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1. 发明公开

EP2377829A3 Reversible lichtempfindliche Beschichtung und Verfahren zu deren Herstellung 审中-公开
标题翻译：可逆光敏涂层和它们的制备方法
公开(公告)号：EP2377829A3
公开(公告)日：2012-11-21
申请号：EP11162669.3
申请日：2011-04-15
申请人： Hardman, Christine , Rössler, Karin Barbara
发明人： Hardman, Christine
IPC分类号： C03C4/06 , C03C8/14 , C09K9/00 , C04B41/50
CPC分类号： C03C8/14 , C03C4/06 , C04B41/009 , C04B41/5022 , C04B41/86 , C04B2111/80 , C09D1/00 , C09D5/29 , C09D7/61 , C09K9/00 , C04B33/00 , C04B41/4539 , C04B41/4549 , C04B41/4574 , C04B41/5089 , C04B2103/0015
摘要： Gegenstand der Erfindung ist eine auf der Nanotechnologie basierende lichtempfindliche Beschichtung mit der Eigenschaft, in einem reversiblen Prozess, allein unter Lichteinwirkung, ohne thermische Behandlung, die Farbe zu wechseln.
Im Unterschied zu bekannten lichtempfindlichen Glasuren verbessert der eingebrannte Nanoglasurversatz die optischen Eigenschaften und reversiblen Prozesse im Glasurraum. Die Abbildungsqualität, die Schärfe und der Kontrast der Lichtbilder werden signifikant verbessert und die Reaktionsfähigkeit der Beschichtung mit Licht massgeblich erhöht. Es ermöglicht das präzisere Erzeugen von temporären Licht- und Schattenbildern. Zusätzlich gibt es viele Kombinationen mit temporären und fixierten Bildern auf einem Träger.
Dies eröffnet Möglichkeiten in Architektur und Kunst, in der Verwendung als Wand- oder Bodenplatte, in einem Schwimmbad, an einem Brunnen oder als Bank, Tisch, Stuhl oder Möbel und Geschirr und öffnet das Feld für Interaktionen des Menschen mit dem Material und seiner Umgebung.

2. 发明授权

EP1015394B1 IMPROVED PHOTOCHROMIC GLASSES 失效
标题翻译：改进的光致变色玻璃
公开(公告)号：EP1015394B1
公开(公告)日：2008-06-04
申请号：EP98906027.2
申请日：1998-01-29
申请人： Corning S.A.
发明人： BROCHETON, Yves, A., H. , PRASSAS, Michel
IPC分类号： C03C4/06 , C03C3/11 , C03C3/093 , C03C3/095
CPC分类号： C03C4/06 , C03C3/093 , C03C3/095 , C03C3/11
摘要： The invention concerns photochromic glasses with improved properties having the following composition, in wt.%: SiO2: 51-66, B2O3: 15-23, Al2O3: 3-10, ZrO2: 2.5-11, TiO2: 0-1, Li2O: 3-7, Na2O: 0-8, K2O: 2-9, Ag: 0.080-0.30, CuO⊃ 0.0020-0.0130, Cl: 0.1-0.6, Br: 0.040-0.3, MgO: 0-3, CaO: 0-3, SrO: 0-3, BaO: 0-3, Nb2O5: 0-1, La2O3: 0-8, Y2O3: 0-8, with 0.2∫Ag/(Cl+Br)≤0.5, Br/(Cl+Br)⊃0.15, 0.5≤La2O3 + Y2O3≤8, TiO2 + Nb2O5≤1.2, 10≤Al2O3 + ZrO2≤17, MgO + CaO + SrO + BaO≤6. Use for the production of ophthalmic lenses.

3. 发明公开

EP1015394A4 IMPROVED PHOTOCHROMIC GLASSES 失效
标题翻译：改进的光致变色玻璃
公开(公告)号：EP1015394A4
公开(公告)日：2005-01-05
申请号：EP98906027
申请日：1998-01-29
申请人： CORNING SA
发明人： BROCHETON YVES A H , PRASSAS MICHEL
IPC分类号： C03C3/091 , C03C3/093 , C03C3/095 , C03C3/11 , C03C4/06
CPC分类号： C03C4/06 , C03C3/093 , C03C3/095 , C03C3/11
摘要： The invention concerns photochromic glasses with improved properties having the following composition, in wt.%: SiO2: 51-66, B2O3: 15-23, Al2O3: 3-10, ZrO2: 2.5-11, TiO2: 0-1, Li2O: 3-7, Na2O: 0-8, K2O: 2-9, Ag: 0.080-0.30, CuO⊃ 0.0020-0.0130, Cl: 0.1-0.6, Br: 0.040-0.3, MgO: 0-3, CaO: 0-3, SrO: 0-3, BaO: 0-3, Nb2O5: 0-1, La2O3: 0-8, Y2O3: 0-8, with 0.2∫Ag/(Cl+Br)≤0.5, Br/(Cl+Br)⊃0.15, 0.5≤La2O3 + Y2O3≤8, TiO2 + Nb2O5≤1.2, 10≤Al2O3 + ZrO2≤17, MgO + CaO + SrO + BaO≤6. Use for the production of ophthalmic lenses.

4. 发明公开

EP0984929A4 NAPHTHOPYRAN DERIVATIVES, COMPOSITIONS AND (CO)POLYMERS MATRICES CONTAINING SAME 失效
标题翻译： NAPHTHOPYRANDERIVATE，制剂和含（共）聚合物基质
公开(公告)号：EP0984929A4
公开(公告)日：2000-03-15
申请号：EP98911739
申请日：1998-03-17
申请人： CORNING INC
发明人： BREYNE OLIVIER , CHAN YOU-PING
IPC分类号： G02C7/10 , C03C1/10 , C03C4/06 , C03C14/00 , C07D311/92 , C08F24/00 , C08K5/1545 , C08L101/00 , C09K9/02 , G02B5/23 , C07D205/02 , C07D207/02 , C07D223/04 , C07D225/02 , C07D313/18 , C07D333/02 , C07D337/04 , C07D337/16 , C07D409/10 , C08K5/15
CPC分类号： C08F24/00 , C03C1/10 , C03C4/06 , C03C14/008 , C03C2214/17 , C07D311/92 , C09K9/02
摘要： For subject, the present invention has novel naphthopyran derivatives of formula (I) optionally substituted in position(s) 2, 3, 4, 6, 7, 8, 9 or/and 10; the substituent Z in position 5 being of formula -C(R1)(R2)(OR3). The invention also relates to compositions and (co)polymer matrices containing such derivatives. Said derivatives have interesting photochromic properties.

5. 发明公开

EP0931029A1 METHOD OF MAKING A POLARIZING GLASS 失效
标题翻译：工艺用于制造玻璃POLARISTERENDEM
公开(公告)号：EP0931029A1
公开(公告)日：1999-07-28
申请号：EP97941471.0
申请日：1997-09-08
申请人： CORNING INCORPORATED
发明人： GROSSMAN, David, G. , VANDEGRIFT, Lisa, R. , WHITBRED, George, N., III , WILLIAMS, Joseph, M.
IPC分类号： G02B5 , C03B23 , C03B32 , C03C3 , C03C4 , C03C10 , C03C14 , C03C15 , C03C23 , G02B1
CPC分类号： C03C4/06 , C03B23/0006 , C03B32/02 , C03C14/006 , C03C23/007
摘要： A method of producing a polarizing glass article that exhibits a broad band of high contrast polarizing properties in the infrared region of the radiation spectrum, that is phase-separated or exhibits photochromic properties based on silver, copper, or copper-cadmium halide crystals or a combination thereof precipitated in the glass and having a size in the range of 200-5000 Angströms, and that has a surface layer containing elongated silver, copper, or copper cadmium metal particles, or a mixture of same, the method comprising the step of thermally forming and precipitating large halide crystals by subjecting the glass article to a time-temperature cycle in which the temperature is at least 75 °C above the glass softening point. The figure is a graphical representation of stress levels in psi versus center wavelengths (CWLs) in nm, where center wavelength is defined as the center of a given range of polarizing capability. Specifically, the stess levels required to achieve a given center wavelength is compared for two heat treatment cycles. The upper line (A) represents data for the standard heat treatment of polarizing glasses; 710 °C for 4 hours. Line (B) represents data for the new high temperature heat treatment of 750 °C for 8 hours.

6. 发明公开

EP0909744A3 Method of forming glass having integral polarizing and non-polarizing regions 有权
标题翻译：形成具有整体偏振和非偏振区域的玻璃的方法
公开(公告)号：EP0909744A3
公开(公告)日：1999-04-28
申请号：EP98116599.6
申请日：1998-09-02
申请人： CORNING INCORPORATED
发明人： Sarhangi, Ahmad , Gill, Sherry Jeanne
IPC分类号： C03C3/064 , C03C3/11 , C03C4/06 , C03C8/10 , C03C8/14 , C03C14/00 , C03C17/04 , C03C23/00 , G02B5/30
CPC分类号： C03C4/00 , C03C3/064 , C03C3/11 , C03C4/06 , C03C8/10 , C03C8/14 , C03C14/006 , C03C17/04 , C03C23/00 , C03C2214/08 , C03C2214/30 , C03C2218/33 , G02B5/3033 , G02B6/126 , G02B6/13 , G02B2006/12116
摘要： Method of making polarizing glass having integral polarizing and non-polarizing regions disclosed.
摘要翻译：公开了制造具有整体偏振和非偏振区域的偏振玻璃的方法。

7. 发明授权

EP0353834B1 High index photochromic glasses 失效
标题翻译：光致变色玻璃具有高折射率。
公开(公告)号：EP0353834B1
公开(公告)日：1994-05-11
申请号：EP89302737.5
申请日：1989-03-20
申请人： Corning Glass Works
发明人： Prassas, Michel
IPC分类号： C03C4/06 , C03C3/068 , C03C3/066 , C03C3/064 , C03C3/11
CPC分类号： C03C4/06 , C03C3/064 , C03C3/066 , C03C3/068 , C03C3/11

8. 发明公开

EP0384555A1 Method for making infrared polarizing glasses 失效
标题翻译： Verfahren zur Herstellung infrarot polarisierenderGläser。
公开(公告)号：EP0384555A1
公开(公告)日：1990-08-29
申请号：EP90300038.8
申请日：1990-01-03
申请人： Corning Incorporated
发明人： Jones, Kelly Evan , Noll, Frederick Ernest
IPC分类号： C03C4/06 , C03B32/00
CPC分类号： C03C3/11 , C03C4/06
摘要： This invention is directed to the preparation of glass articles exhibiting a relatively broad band of high contrast polarizing properties in the infrared region of the radiation spectrum from glasses containing silver halide particles selected from the group consisting of AgCl, AgBr, and AgI. The inventive method comprises the following five general steps:

(a) melting a batch for a glass containing silver and at least one halide selected from the group consisting of chloride, bromide, and iodide;
(b) cooling and shaping said melt into a glass article of a desired configuration;
(c) subjecting said glass article to a temperature at least above the strain point, but not in excess of 75°C above the softening point of the glass, for a sufficient length of time to cause the generation of silver halide particles therein selected from the group consisting of AgCl, AgBr, and AgI, said particles ranging in size between about 200-5000Å;
(d) elongating said glass article under stress at a temperature above the annealing point, but below that where said glass exhibits a viscosity of about 10⁸ poises, such that said silver halide particles are elongated to an aspect ratio of at least 5:1 and aligned in the direction of the stress; and, thereafter,
(e) exposing said elongated glass article to a reducing environment at a pressure greater than atmospheric pressure and at a temperature above about 250°C, but no higher than about 25°C above the annealing point of the glass, for a period of time sufficient to develop a reducing surface layer on said glass article having a thickness of at least 10 microns wherein at least a portion of said elongated silver halide particles are reduced to elemental silver particles having aspect ratios greater than 2:1 which are deposited in and/or upon said elongated particles.

The single figure illustrates the improved contrast and bandwidth achieved by the process (curves B, C and D).
摘要翻译：本发明涉及在含有选自AgCl，AgBr和AgI的卤化银颗粒的玻璃的辐射光谱的红外区域中具有相对宽带的高对比度偏振特性的玻璃制品的制备。本发明的方法包括以下五个一般步骤：（a）熔化含有银和至少一种选自氯化物，溴化物和碘化物的卤化物的玻璃的批料; （b）将所述熔体冷却和成形为所需构型的玻璃制品; （c）使所述玻璃制品至少高于应变点的温度，但不超过玻璃软化点的75℃，持续足够长的时间以引起其中选出的卤化银颗粒由AgCl，AgBr和AgI组成的组，所述颗粒的尺寸范围为约200-5000安培; （d）在高于退火点的温度下在应力下拉伸所述玻璃制品，但低于所述玻璃的粘度为约10 8泊的温度，使得所述卤化银颗粒被拉长至至少5的纵横比：1并在应力方向对齐; 然后（e）将所述细长玻璃制品暴露于压力大于大气压的压力下，并在高于玻璃退火温度的约250℃，但不高于约25℃的温度下，足以在所述玻璃制品上形成具有至少10微米厚度的还原表面层的时间段，其中所述细长卤化银颗粒的至少一部分被还原成具有高于2:1的纵横比的元素银颗粒，它们是沉积在所述细长颗粒中和/或之上。单个图示出了通过该过程（曲线B，C和D）实现的改善的对比度和带宽。

9. 发明授权

EP0164884B1 Ultraviolet absorbing photochromic glass of low silver content 失效
标题翻译： ULTRAVIOLET吸收低铁含量的光致变色玻璃
公开(公告)号：EP0164884B1
公开(公告)日：1989-08-23
申请号：EP85303221.7
申请日：1985-05-07
申请人： Corning Glass Works
发明人： Araujo, Roger Jerome , Kerko, David Joseph , Morse, David Lathrop , Hares, George Bigelow , Morgan, David William
IPC分类号： C03C4/06 , C03C4/08
CPC分类号： C03C4/06 , C03C3/091

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