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1. 发明公开

EP3222609A1 METHOD FOR PREPARING METHYL FORMATE AND COPRODUCING DIMETHYL ETHER 审中-公开
标题翻译：制备甲酸甲酯和生产二甲醚的方法
公开(公告)号：EP3222609A1
公开(公告)日：2017-09-27
申请号：EP14906419.8
申请日：2014-11-17
申请人： Dalian Institute Of Chemical Physics Chinese Academy of Sciences
发明人： NI, Youming , ZHU, Wenliang , LIU, Yong , LIU, Hongchao , LIU, Zhongmin , LI, Lina , LIU, Shiping , ZHOU, Hui
IPC分类号： C07C67/00 , C07C69/06 , C07C41/50 , C07C43/30 , C07C43/04
CPC分类号： C07C67/39 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/7007 , B01J29/7038 , B01J31/10 , B01J39/05 , B01J39/20 , B01J2231/50 , B01J2231/70 , C07C41/18 , C07C41/50 , C07C43/04 , C07C43/30 , C07C67/00 , C07C69/06
摘要： The present invention provides a method for preparing methyl formate and coproducing dimethyl ether. A raw material containing formaldehyde and methanol is introduced into a First Reaction Region contacting with a Catalyst A to react, and the post-reaction material is separated to obtain Constituent I.
The Constituent I is introduced into a Second Reaction Region contacting with a Catalyst B to react, and the post-reaction material separating is separated to obtain methyl formate, dimethyl ether and Constituent II. At least 1% of dimethyl ether is taken as product, and the rest of dimethyl ether is recycled to the First Reaction Region. The Constituent II is recycled to the Second Reaction Region. In the raw material, the molar ratio range of formaldehyde to methanol is from 1:4 to 1:0.05, and the molar of formaldehyde and methanol are calculated according to the molar of carbon atoms contained in formaldehyde and methanol, respectively. The weight hourly space velocity of formaldehyde in the raw material ranges from 0.01 h -1 to 15.0 h -1 . The reaction temperature of the First Reaction Region ranges from 50°C to 100°C. The reaction temperature range of the Second Reaction Region is from 50°C to 200°C, and the reaction pressure range is from 0.1 MPa to 10 MPa. Each component is gaseous phase and/or liquid phase, independently. The method shows benefits, including a long catalyst life, a mild reaction condition, a high utilization ratio of raw materials, an achievement of continuous production and an application potential of large scale industrial.
摘要翻译：本发明提供了一种制备甲酸甲酯和联产二甲醚的方法。将含有甲醛和甲醇的原料引入到与催化剂A接触的第一反应区中以进行反应，并将后反应物分离以获得组分I.将组分I引入到与催化剂B接触的第二反应区中进行反应，分离后反应物分离得到甲酸甲酯，二甲醚和组分II。将至少1％的二甲醚作为产物，其余的二甲醚再循环至第一反应区。组分II被回收到第二反应区。在原料中，甲醛与甲醇的摩尔比范围为1：4〜1：0.05，甲醛与甲醇的摩尔数分别根据甲醛与甲醇中所含碳原子的摩尔数计算。原料中甲醛的重时空速范围为0.01 h-1至15.0 h-1。第一反应区的反应温度范围为50℃至100℃。第二反应区域的反应温度范围为50℃至200℃，反应压力范围为0.1MPa至10MPa。每个组分独立地是气相和/或液相。该方法具有催化剂使用寿命长，反应条件温和，原料利用率高，连续生产成本高，具有大规模工业应用潜力等优点。

2. 发明公开

EP2987781A1 VERFAHREN ZUR HERSTELLUNG VON OXYMETHYLENDIALKYLETHERN UND DEREN VERWENDUNG 审中-公开
标题翻译：用于生产OXYMETHYLENDIALKYLETHERN及其用途
公开(公告)号：EP2987781A1
公开(公告)日：2016-02-24
申请号：EP15002061.8
申请日：2015-07-09
申请人： Karlsruher Institut für Technologie
发明人： Arnold, Ulrich , Lautenschütz, Ludger , Oestreich, Dorian , Sauer, Jörg
IPC分类号： C07C41/56 , C10L1/185
CPC分类号： C07C41/56 , C10L1/02 , C10L1/1852 , C10L1/1985 , C10L10/12 , C10M129/16 , C10M145/26 , C10M2207/04 , C10M2209/103 , C07C43/30 , C10M2209/108
摘要： Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Oxymethylendialkylethern und deren direkte Verwendung als Kraftstoffadditive. Oligomere Oxymethylendialkylether (OMDAE) lassen sich durch folgendes Verfahren einfach und direkt herstellen und als Additiv in Kraftstoffen einsetzen. Mindestens ein Alkohol und/oder Carbonsäure werden mit mindestens einem Aldehyd und/oder Keton in Anwesenheit eines sauren Katalysators umgesetzt. Während der Reaktion oder anschließend wird durch Zugabe oder Entstehung eines Extraktionsmittels eine wässrigen und eine organischen Phase erzeugt und anschließend die organische Phase entnommen.
摘要翻译：本发明涉及一种用于Oxymethylendialkylethern的制备及其作为燃料添加剂直接使用的方法。低聚物Oxymethylendialkylether（OMDAE）可以容易地和直接地制造和通过以下的方法作为添加剂在燃料中使用。至少一种醇和/或羧酸与在酸催化剂的存在下至少一种醛和/或酮反应。反应或随后过程中产生的水，并通过萃取剂的添加或形成有机相，然后除去有机相。

3. 发明授权

EP1925607B1 Substituted hydrogenated naphthalene derivatives and their use in fragrance formulations 有权转让
标题翻译：取代氢化Naphtalinderivate及其使用的芳香剂制剂
公开(公告)号：EP1925607B1
公开(公告)日：2014-08-13
申请号：EP07254376.2
申请日：2007-11-06
申请人： International Flavors & Fragrances Inc.
发明人： Narula, Anubhav P.S. , Arruda, Edward Mark , Pieschl, Paul J.
IPC分类号： C07C33/34 , C11B9/00
CPC分类号： C07C43/30 , C07C33/14 , C07C43/162 , C07C69/007 , C07C2602/28 , C11B9/0053

4. 发明公开

EP2450336A1 Process for the production of pure methylal 审中-公开
标题翻译： Verfahren zur Herstellung von reinem Methylal
公开(公告)号：EP2450336A1
公开(公告)日：2012-05-09
申请号：EP10190581.8
申请日：2010-11-09
申请人： INEOS Paraform GmbH
发明人： Hasse, Hans, Prof. Dr.-Ing. , Drunsel, Jan-Oliver , Burger, Jakob , Schmidt, Ulrich , Renner, Mario , Blagov, Sergej, Dr.
IPC分类号： C07C41/56 , C07C43/30 , C07C43/303
CPC分类号： C07C41/09 , B01D3/009 , B01D3/143 , C07C41/56 , C07C41/58 , C07C43/30
摘要： The invention relates to a continuous process to make and isolate methylal by reacting formaldehyde and methanol with an acid catalyst under at least partial formation of methylal and water, to form a mixture M2 comprising formaldehyde, methanol, methylal, and water, separating the said mixture M2 in a distillation column B into three distinct product streams, one being a distillate taken from the column head BH which is rich in methylal, one taken from the column bottom stream BB being almost pure water, and one taken from the side of the column B below the second reaction zone which stream is rich in methanol, characterised in that the ratio of the amount of substance of methanol to the amount of substance of formaldehyde in the mixture M1 is at least 3 mol/mol, and to an apparatus to be used with this process.
摘要翻译：本发明涉及通过在至少部分形成甲缩醛和水的情况下使甲醛和甲醇与酸催化剂反应制备和分离甲缩醛的连续方法，以形成包含甲醛，甲醇，甲缩醛和水的混合物M2，将所述混合物分离 M2在蒸馏塔B中分成三个不同的产物流，一个是从柱头BH获得的富含甲缩醛的馏出物，一个取自塔底馏分BB几乎是纯水，一个从塔的一侧取出 B在第二反应区之下，该物流富含甲醇，其特征在于，混合物M1中甲醇的物质与甲醛的物质的量的比例为至少3mol / mol，与此过程一起使用。

5. 发明授权

EP1893667B1 VERFAHREN ZUR HERSTELLUNG VON POLYOXYMETHYLENDIMETHYLETHERN AUS METHANOL UND FORMALDEHYD 有权
标题翻译：用于生产聚甲醛二甲醚甲醇和甲醛
公开(公告)号：EP1893667B1
公开(公告)日：2008-12-10
申请号：EP06841251.9
申请日：2006-06-12
申请人： BASF SE
发明人： STROEFER, Eckhard , HASSE, Hans , BLAGOV, Sergej
IPC分类号： C08G65/00
CPC分类号： C08G16/0212 , C07C41/56 , C07C43/30

6. 发明公开

EP1902009A1 VERFAHREN ZUR HERSTELLUNG VON POLYOXYMETHYLENDIALKYLETHERN AUS TRIOXAN UND DIALKYLETHER 有权
标题翻译：用于生产聚甲醛二烷基醚和二烷基三烷OFF
公开(公告)号：EP1902009A1
公开(公告)日：2008-03-26
申请号：EP06763634.0
申请日：2006-06-12
申请人： BASF SE
发明人： STRÖFER, Eckhard , SCHELLING, Heiner , HASSE, Hans , BLAGOV, Sergej
IPC分类号： C07C41/50 , C07C43/30
CPC分类号： C07C41/50 , C07C41/58 , C07C43/303 , C07C43/30
摘要： The invention relates to a method for production of polyoxymethylene dialkyl ethers of formula H2m+1CmO(CH2O)nCmH2m+1, where n = 2 - 10, m independently = 1 or 2, in which a dialkyl ether selected from dimethyl ether, methyl ethyl ether or diethyl ether and trioxan are fed into a reactor and reacted in the presence of an acid catalyst, whereby the amount of water introduced into the reaction mixture with the dialkyl ether, trioxan and/or the catalyst is

7. 发明公开

EP1505049A1 A process for the selective production of dialkyl-polyformals 审中-公开
标题翻译：维他命Zur selektiven Herstellung von Dialkylpolyformalen
公开(公告)号：EP1505049A1
公开(公告)日：2005-02-09
申请号：EP04105812.4
申请日：2000-07-18
申请人： SNAMPROGETTI S.p.A.
发明人： Patrini, Renata , Marchionna, Mario
IPC分类号： C07C41/56 , C07C41/60 , C07C43/30
CPC分类号： C10L10/12 , C07C41/56 , C08G2/08 , C10L1/026 , C10L1/143 , C10L1/1811 , C10L1/1852 , C10L1/1985 , C10L1/231 , C07C43/30
摘要： A process is described for the production of dialkyl-polyformals, starting from alcohol and/or dialkylformals and formaldehyde in the presence of sulfonic acids optionally substituted.
摘要翻译：描述了在任选取代的磺酸存在下从醇和/或二烷基甲醛和甲醛开始制备二烷基 - 聚甲醛的方法。

8. 发明公开

EP0865454A1 ADDITION OF AMINE TO IMPROVE PARAFORMALDEHYDE 失效
标题翻译：加入胺，以提高多聚甲醛
公开(公告)号：EP0865454A1
公开(公告)日：1998-09-23
申请号：EP97916084.0
申请日：1997-03-19
申请人： Celanese International Corporation
发明人： CHEUNG, Hung-Cheun , SUPPLEE, Carolyn , SEAMAN, George, C. , GERBERICH, H., Robert
IPC分类号： C07C43 , C08G2
CPC分类号： C07C43/30 , C08G2/08
摘要： Disclosed is a process to produce paraformaldehyde prills having a low dissolution time and low concentration of insoluble formation. The insolubles are believed to lead to stickiness, tackiness, and loss of flowability of the product, loss of handling, and lead to storage problems of the final prill product. To address this problem, a concentrated formaldehyde solution is prepared having a purity ranging from 37 %-99 % and may be mixed with an amine additive, an amine and alcohol additive, or amine, alcohol, and caustic additive. Alternatively, the final prill may be sprayed with an amine or amine mixture stabilizer.

10. 发明授权

EP0308438B1 Flüssigkristalline Phase, Tolane enthaltend 失效
标题翻译：液相晶体相
公开(公告)号：EP0308438B1
公开(公告)日：1993-09-29
申请号：EP88902100.2
申请日：1988-03-10
申请人： MERCK PATENT GmbH
发明人： REIFFENRATH, Volker , KRAUSE, Joachim , WEBER, Georg , HITTICH, Reinhard
IPC分类号： C07C25/24 , C07C15/54 , C07C69/75 , C07C43/215 , C07C255/50 , C07C43/225 , C07C43/30 , C07C43/313 , C07D319/06 , C07C255/36
CPC分类号： C07C255/00 , C07C15/54 , C07C25/24 , C07C43/215 , C07C43/225 , C07C43/30 , C09K19/0216 , C09K19/12 , C09K19/18 , C09K19/3059 , C09K19/3068 , C09K19/3402 , C09K19/42 , C09K2019/3422
摘要： Tolanes having the formula (I): R1-(A1-Z1)m-A3-C=C-A4-(A2)n-R2, in which R1, A1, Z1, m, A3, A4, A2, n and R2 are as given in claim (1), and application of said tolanes as components of liquid crystal phases, particularly as components of liquid crystal phases for electyro-optical display elements based on the ECB effect.

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