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    • 7. 发明公开
    • METHOD FOR EXTRACTING GALLIUM FROM FLY ASH
    • VERFAHREN ZUR EXTRAKTION VON GALLIUM AUS FLUGASCHE
    • EP2565284A4
    • 2014-09-17
    • EP11774394
    • 2011-04-27
    • CHINA SHENHUA ENERGY CO LTD
    • LING WENJIANG YINSHANWEI CUNDILI NANGU DAZHAOGUO ZHAOHUAYANG DIANFANCHI JUNZHOUZOU PING
    • C22B58/00C22B3/24C25C1/22
    • C25C1/22B03C1/03B03C1/032B03C1/0335B03C2201/18C22B3/10C22B3/42C22B3/44C22B7/007C22B7/02C22B58/00Y02P10/234
    • Disclosed is a method for extracting gallium from fly ash, which comprises the following steps: crushing the fly ash and removing Fe by magnetic separation; then dissolving it by using hydrochloride acid (2) to obtain hydrochloric acid leachate; adsorbing gallium in the hydrochloric acid leachate with macro-porous cationic resin, followed by eluting to obtain the eluent (5) containing gallium; adding sodium hydroxide (6) solution into the eluent containing gallium to react and obtaining sodium metaaluminate solution containing gallium (8); introducing CO 2 into the sodium metaaluminate solution containing gallium (8) for carbonation, followed by separating gallium from aluminum and obtaining aluminum-gallium double salt (15) with the gallium to alumina mass ratio being more than 1:340; adding the aluminum-gallium double salt (15) into sodium hydroxide (17) to react, followed by alkalinity-adjustment concentration to obtain alkali solution containing gallium and aluminum; electrolyzing (10) the alkali solution containing gallium and aluminum to obtain metal gallium (11). The method simplifies the process and improves extraction efficiency of gallium.
    • 公开了一种从粉煤灰中提取镓的方法,包括以下步骤:粉碎飞灰并通过磁力分离除去Fe; 然后用盐酸(2)溶解得到盐酸浸出液; 用大孔阳离子树脂将镓吸附在盐酸浸出液中,然后洗脱得到含有镓的洗脱剂(5); 向含镓镓的洗脱液中加入氢氧化钠(6)溶液进行反应,得到含有镓(8)的偏铝酸钠溶液; 将二氧化碳引入含镓(8)碳酸钙的偏铝酸钠溶液中,然后从铝中分离镓,得到镓与铝的双重盐(15),镓与氧化铝的质量比大于1:340; 将铝 - 镓复合盐(15)加入氢氧化钠(17)中进行反应,然后进行碱度调节浓度,得到含镓和铝的碱溶液; 电解(10)含有镓和铝的碱溶液以获得金属镓(11)。 该方法简化了工艺,提高了镓的提取效率。