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    • 2. 发明公开
    • A METHOD FOR INCREASING THE CAPACITY OF AN AMMONIA PLANT
    • VERFAHREN ZURERHÖHUNGDERKAPAZITÄTEINER AMMONIAKANLAGE
    • EP3095760A1
    • 2016-11-23
    • EP15168757.1
    • 2015-05-21
    • Casale SA
    • Panza, SergioPasco, Luca
    • C01C1/04C01B3/02B01D3/38
    • C01C1/047B01D3/38C01B3/025C01B2203/0205C01B2203/0475C01B2203/068C01C1/0447Y02P20/52
    • A method for treatment of process condensate (1) in an ammonia plant, wherein the ammonia plant comprises a front-end section producing a make-up gas and a synthesis section where the make-up gas is reacted to ammonia, and said process condensate (1) is collected from one or more equipment of the ammonia plant and is an aqueous solution comprising ammonia, carbon dioxide and methanol. Said method comprises: stripping said process condensate with low-pressure steam (4), obtaining a vapour phase (5) comprising ammonia, carbon dioxide and methanol stripped from the process condensate; condensing said vapour phase, obtaining a solution (11) enriched of ammonia and methanol (11); re-introducing a first portion (12) of said solution to said stripping environment; recycling a second portion (13) of said solution to said ammonia plant.
    • 一种用于处理氨装置中的工艺冷凝物(1)的方法,其中所述氨装置包括产生补充气体的前端部分和补充气体与氨反应的合成部分,所述工艺冷凝物 (1)从氨厂的一个或多个设备收集,并且是包含氨,二氧化碳和甲醇的水溶液。 所述方法包括:用低压蒸汽(4)汽提所述工艺冷凝物,得到包含氨,二氧化碳和从工艺冷凝液中除去的甲醇的气相(5); 冷凝所述气相,得到富含氨和甲醇的溶液(11)(11); 将所述溶液的第一部分(12)重新引入所述剥离环境; 将所述溶液的第二部分(13)再循环到所述氨装置。
    • 4. 发明公开
    • AMMONIA SYNTHESIS SYSTEM AND METHOD
    • 氨合成系统和方法
    • EP3190088A1
    • 2017-07-12
    • EP15837863.8
    • 2015-04-21
    • Mitsubishi Heavy Industries, Ltd.
    • SAKURAI, MikiyaTANAKA, YukioOKUZUMI, NaoyaOSORA, HiroyukiHIRAYAMA, Haruaki
    • C01C1/02
    • C01C1/047B01D53/002B01J23/462B01J23/58B01J23/63C01C1/02C01C1/0411C09K5/04F25B9/002Y02P20/52
    • The present invention comprises: an ammonia converter 13 that synthesizes ammonia; a discharge line L 11 that discharges a synthesis gas 14 which includes an obtained ammonia gas 12A and an unreacted source gas 11A; a water cooled condenser 16 that is interdisposed in the discharge line L 11 and cools the synthesis gas 14 with a coolant 15; an ammonia separator 17 into which the cooled synthesis gas 14A is introduced, said separator 17 separating the ammonia gas 12A and liquid ammonia 12B; a source return line L 12 that returns the source gas including the separated ammonia gas 12A to the ammonia converter 13 side as a return source gas 11B; and a compressor 18 that is interdisposed in the source return line L 12 and compresses the return source gas 11B. The ammonia concentration in the return source gas 11B intro - duced into the ammonia converter 13 is 5 mol% or more and an ammonia synthesis catalyst that synthesizes the ammonia gas 12A in the ammonia converter 13 is a ruthenium catalyst.
    • 本发明包括:合成氨的氨转化器13; 排出包含获得的氨气12A和未反应的原料气体11A的合成气体14的排出管线L11; 水冷冷凝器16,其插置在排放管线L11中并用冷却剂15冷却合成气体14; 将冷却的合成气体14A导入其中的氨分离器17,所述分离器17分离氨气12A和液氨12B; 将包含分离出的氨气12A的原料气体作为返回原料气体11B返回到氨气转换器13侧的原料返回管线L12; 以及插入到源返回管线L12并压缩返回源气体11B的压缩机18。 在氨转换器13中流入的返回原料气体11B中的氨浓度为5摩尔%以上,在氨转换器13中合成氨气体12A的氨合成催化剂为钌催化剂。
    • 5. 发明公开
    • AMMONIA SYNTHESIS SYSTEM AND METHOD
    • SYSTEM UND VERFAHRENFÜRAMMONIAKSYNTHESE
    • EP3190088A4
    • 2017-08-09
    • EP15837863
    • 2015-04-21
    • MITSUBISHI HEAVY IND LTD
    • SAKURAI MIKIYATANAKA YUKIOOKUZUMI NAOYAOSORA HIROYUKIHIRAYAMA HARUAKI
    • C01C1/02B01J23/46C01C1/04
    • C01C1/047B01D53/002B01J23/462C01C1/02C01C1/0411C09K5/04F25B9/002Y02P20/52
    • The present invention comprises: an ammonia converter 13 that synthesizes ammonia; a discharge line L 11 that discharges a synthesis gas 14 which includes an obtained ammonia gas 12A and an unreacted source gas 11A; a water cooled condenser 16 that is interdisposed in the discharge line L 11 and cools the synthesis gas 14 with a coolant 15; an ammonia separator 17 into which the cooled synthesis gas 14A is introduced, said separator 17 separating the ammonia gas 12A and liquid ammonia 12B; a source return line L 12 that returns the source gas including the separated ammonia gas 12A to the ammonia converter 13 side as a return source gas 11B; and a compressor 18 that is interdisposed in the source return line L 12 and compresses the return source gas 11B. The ammonia concentration in the return source gas 11B intro - duced into the ammonia converter 13 is 5 mol% or more and an ammonia synthesis catalyst that synthesizes the ammonia gas 12A in the ammonia converter 13 is a ruthenium catalyst.
    • 本发明包括:合成氨的氨转化器13; 排出包含获得的氨气12A和未反应的原料气体11A的合成气体14的排出管线L11, 水冷冷凝器16,其插置在排放管线L11中并用冷却剂15冷却合成气体14; 将冷却的合成气体14A导入其中的氨分离器17,所述分离器17分离氨气12A和液氨12B; 将包含分离出的氨气12A的原料气体作为返回原料气体11B返回到氨气转换器13侧的原料返回管线L12; 以及与源返回管线L12隔开而压缩返回源气体11B的压缩机18。 在氨转换器13中流入的返回原料气体11B中的氨浓度为5摩尔%以上,在氨转换器13中合成氨气体12A的氨合成催化剂为钌催化剂。