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1. 发明公开

EP2510024A1 ACRYLNITRIL-SILAZAN-COPOLYMERE, INSBESONDERE IN FASERFORM, VERFAHREN ZU DEREN HERSTELLUNG UND IHRE VERWENDUNG 有权
标题翻译：丙烯腈硅氮烷共聚物，尤其是纤维形式，其制造方法相同，它们的用途
公开(公告)号：EP2510024A1
公开(公告)日：2012-10-17
申请号：EP10787475.2
申请日：2010-12-08
申请人： Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. , Clariant Finance (BVI) Limited , Universität Bayreuth
发明人： BAUER, Monika , DECKER, Daniel , MOTZ, Guenther
IPC分类号： C08F220/44 , C08F283/00 , C08G77/62 , D01D5/08
CPC分类号： C04B35/62281 , C04B35/62295 , C04B35/6281 , C04B2235/483 , C04B2235/5264 , C04B2235/6021 , C08F220/44 , C08F283/00 , C08G77/62 , D01F6/38 , C08F230/08
摘要： The present invention relates to a copolymer which is obtainable by reacting acrylonitrile or a mixture of acrylonitrile and an organic molecule which can be copolymerized with acrylonitrile with at least one monomeric, oligomeric and/or polymeric silazane, said silazane containing at least one vinylic double bond. The copolymer can be converted to fiber form and/or made infusible. Fibrous copolymers can be used to produce ceramic fibers by pyrolysis.
摘要翻译：本发明涉及通过使丙烯腈或有机分子的丙烯腈和的混合物的混合物而获得的共聚物也可与丙烯腈共聚，用其中A单体，低聚和/或聚合的硅氮烷，可以获得，所述的硅氮烷含有至少一种乙烯基双键。该共聚物可以被带入纤维形式和/或由可输注。通过热解生产的陶瓷纤维是可能的纤维状共聚物。

2. 发明授权

EP1317462B1 SILICIUMBORKARBONITRIDKERAMIKEN UND VORLAEUFERVERBINDUNGEN, VERFAHREN ZU DEREN HERSTELLUNG UND VERWENDUNG 有权
标题翻译：硅碳棒陶瓷和模板化合物，其制备和使用方法
公开(公告)号：EP1317462B1
公开(公告)日：2005-06-01
申请号：EP01972062.2
申请日：2001-09-14
申请人： Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. , Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.
发明人： JANSEN, Martin , MÜLLER, Utz , CLADE, Jürgen , SPORN, Dieter
IPC分类号： C07F7/10 , C07F7/12 , C04B35/589
CPC分类号： C07F7/12 , C01B21/0602 , C01B21/088 , C04B35/589 , C04B35/62295 , C04B35/62675 , C04B35/6268 , C04B2235/6022 , C04B2235/6026 , C04B2235/658 , C04B2235/723 , C04B2235/96 , C07F7/10

3. 发明公开

EP2195131A2 METHOD FOR PRODUCING A THREE-DIMENSIONAL MACROPOROUS FILAMENT CONSTRUCT BASED ON PHASE INVERSION AND CONSTRUCT THEREBY OBTAINED 有权
标题翻译：一种用于生产三维大孔FILAMENTKONSTRUKTION基于相转移，从而获得施工
公开(公告)号：EP2195131A2
公开(公告)日：2010-06-16
申请号：EP08803417.8
申请日：2008-08-29
申请人： Vito NV
发明人： MULLENS, Steven Hans Rik Wouter , THIJS, Ivo , LUYTEN, Jan Roger , BOUWEN, Wim Louis
IPC分类号： B22F3/22 , B22F7/00 , C04B35/63
CPC分类号： C04B35/6263 , B22F3/1121 , B22F2998/00 , B82Y30/00 , C04B35/62231 , C04B35/62236 , C04B35/62245 , C04B35/6225 , C04B35/62259 , C04B35/62268 , C04B35/62281 , C04B35/62295 , C04B35/6266 , C04B35/634 , C04B2235/5252 , C04B2235/5264 , C04B2235/5284 , C04B2235/6021 , C04B2235/6026 , C04B2235/656 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/661 , Y10T428/24355 , Y10T428/24802 , B22F3/227
摘要： The present invention relates to a method for producing a three-dimensional macroporous filament construct comprising interconnected microporous filaments showing a suitable surface roughness and microporosity. The method comprises the steps of: a) preparing a suspension comprising particles of a predetermined material, a liquid solvent, one or more binders and optionally one or more dispersants, b) depositing said suspension in the form of filaments in a predetermined three-dimensional pattern, preferably in a non-solvent environment, thereby creating a three-dimensional filament-based porous structure, c) inducing phase inversion, whereby said filaments are transformed from a liquid to a solid state, by exposing said filaments during the deposition of the filaments with a non-solvent vapour and to a liquid non-solvent, d) thermally treating the structure of step d) by calcining and sintering said structure. The invention further provides a three-dimensional macroporous filament construct comprising interconnected microporous filaments showing a specific surface roughness and microporosity. The invention also relates to various uses of the construct, including its use for the manufacture of a biomedical product, such as a synthetic bone implant or bone graft.

4. 发明授权

EP1537060B1 KERAMISCHE HOHLFASERN HERGESTELLT AUS NANOSKALIGEN PULVERTEILCHEN 有权
标题翻译：陶瓷中空纤维生产的FROM纳米粉末
公开(公告)号：EP1537060B1
公开(公告)日：2008-10-15
申请号：EP02807705.5
申请日：2002-08-30
申请人： ItN Nanovation AG
发明人： NONNINGER, Ralph
IPC分类号： C04B35/622
CPC分类号： C04B35/62277 , B01D67/0041 , B01D69/08 , B01D69/087 , B01D71/024 , B32B2307/75 , B82Y30/00 , C04B20/0056 , C04B35/486 , C04B35/62236 , C04B35/6225 , C04B35/62259 , C04B35/62281 , C04B35/62286 , C04B35/62295 , C04B35/6263 , C04B35/6264 , C04B35/63 , C04B35/632 , C04B35/634 , C04B35/63424 , C04B35/6365 , C04B2235/3217 , C04B2235/3225 , C04B2235/3244 , C04B2235/3246 , C04B2235/449 , C04B2235/526 , C04B2235/5264 , C04B2235/5284 , C04B2235/6021 , C04B2235/77 , C04B2235/80 , Y10S264/19 , Y10T428/2913 , Y10T428/2975 , C04B14/46
摘要： The invention relates to a method for producing ceramic hollow fibers from nanoscale particles and to hollow fibers produced in such a manner. The inventive method is characterized in that the ceramic material has a solids content of > 25 % by volume, preferably > 30 % by volume and is processed by means of extrusion and spinning. The hollow fiber is sintered according to conventional sintering methods. A hollow fiber produced in this manner is used for metal, polymer and ceramic matrix reinforcements, for artificial organs, for microsystems technology components, for fiber optical waveguides, for ceramic membranes, for solid electrolyte in fuel cells (SOFC), for tissue engineering and for producing extremely light ceramic parts, such as heat shields or brake systems, that are subjected to temperature stresses. The inventive ceramic batch can also be processed by means of silk screening whereby resulting in the production of filigree structures over the ceramic silk screening.

5. 发明公开

EP1537060A1 KERAMISCHE HOHLFASERN HERGESTELLT AUS NANOSKALIGEN PULVERTEILCHEN 有权
标题翻译： KERAMISCHE HOLLFASERN HERGESTELLT AUS NANOSKALIGEN PULVERTEILCHEN
公开(公告)号：EP1537060A1
公开(公告)日：2005-06-08
申请号：EP02807705.5
申请日：2002-08-30
申请人： ITN NANOVATION GMBH
发明人： NONNINGER, Ralph
IPC分类号： C04B35/622
CPC分类号： C04B35/62277 , B01D67/0041 , B01D69/08 , B01D69/087 , B01D71/024 , B32B2307/75 , B82Y30/00 , C04B20/0056 , C04B35/486 , C04B35/62236 , C04B35/6225 , C04B35/62259 , C04B35/62281 , C04B35/62286 , C04B35/62295 , C04B35/6263 , C04B35/6264 , C04B35/63 , C04B35/632 , C04B35/634 , C04B35/63424 , C04B35/6365 , C04B2235/3217 , C04B2235/3225 , C04B2235/3244 , C04B2235/3246 , C04B2235/449 , C04B2235/526 , C04B2235/5264 , C04B2235/5284 , C04B2235/6021 , C04B2235/77 , C04B2235/80 , Y10S264/19 , Y10T428/2913 , Y10T428/2975 , C04B14/46
摘要： The invention relates to a method for producing ceramic hollow fibers from nanoscale particles and to hollow fibers produced in such a manner. The inventive method is characterized in that the ceramic material has a solids content of > 25 % by volume, preferably > 30 % by volume and is processed by means of extrusion and spinning. The hollow fiber is sintered according to conventional sintering methods. A hollow fiber produced in this manner is used for metal, polymer and ceramic matrix reinforcements, for artificial organs, for microsystems technology components, for fiber optical waveguides, for ceramic membranes, for solid electrolyte in fuel cells (SOFC), for tissue engineering and for producing extremely light ceramic parts, such as heat shields or brake systems, that are subjected to temperature stresses. The inventive ceramic batch can also be processed by means of silk screening whereby resulting in the production of filigree structures over the ceramic silk screening.
摘要翻译：本发明涉及一种从纳米尺寸颗粒制造陶瓷中空纤维的方法和以这种方式生产的中空纤维。本发明的方法的特征在于，陶瓷材料的固体含量> 25体积％，优选> 30体积％，并通过挤出和纺丝加工。中空纤维根据常规烧结方法烧结。以这种方式生产的中空纤维用于人造器官，微系统技术部件，纤维光波导，陶瓷膜，燃料电池（SOFC）中的固体电解质，组织工程和金属，用于生产经受温度胁迫的极轻的陶瓷部件，例如隔热罩或制动系统。本发明的陶瓷批料也可以通过丝网印染加工，从而导致在陶瓷丝网筛选上生产丝状结构。

6. 发明公开

EP0439844A2 SiC1-Gruppen enthaltende Silazanpolymere, Verfahren zu ihrer Herstellung, aus ihnen herstellbare, Siliciumnitrid enthaltende keramische Materialien, sowie deren Herstellung 失效
标题翻译：硅氮烷聚合物SIC1基的，它们的制备方法，可以从他们，氮化硅，陶瓷材料，和它们的制备来制备。
公开(公告)号：EP0439844A2
公开(公告)日：1991-08-07
申请号：EP90125843.4
申请日：1990-12-31
申请人： HOECHST AKTIENGESELLSCHAFT
发明人： Vaahs, Tilo, Dr. , Kleiner, Hans-Jerg, Dr. , Brück, Martin
IPC分类号： C08G77/62 , C08G77/60 , C04B35/58
CPC分类号： C01B21/068 , C04B35/589 , C04B35/62295 , C04B2235/465 , C04B2235/5264 , C04B2235/721 , C08G77/24 , C08G77/62
摘要： Die Erfindung betrifft neue, SiCl-Gruppen enthaltende Silazanpolymere, ihre Herstellung, ihre Weiterverarbeitung zu Siliziumnitrid enthaltendem keramischen Material, sowie dieses Material selbst. Zur Herstellung der SiCl-Gruppen enthaltenden Silazanpolymeren werden α,ω-Chlorsilazane der Formel I

worin m Werte zwischen 1 und 12 annimmt und -(Si) ein Silylrest der Formel -SiHR¹Cl, -SiR²R³Cl, -SiR⁴Cl₂, -SiR⁵Cl-CH₂CH₂-SiR⁵Cl₂, oder -SiCl₂-CH₂CH₂-SiR⁶Cl₂ und R = C₁-C₆-Alkyl oder C₂-C₆-Alkenyl und unabhängig voneinander R¹-R⁶ = H, C₁-C₆-Alkyl oder C₂-C₆-Alkenyl ist, auf Temperaturen von 100°C bis 400°C erhitzt.
Die erfindungsgemäßen SiCl-Gruppen enthaltenden Silazanpolymeren können durch Umsetzung mit Ammoniak in Polysilazane umgewandelt werden, die ihrerseits zu Siliziumnitrid enthaltenden keramischen Materialien pyrolysiert werden können.
摘要翻译：本发明涉及新的，含有SiCl基硅氮烷聚合物，其制备方法，其进一步处理以产生含氮化硅陶瓷材料，而这种材料本身。为了制备含有硅氮烷聚合物的SiCl基是下式的α，ω-chlorosilazane I 其中m值式的基团的甲硅烷-SiHR¹Cl，-SiR²R³Cl，-SiR <4> CL2，-SiR <5> CL-CH2CH2-SIR（Si）的<5> CL2，或-SiCl2-CH2CH2-SIR < - 取1-12和 6> Cl 2和R = C1-C6烷基C2-C6链烯基，并且独立地或一个另一条R-R <6> = H，C1-C6烷基或C2-C6链烯基，于100℃的温度至400 加热℃。含有根据本发明的SiCl基硅氮烷聚合物可以通过在聚硅氮烷氨反应被转化，反过来，陶瓷材料含氮化硅可被热解。

7. 发明公开

EP0357176A2 Production of ultrastructural ceramics 失效
标题翻译： Herstellung von Keramiken mit einer Ultrastruktur。
公开(公告)号：EP0357176A2
公开(公告)日：1990-03-07
申请号：EP89304258.0
申请日：1989-04-27
申请人： Sullivan, Thomas Milton
发明人： Sullivan, Thomas Milton
IPC分类号： C04B35/58 , C04B35/56 , C04B35/64 , D01F9/10
CPC分类号： C04B35/65 , C04B35/571 , C04B35/58 , C04B35/58014 , C04B35/58028 , C04B35/58042 , C04B35/589 , C04B35/591 , C04B35/62295 , C04B35/645 , Y10S264/11
摘要： A process for the production of high-performance ceramics and ceramic precursors is disclosed which comprises reacting an organometallic precursor with a reactant in a supercritical fluid and exposing the organometallic product to a ceramic material. A critical temperature (or pressure) is required to produce the supercritical fluid which is the maximum temperature (or pressure) at which a gas or vapor may be liquified by the application of a critical pressure (or temperature).
Nitrogen-containing ceramics such as nitrides, oxynitrides and carbonnitrides, and carbide ceramics are produced by reacting precursors such as alkyl halosilanes and dialkyl silanes in the presence of a supercritical fluid such as nitrogen, hydrogen, ammonia and mixtures thereof for the nitrogen-containing ceramics and in the presence of hydrocarbons, hydrogen or mixtures thereof for the carbide ceramics. The high performance ceramics produced find particular application in the automobile industry.
摘要翻译：公开了一种用于生产高性能陶瓷和陶瓷前体的方法，其包括使有机金属前体与超临界流体中的反应物反应并将有机金属产物暴露于陶瓷材料。需要临界温度（或压力）以产生超临界流体，超临界流体是通过施加临界压力（或温度）使气体或蒸汽液化的最高温度（或压力）。通过使诸如烷基卤代硅烷和二烷基硅烷的前体在氮，氢，氨等超临界流体及其混合物的存在下使含氮陶瓷反应，制备氮化物，氮氧化物和碳氮化物等含氮陶瓷，以及碳化物陶瓷。并且在碳氢化合物，氢气或其混合物的存在下，用于碳化物陶瓷。制造的高性能陶瓷在汽车工业中得到了应用。

8. 发明授权

EP3004214B1 POLYDISILAZANES PREPARED FROM BORON-CONTAINING ADDITIVES 有权
标题翻译：由含硼的添加剂制备的聚二硅氮烷
公开(公告)号：EP3004214B1
公开(公告)日：2017-03-01
申请号：EP14724916.3
申请日：2014-04-09
申请人： General Electric Company
发明人： RUBINSZTAJN, Slawomir , LITTLEJOHN, Matthew, Hal , MILLS, Ryan, Christopher , DAVIS, Peter, Kennedy
IPC分类号： C08G77/56 , C04B35/622 , C08G77/62 , C08G77/60
CPC分类号： C08G77/54 , C01B32/956 , C04B35/62281 , C04B35/62295 , C04B35/6269 , C04B2235/3409 , C04B2235/483 , C04B2235/5264 , C04B2235/9661 , C08G77/60 , C08G77/62 , D01F9/10

9. 发明授权

EP2952495B1 METHOD FOR COMBINED DESIZING AND INTERFACE COATING OF FIBERS FOR CERAMIC MATRIX COMPOSITES 有权转让
标题翻译：方法为陶瓷基质化合物纤维的组合的脱浆和表面涂层
公开(公告)号：EP2952495B1
公开(公告)日：2017-01-04
申请号：EP15170431.9
申请日：2015-06-03
申请人： United Technologies Corporation
发明人： SHEEDY, Paul , MAGDEFRAU, Neal
IPC分类号： C04B35/628 , C04B35/80
CPC分类号： C04B35/62868 , C04B35/62277 , C04B35/62281 , C04B35/62295 , C04B35/62844 , C04B35/6286 , C04B35/62871 , C04B35/62894 , C04B35/76 , C04B35/80 , C04B2235/524 , C04B2235/5244 , C04B2235/5264 , C04B2235/5284 , C04B2235/5288 , C04B2235/6581

10. 发明授权

EP0357176B1 Production of ultrastructural ceramics 失效
标题翻译：制造具有超结构的陶瓷。
公开(公告)号：EP0357176B1
公开(公告)日：1994-07-06
申请号：EP89304258.0
申请日：1989-04-27
申请人： Sullivan, Thomas Milton
发明人： Sullivan, Thomas Milton
IPC分类号： C04B35/58 , C04B35/56 , C04B35/64 , D01F9/10
CPC分类号： C04B35/65 , C04B35/571 , C04B35/58 , C04B35/58014 , C04B35/58028 , C04B35/58042 , C04B35/589 , C04B35/591 , C04B35/62295 , C04B35/645 , Y10S264/11

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