least one multidentate ligand of general formulas (Ia) or (Ib), to a method for producing the metal complexes, to the multidentate ligands themselves, to the production thereof, to catalytically active compositions containing the inventive metal complex, to the use of the inventive catalytic composition for polymerizing or copolymerizing olefins, to a method for polymerizing or copolymerizing olefins, during which the inventive catalytic composition is used, and to a polymer or copolymer that can be produced according to the inventive method.

5. 发明公开

EP0950667A2 Olefin polymerization catalyst and polymerization process 有权
标题翻译：聚烯烃聚合物和聚合物复合材料
公开(公告)号：EP0950667A2
公开(公告)日：1999-10-20
申请号：EP99106268.8
申请日：1999-04-15
申请人： Mitsui Chemicals, Inc.
发明人： Matsui, Shigekazu , Tsuru, Kazutaka , Nitabaru, Masatoshi , Fujita, Terunori , Mitani, Makoto , Takagi, Yukihiro , Nakano, Takashi
IPC分类号： C08F4/00 , C08F10/00
CPC分类号： C08F10/00 , C08F110/02 , C08F4/64048 , C08F2500/17 , C08F4/64044 , C08F4/64051 , C08F4/64075
摘要： An olefin polymerization catalyst having an excellent polymerization activity and an olefin polymerization process using the catalyst are disclosed. The olefin polymerization catalyst comprises (A) a transition metal compound represented by, for example, the following formula (I) and optionally (B) at least one compound selected from an organometallic compound, an organoaluminum oxy-compound and a compound which reacts with the transition metal compound (A) to from an ion pair;
wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table; m is an integer of 1 to 6; A is -O-, -S-, -Se- or -N(R5)-; D is -C(R 7 )(R 8 )-, -Si(R 9 )(R 10 )- or the like; Z is -R 13 and -R 14 , =C(R 15 )R 16 , =NR 17 or the like; R 1 to R 17 are each H, a hydrocarbon group or the like; n is a number satisfying a valence of M; and X is halogen, a hydrocarbon group or the like.
摘要翻译：公开了具有优异聚合活性的烯烃聚合催化剂和使用该催化剂的烯烃聚合方法。烯烃聚合催化剂包含（A）由下式（I）表示的过渡金属化合物和任选的（B）至少一种选自有机金属化合物，有机铝氧化合物和与过渡金属化合物（A）离子对; 其中M是周期表第3族至第11族的过渡金属原子; m为1〜6的整数。 A是-O - ， - S - ， - Se-或-N（R 5） - ; D是-C（R 7）（R 8） - ，-Si（R 9）（R 10） - 等; Z是-R 13和-R 14，= C（R 15）R 16，= NR 17等; R 1至R 17各自为H，烃基等; n是满足M价的数; X为卤素，烃基等。

6. 发明授权

EP1558593B1 ÜBERGANGSMETALLKATALYSATOREN FÜR (CO)POLYMERISATION VON OLEFINISCHEN MONOMEREN 有权
标题翻译：过渡金属催化剂用于烯烃单体的（共）聚合
公开(公告)号：EP1558593B1
公开(公告)日：2010-03-03
申请号：EP03779830.3
申请日：2003-11-03
申请人： Basell Polyolefine GmbH
发明人： PREISHUBER-PFLÜGL, Peter , OKUDA, Jun , REIMER, Valentine , KRISTEN, Marc Oliver
IPC分类号： C07D277/82 , C07D277/42 , C07F7/00 , B01J31/00 , C08F10/00 , C08F4/64 , C08F4/62
CPC分类号： B01J31/2243 , B01J31/143 , B01J31/1616 , B01J31/1815 , B01J31/2204 , B01J31/2295 , B01J2231/12 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07D277/42 , C07D277/82 , C07F7/006 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F4/64075 , C08F4/64141
摘要： The invention relates to metal complexes composed of a transition metal and of at least one multidentate ligand of general formulas (Ia) or (Ib), to a method for producing the metal complexes, to the multidentate ligands themselves, to the production thereof, to catalytically active compositions containing the inventive metal complex, to the use of the inventive catalytic composition for polymerizing or copolymerizing olefins, to a method for polymerizing or copolymerizing olefins, during which the inventive catalytic composition is used, and to a polymer or copolymer that can be produced according to the inventive method.

7. 发明公开

EP1767549A1 Polymerisation catalysts 审中-公开
标题翻译： Polymerisationskatalysatoren
公开(公告)号：EP1767549A1
公开(公告)日：2007-03-28
申请号：EP05255794.9
申请日：2005-09-20
申请人： INEOS EUROPE LIMITED
发明人： The designation of the inventor has not yet been filed
IPC分类号： C08F10/00 , C08F4/64 , C07F7/28
CPC分类号： C07F7/006 , C08F10/00 , C08F210/16 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F4/64075
摘要： A complex compound comprising the skeletal unit of Formula A

wherein the ring C(R') -A 1 -A 2 -(A 3 ) x -C(R 2 ) -C- has delocalised unsaturation, A 1 , A 2 and A 3 can be substituted with hydrogen, alkyl, aryl, halogen, and heterocyclic groups containing at least one N, S or O in a carbon ring; A 1 , A 2 and A 3 are carbon, nitrogen or oxygen, R 1 and R 2 are hydrocarbyl, chlorine, bromine or iodine, at least one R 1 and R 2 is halogen, x is zero or 1, O is oxygen, E is nitrogen, phosphorus or arsenic, Q is a divalent bridging organic group optionally comprising one or more other Group 14 atoms; X is a monovalent atom or group covalently or ionically bonded to M; L is a mono- or bidentate molecule datively bound to M, x satisfies the valency of M and z is from 0 to 5. The complex can be used to polymerise olefins optionally with organo-A1 or -B compounds as activator.
摘要翻译：包含式A的骨架单元的络合物，其中环C（R'）-A 1 -A 2 - （A 3）x -C（R 2）-C-具有离域不饱和键，A 1，A 2和A 3可以被碳环中含有至少一个N，S或O的氢，烷基，芳基，卤素和杂环基团取代; A 1，A 2和A 3是碳，氮或氧，R 1和R 2是烃基，氯，溴或碘，至少一个R 1和R 2是卤素，x是0或1，O是氧， E是氮，磷或砷，Q是任选地包含一个或多个其它第14族原子的二价桥连有机基团; X是与M共价或离子键合的单价原子或基团; L是与M偶合的单齿或双齿分子，x满足M的化合价，z为0至5.该络合物可用于任选与有机-Al或-B化合物作为活化剂聚合烯烃。

8. 发明公开

EP0950667A3 Olefin polymerization catalyst and polymerization process 有权
标题翻译：烯烃聚合催化剂和聚合
公开(公告)号：EP0950667A3
公开(公告)日：2003-02-05
申请号：EP99106268.8
申请日：1999-04-15
申请人： Mitsui Chemicals, Inc.
发明人： Matsui, Shigekazu , Tsuru, Kazutaka , Nitabaru, Masatoshi , Fujita, Terunori , Mitani, Makoto , Takagi, Yukihiro , Nakano, Takashi
IPC分类号： C08F4/00 , C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , C08F110/02 , C08F4/64048 , C08F2500/17 , C08F4/64044 , C08F4/64051 , C08F4/64075
摘要： An olefin polymerization catalyst having an excellent polymerization activity and an olefin polymerization process using the catalyst are disclosed. The olefin polymerization catalyst comprises (A) a transition metal compound represented by, for example, the following formula (I) and optionally (B) at least one compound selected from an organometallic compound, an organoaluminum oxy-compound and a compound which reacts with the transition metal compound (A) to from an ion pair; wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table; m is an integer of 1 to 6; A is -O-, -S-, -Se- or -N(R5)-; D is -C(R 7 )(R 8 )-, -Si(R 9 )(R 10 )- or the like; Z is -R 13 and -R 14 , =C(R 15 )R 16 , =NR 17 or the like; R 1 to R 17 are each H, a hydrocarbon group or the like; n is a number satisfying a valence of M; and X is halogen, a hydrocarbon group or the like.

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