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1. 发明公开

EP3252009A4 PREPARATION METHOD FOR METAL-MODIFIED SAPO MOLECULAR SIEVE 审中-公开
公开(公告)号：EP3252009A4
公开(公告)日：2018-08-01
申请号：EP15879430
申请日：2015-01-30
申请人： DALIAN INST CHEM & PHYSICS CAS
发明人： XIANG XIAO , TIAN PENG , LIU ZHONGMIN , YANG YUE , LIU LIN , YANG MIAO , YANG HONGYI , SANG SHIYUN , HE YANLI
IPC分类号： C01B39/54 , B01D53/86 , B01J29/85 , B01J37/00 , B01J37/06 , B01J37/08 , B01J37/30 , C01B37/08 , C01B39/02 , C07C1/20
CPC分类号： B01J29/85 , B01D53/8628 , B01D2255/50 , B01D2258/06 , B01J37/0018 , B01J37/06 , B01J37/08 , B01J37/30 , B01J2229/183 , C01B37/08 , C01B39/026 , C01B39/54 , C07C1/20 , C07C2529/85
摘要： A preparation method for a metal-modified SAPO molecular sieve is disclosed, characterized in adding a raw powder of the SAPO molecular sieve to a solution containing metal ions for performing ion exchange, and then washing and drying the obtained solid after ion exchange, so as to obtain the metal-modified SAPO molecular sieve. The metal-modified SAPO molecular sieve prepared has a relatively high degree of crystallinity, and the metal elements occupy the ionic positions in the channels and/or cages of the SAPO molecular sieve, and the metal-modified SAPO molecular sieve shows excellent catalytic performance in the catalytic reaction.

2. 发明公开

EP3233804A2 HIERARCHICAL ALUMINOPHOSPHATES AS CATALYSTS FOR THE BECKMANN REARRANGEMENT 有权
标题翻译：用于贝克曼重排催化剂的层状铝氧化物
公开(公告)号：EP3233804A2
公开(公告)日：2017-10-25
申请号：EP15870717.4
申请日：2015-12-09
申请人： Advansix Resins & Chemicals LLC. , University Of Southampton
发明人： LEVY, Alan B. , RAJA, Robert , NEWLAND, Stephanie H. , KEENAN, Scott R. , BARE, Simon R.
IPC分类号： C07D225/02 , C07C251/32 , C07C227/22 , B01J29/85
CPC分类号： B01J29/84 , B01J29/85 , B01J29/89 , B01J35/1057 , B01J35/1061 , B01J2229/183 , C01B37/08 , C01B39/54 , C07D223/10 , C07D225/02
摘要： Methods for producing lactams from oximes by performing a Beckmann rearrangement using a hierarchical porous aluminophosphate catalyst having interconnected microporous and mesoporous networks are provided. Exemplary catalysts include a plurality of weak Brønsted acid active sites, including silicon-containing aluminophosphates having the IZA framework code AFI, such as SAPO-5, CHA, such as SAPO-34, and FAU, such as SAPO-37.
摘要翻译：提供了使用具有互连的微孔和中孔网络的分层多孔铝磷酸盐催化剂通过进行贝克曼重排从肟生产内酰胺的方法。示例性的催化剂包括多个弱布朗斯台德酸活性位点，包括具有IZA框架编码AFI的诸如SAPO-5，CHA，诸如SAPO-34的含硅铝磷酸盐和FAU，诸如SAPO-37。

3. 发明公开

EP3227234A1 ALUMINOPHOSPHATE MOLECULAR SIEVES USING AN ORGANO-1-OXA-4-AZONIUMCYCLOHEXANE COMPOUND 有权
标题翻译：使用有机基-1-氧杂-4-氮杂环己烷化合物的磷酸铝分子筛
公开(公告)号：EP3227234A1
公开(公告)日：2017-10-11
申请号：EP15864721.4
申请日：2015-11-30
申请人： UOP LLC
发明人： YUHAS, Benjamin D. , NICHOLAS, Christopher P. , MILLER, Mark A. , GALEY, Melissa M.
IPC分类号： C01B39/54
CPC分类号： C01B39/54 , B01J29/83 , B01J29/84 , B01J29/85 , B01J37/0018 , B01J37/10 , C01B37/08
摘要： A method for synthesizing an aluminophosphate based molecular sieve is described. The method may include the steps of: (a) preparing an aqueous mixture comprising water, a substituted hydrocarbon, and a 1-oxa-4-azacyclohexane derivative; (b) reacting the aqueous mixture; (c) obtaining a solution comprising an organo-1-oxa-4-azoniumcyclohexane compound; (d) forming a reaction mixture comprising reactive sources of Al, and P, and the solution; and (e) heating the reaction mixture to form the molecular sieve.
摘要翻译：描述了用于合成铝磷酸盐基分子筛的方法。该方法可以包括以下步骤：（a）制备包含水，取代的烃和1-氧杂-4-氮杂环己烷衍生物的含水混合物; （b）使含水混合物反应; （c）获得包含有机-1-氧杂-4-氮鎓环己烷化合物的溶液; （d）形成包含Al和P的反应源的反应混合物和溶液; 和（e）加热反应混合物以形成分子筛。

4. 发明授权

EP2860158B1 METAL-CONTAINING SILICOALUMINOPHOSPHATE MOLECULAR SIEVE HAVING THE RHO FRAMEWORK STRUCTURE AND PROCESS FOR ITS PREPARATION 有权
标题翻译：具有RHO骨架结构的含金属的硅铝磷酸盐分子筛及其制备方法
公开(公告)号：EP2860158B1
公开(公告)日：2017-08-02
申请号：EP12878414.7
申请日：2012-06-08
申请人： Dalian Institute Of Chemical Physics, Chinese Academy of Sciences
发明人： TIAN, Peng , SU, Xiong , LIU, Zhongmin , FAN, Dong , ZHANG, Ying , YANG, Yue
IPC分类号： C01B39/54 , B01J20/18 , B01J20/30 , B01J29/85 , C07C45/32
CPC分类号： C01B39/54 , B01J20/18 , B01J20/3078 , B01J29/85 , B01J37/082

5. 发明公开

EP3153471A1 SYNTHESIS OF SAPO-18 AND THE CATALYTIC APPLICATIONS THEREOF 审中-公开
标题翻译：合成VAN SAPO-18在KATALYTISCHE VERWENDUNGEN DAVON
公开(公告)号：EP3153471A1
公开(公告)日：2017-04-12
申请号：EP15802461.2
申请日：2015-06-03
申请人： Consejo Superior de Investigaciones Cientificas (CSIC) , Universidad Politécnica de Valencia
发明人： CORMA CANÓS, Avelino , MOLINER MARÍN, Manuel , MARTÍNEZ FRANCO, Raquel
IPC分类号： C01B39/54 , B01J29/85
CPC分类号： B01J29/85 , B01J29/7015 , B01J29/723 , B01J29/743 , B01J29/763 , B01J37/0018 , B01J37/009 , B01J37/04 , B01J37/10 , C01B39/54 , C07D211/14 , C30B7/10 , C30B29/14
摘要： The invention relates to the synthesis of silicoaluminophosphate and metal silicoaluminophosphate polymorphs of the molecular sieve SAPO-18 using cyclic quaternary ammoniums as organic structure-directing agents (OSDA), and to the use thereof as a catalyst.
摘要翻译：本发明涉及使用环状季铵作为有机结构导向剂（OSDA）的分子筛SAPO-18的硅铝磷酸盐和金属硅铝磷酸盐多晶型物的合成及其作为催化剂的用途。

6. 发明公开

EP2660203A4 METHOD FOR SYNTHESIZING SAPO MOLECULAR SIEVE BY SOLVOTHERMAL METHOD AND CATALYST PREPARED THEREBY 失效
标题翻译：法合成SAPO分子七个由SOLVOTHERMISCHES过程，并在这个过程中制得的催化剂
公开(公告)号：EP2660203A4
公开(公告)日：2017-04-12
申请号：EP11852524
申请日：2011-06-24
申请人： DALIAN INST CHEMICAL PHYSICS CAS
发明人： TIAN PENG , LIU ZHONGMIN , ZHANG YING , FAN DONG , SU XIONG
IPC分类号： C01B39/54 , B01J29/85 , C01B37/08
CPC分类号： B01J29/85 , C01B37/08 , C01B39/54 , C07C1/20 , C07C2529/85 , Y02P30/42
摘要： A solvothermal synthesis process of the SAPO molecular sieves and catalysts prepared thereby are provided. The synthesis process comprises the following steps: a) an organic amine, an aluminum source, a phosphorus source, a silicon source, and water are mixed in a molar ratio of 6-30 : 1 : 0.5-5 : 0.01-1.0 : 0.1-15, to obtain an initial mixture for preparing the SAPO molecular sieves, wherein the molar ratio of water to the organic amine is less than 2.0; b) the initial mixture obtained in the step a) is maintained at 30-60 °C and aged with stirring for not more than 24 hours, to obtain an initial gel; c) the initial gel obtain in the step b) is crystallized at 150-250 °C for 0.5-15 days. The SAPO molecular sieves prepared thereby are used, after being calcined at 400 - 700 °C in air, as catalysts for acid-catalyzed reactions or for conversion reactions of oxygen-containing compounds to olefins.
摘要翻译：设置在SAPO分子筛，并由此制得的催化剂的溶剂热合成方法。合成方法包括以下步骤：a）以有机胺铝源，磷源，硅源，水和在6-30的摩尔比混合的，：1：0.5-5：0.01〜1.0：0.1 -15，以获得在初始混合物用于制备SAPO分子筛，worin的水的摩尔比的有机胺是小于2.0; b）在步骤a）中获得的初始混合物保持在30-60℃并老化搅拌不超过24小时，以获得在初始凝胶; c）该初始凝胶获得在步骤b）在150-250℃下结晶为0.5〜15天。由此制备的SAPO分子筛的使用，在400煅烧至700℃的空气中，作为催化剂用于酸催化的反应或反应为含氧化合物转化成烯烃后。

7. 发明授权

EP2205527B1 METHOD OF MAKING M41S FAMILY MOLECULAR SIEVE 失效
标题翻译：用于生产分子筛M41S系列
公开(公告)号：EP2205527B1
公开(公告)日：2017-01-11
申请号：EP08843236.4
申请日：2008-09-30
申请人： ExxonMobil Chemical Patents Inc.
发明人： LAI, Wenyih, F. , KAY, Robert, Ellis , MCCARTHY, Stephen, J.
IPC分类号： B01J29/03 , C01B37/00 , C01B37/02 , B01J29/70 , B01J29/76 , B01J29/82 , B01J29/83 , B01J29/84 , B01J29/85 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/48 , C01B39/54 , B01J29/04
CPC分类号： C01B37/02 , B01J29/0308 , B01J29/0333 , B01J29/041 , B01J29/044 , B01J29/70 , B01J29/76 , B01J29/82 , B01J29/83 , B01J29/84 , B01J29/85 , B01J2229/42 , C01B37/005 , C01B37/04 , C01B37/06 , C01B37/065 , C01B37/08 , C01B39/48 , C01B39/54

8. 发明公开

EP3110550A1 SCR CATALYSTS HAVING IMPROVED LOW TEMPERATURE PERFORMANCE, AND METHODS OF MAKING AND USING THE SAME 有权
标题翻译：与生产和使用并且改善低温性能和方法SCR催化剂
公开(公告)号：EP3110550A1
公开(公告)日：2017-01-04
申请号：EP15708039.1
申请日：2015-02-27
申请人： Johnson Matthey Public Limited Company
发明人： CHANDLER, Guy Richard , COLLIER, Jillian Elaine , GREEN, Alexander Nicholas Michael , DURAN-MARTIN, Desiree , PHILLIPS, Paul Richard , RAJARAM, Raj Rao , REID, Stuart David
IPC分类号： B01J37/10 , B01J37/14 , B01J37/16 , B01J37/18 , B01J29/072 , B01J29/46 , B01J29/68 , B01J29/76 , B01J29/85 , B01J37/02 , B01D53/94
CPC分类号： B01J29/072 , B01D53/56 , B01D53/565 , B01D53/9418 , B01D2251/2062 , B01D2251/2067 , B01D2255/20738 , B01D2255/50 , B01D2255/502 , B01D2255/504 , B01D2258/012 , B01D2258/0283 , B01J29/46 , B01J29/68 , B01J29/76 , B01J29/7615 , B01J29/763 , B01J29/85 , B01J37/0036 , B01J37/0045 , B01J37/12 , B01J37/14 , B01J37/16 , B01J37/18 , B01J2229/10 , B01J2229/186 , B01J2229/36 , B01J2229/40 , C01B39/02 , C01B39/44 , C01B39/54
摘要： SCR-active molecular-sieve based catalysts with improved low-temperature performance are made by heating a molecular-sieve in a non-oxidizing atmosphere with steam (hydrothermal treatment), or in a reducing atmosphere without steam (thermal treatment), at a temperature in the range of 600-900° C. for a time period from 5 minutes to two hours. The resulting SCR-active iron-containing molecular sieves exhibit a selective catalytic reduction of nitrogen oxides with NH3 or urea at 250° C. that is at least 50% greater than if the iron-containing molecular-sieve were calcined at 500° C. for two hours without performing the hydrothermal or thermal treatment.
摘要翻译：具有改进的低温性能SCR活性分子筛基催化剂通过在非氧化性气氛与蒸汽（水热处理）加热分子筛在没有蒸汽（热处理）的还原性气氛中，在温度制成，或者在600-900℃的时间段为5分钟到两个小时的范围内。将所得的SCR活性含铁分子筛在250℃下表现出与NH 3或尿素氮氧化物的选择性催化还原所做的是比如果含铁分子筛在500℃下煅烧大至少50％两小时不进行水热或热处理。

9. 发明授权

EP2440328B1 SAPO MOLECULAR SIEVE CATALYSTS AND THEIR PREPARATION AND USES 有权
标题翻译： SAPO分子筛，生产和使用
公开(公告)号：EP2440328B1
公开(公告)日：2016-08-17
申请号：EP10725612.5
申请日：2010-06-10
申请人： Albemarle Europe Sprl.
发明人： MIES, Martijn, J., M. , HARTE, Mark, H. , STEENWINKEL, Edgar, Evert , VAN BROEKHOVEN, Emanuel Hermanus
IPC分类号： B01J29/85
CPC分类号： B01J29/85 , B01J29/005 , B01J37/10 , B01J2229/18 , C01B39/54 , C07C5/2775 , C07C2529/85 , C10G45/64 , C07C9/22

10. 发明授权

EP2517773B1 COPPER/LEV-ZEOLITE SCR CATALYST 有权
标题翻译： SCR-KUPFER / LEV-ZEOLITKATALYSATOR
公开(公告)号：EP2517773B1
公开(公告)日：2016-05-11
申请号：EP12177604.1
申请日：2008-04-24
申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY
发明人： Andersen, Paul Joseph , Collier, Jillian Elaine , Casci, John Leonello , Chen, Hai-Ying , Fedeyko, Joseph Michael , Foo, Rodney Kok Shin , Rajaram, Raj Rao
IPC分类号： B01D53/94
CPC分类号： B01D53/9418 , B01D53/565 , B01D53/8628 , B01D53/9431 , B01D53/945 , B01D2251/2062 , B01D2251/2067 , B01D2255/2065 , B01D2255/20738 , B01D2255/20761 , B01D2255/2092 , B01D2255/30 , B01D2255/50 , B01D2255/502 , B01D2255/504 , B01J29/005 , B01J29/061 , B01J29/064 , B01J29/072 , B01J29/076 , B01J29/46 , B01J29/56 , B01J29/72 , B01J29/76 , B01J29/7615 , B01J29/763 , B01J29/80 , B01J29/83 , B01J29/85 , B01J29/87 , B01J35/04 , B01J2029/062 , B01J2229/18 , B01J2229/183 , B01J2229/36 , C01B39/38 , C01B39/46 , C01B39/54 , Y02A50/2324 , Y02A50/2325 , Y02C20/10 , Y02T10/22 , Y02T10/24
摘要： A zeolite catalyst for converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of the zeolite catalyst, which zeolite catalyst comprising a small pore zeolite containing a maximum ring size of eight tetrahedral atoms and having the AEI Framework Type Code and containing a total of from 0.01 to 20 weight percent of at least one transition metal selected from the group consisting of Cr, Ce, Mn, Fe, Co, Ni and Cu, based on the total weight of the zeolite catalyst.
摘要翻译：一种用于通过在沸石催化剂存在下使氮氧化物与含氮还原剂接触而将气体中的氮氧化物转化为氮的沸石催化剂，所述沸石催化剂包含含有最大环尺寸为八面体原子的小孔沸石，并且具有 AEI框架类型代码，并且基于沸石催化剂的总重量，含有0.01至20重量％的至少一种选自Cr，Ce，Mn，Fe，Co，Ni和Cu的过渡金属。

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