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    • 2. 发明公开
    • A PROCESS FOR RECOVERING HYDROCARBONS IN A SOLUTION POLYMERISATION PROCESS
    • EP3394114A1
    • 2018-10-31
    • EP16825742.6
    • 2016-12-21
    • Borealis AG
    • AL-HAJ ALI, MohammadERIKSSON, ErikMATHIVANAN, GuhanSLEIJSTER, HenryVIJAY, SameerWURNITSCH, ChristofZITTING, Samuli
    • C08F2/06C08F6/00C08J11/02C08F6/12
    • C08F6/12B01D3/143B01D3/42C08F2/06C08F6/003C08F6/04C08F10/02C08F10/06C08F36/02C08L23/00
    • The present invention relates to a process for producing a polymer composition comprising the steps of: (A) polymerising, in a first polymerisation reactor in a first solvent,—a first olefin monomer having two or more carbon atoms, —in the presence of a first polymerisation catalyst for producing a first solution comprising a first polymer of the first olefin monomer and the first solvent; (B) withdrawing a first stream of the first solution from the first polymerisation reactor; (C) passing the first stream of the first solution into a first separator wherein a first liquid phase comprising the polymer and a first vapour phase coexist; (D) withdrawing a first vapour stream and a first concentrated solution stream comprising the polymer from the first separator; (E) passing at least a part of the first vapour stream to a first fractionator; (F) withdrawing a first overhead stream and a first bottom stream from the first fractionator; (G) recovering at least a part of the first overhead stream as a first recycle stream and passing it to the first polymerisation reactor; (H) passing the first concentrated solution stream from the first separator (4) to a second separator (8) wherein a second liquid phase comprising the polymer and a second vapour phase coexist; (I) withdrawing a second vapour stream and a second concentrated solution stream comprising the polymer from the second separator; (J) passing at least a part of the second pour stream to a second fractionator; (K) withdrawing a second overhead stream and a second bottom stream from the second fractionator; (L) recovering at least a part of the second overhead stream as a second recycle stream and passing it to the first polymerisation reactor; (M) passing the second concentrated solution stream from the second separator to a third separator wherein a third liquid phase comprising the polymer and a third vapour phase coexist; characterised in that the mass flow rate of the first recycle stream is at least 80% of the mass flow rate of the first vapour stream and the mass flow rate of the second recycle stream is at least 70% of the mass flow rate of the second vapour stream.
    • 8. 发明公开
    • METHOD FOR MANUFACTURING CONJUGATED DIENE POLYMER WITH MODIFIED END, CONJUGATED DIENE POLYMER WITH MODIFIED END, RUBBER COMPOSITION, AND TIRE
    • VERFAHREN ZUR HERSTELLUNG VON KONJUGIERTEM DIENPOLYMER MIT MODIFIZIERTEM ENDE,KONJUGIERTES DIENPOLYMER MIT MODIFIZIERTEN ENDE,KAUTSCHUKZUSAMMENSETZUNG UND REIFEN
    • EP3184554A4
    • 2017-08-23
    • EP15833853
    • 2015-07-02
    • BRIDGESTONE CORP
    • HIRATA NARUKUNIYAMAGATA YUSUKETANABE TOMOEKAITA SHOJIRO
    • C08C19/00B60C1/00C08F4/54C08F4/602C08L15/00
    • C08F36/02B60C1/00C08C19/00C08F4/12C08F4/54C08F4/602C08F8/18C08F8/34C08F8/40C08J2353/02C08L15/00
    • This disclosure is to provide a method for preparing a terminal-modified conjugated diene polymer which achieves an extremely high compounding amount of cis-1,4 without complicated preparing conditions, a terminal-modified conjugated diene polymer obtained via the method, a rubber composition containing the terminal-modified conjugated diene polymer, and a tire using the rubber composition. This disclosure is A method for preparing a terminal-modified conjugated diene polymer comprising: polymerizing a conjugated diene compound by using a polymerization catalyst composition and modifying a polymer obtained via the polymerization by using a modifier, wherein the polymerization catalyst composition contains a rare earth element compound, and a coordination compound having a cyclopentadiene skeleton selected from substituted or unsubstituted cyclopentadienes, substituted or unsubstituted indenes, and substituted or unsubstituted fluorenes, and wherein the polymerization and modification is performed in a one-pot way.
    • 本发明提供一种制备在没有复杂的制备条件下实现极高配合量的顺式-1,4的末端改性共轭二烯聚合物的方法,通过该方法获得的末端改性共轭二烯聚合物,含有 末端改性共轭二烯聚合物,以及使用该橡胶组合物的轮胎。 本发明是一种制备末端改性的共轭二烯聚合物的方法,其包括:通过使用聚合催化剂组合物聚合共轭二烯化合物,并使用改性剂改性通过聚合获得的聚合物,其中所述聚合催化剂组合物包含稀土元素 化合物和具有选自取代或未取代的环戊二烯,取代或未取代的茚和取代或未取代的芴的环戊二烯骨架的配位化合物,并且其中聚合和改性以一锅法进行。