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    • 5. 发明公开
    • VERFAHREN ZUR HERSTELLUNG VON GLÄSERN, GLASKERAMIKEN UND DEREN VERWENDUNG
    • VERFAHREN ZUR HERSTELLUNG VONGLÄSERN,GLASKERAMIKEN UND DEREN VERWENDUNG
    • EP2817265A1
    • 2014-12-31
    • EP13704477.2
    • 2013-02-18
    • Schott AG
    • LENTES, Frank-ThomasNAUMANN, KarinSCHIFFNER, UlrichSIEBERS, FriedrichMÜLLER, ChristianSCHÖNBERGER, KlausWEISS, Evelin
    • C03B5/225C03C10/12C03C1/00
    • C03B5/225C03C1/004C03C3/085C03C3/087C03C3/095C03C10/0009C03C10/0027
    • The invention relates to a method for producing bubble-free glasses, in which a glass mixture that is arsenic-free and antimony-free with the exception of any unavoidable raw material impurities as well as at least one sulphate compound and SnO
      2 as refining agents are used. The glass mixture comprising refining agents is melted in a melting tank (1), melting down taking place and a primary refinement being carried out in a first region (10) of the melting tank (1), an average melting temperature (T
      1 ) being set at T
      1 > 1560 °C and an average melt residence time (t
      1 ) being set at t
      1 > 2 hours in said first region (10). The proportion of SO
      3 resulting from the decomposition of the sulphate compound is reduced to less than 0.002 wt.% as the primary refinement is being carried out. A secondary refinement is carried out in a second region (20) of the melting tank (1), an average melting temperature (T
      2 ) being set at T
      2 > 1640 °C and an average melt residence time (t
      2 ) being set at t
      2 > 1 hour in the second region (20).
    • 本发明涉及一种生产无气泡玻璃的方法,其中除了任何不可避免的原料杂质以及至少一种硫酸盐化合物和SnO 2作为澄清剂以外,无砷和无锑的玻璃混合物 被使用。 包含澄清剂的玻璃混合物在熔化槽(1)中熔化,熔化并在熔化槽(1)的第一区域(10)中进行初步精炼,平均熔化温度(T 1) 设定为T 1> 1560℃,并且在所述第一区域(10)中将平均熔体停留时间(t 1)设定为t 1> 2小时。 随着主要精炼的进行,由硫酸盐化合物分解产生的SO 3的比例减少到小于0.002重量%。 在熔化槽(1)的第二区域(20)中进行二次精炼,平均熔化温度(T 2)被设定为T 2> 1640℃且平均熔体停留时间(t 2)被设定 在第二区域(20)中t 2> 1小时。