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1. 发明授权

EP1899269B1 PROCEDE D'OLIGOMÉRISATION D'UNE CHARGE OLÉFINIQUE 有权
公开(公告)号：EP1899269B1
公开(公告)日：2018-11-21
申请号：EP06764819.6
申请日：2006-06-22
申请人： IFP Energies nouvelles
发明人： SIMON, Laurent , LACOMBE, Sylvie
IPC分类号： B01J29/06 , B01J29/18 , B01J29/65 , B01J29/70 , B01J37/00 , C07C2/12 , C10G50/00 , C01B39/02 , C01B39/06
CPC分类号： B01J29/06 , B01J29/18 , B01J29/65 , B01J29/7026 , B01J37/0009 , B01J2229/16 , B01J2229/186 , B01J2229/32 , B01J2229/37 , C01B39/026 , C01B39/06 , C07C2/12 , C10G50/00 , C10G2300/1088 , C10G2400/20 , C10G2400/22 , C07C11/02

2. 发明公开

EP3351300A1 MANGANESE OXIDE CONTAINING ALUMINA COMPOSITION, A METHOD FOR MANUFACTURING THE SAME AND USE THEREOF 审中-公开
公开(公告)号：EP3351300A1
公开(公告)日：2018-07-25
申请号：EP17152530.6
申请日：2017-01-20
申请人： SASOL Germany GmbH
发明人： NIEMEYER, Dierk , HARMENING, Thomas , SCHÖNEBORN, Marcos , ROLFS, Sönke
IPC分类号： B01J21/12 , B01J23/34 , B01J35/10 , B01J37/02 , B01D53/86
CPC分类号： B01J21/12 , B01D53/944 , B01D2255/20715 , B01D2255/2073 , B01D2255/2092 , B01D2255/30 , B01D2255/9205 , B01D2255/9207 , B01J23/34 , B01J35/1019 , B01J37/0201 , B01J37/0215 , B01J37/0221 , B01J2229/32
摘要： The present invention is concerned with a manganese oxide containing alumina composition with high resistance against SOx and a method for making the composition and use of the composition as catalyst carrier. The composition comprises an alumina based material, manganese oxide, and silica.

3. 发明公开

EP3056272A4 BETA MOLECULAR SIEVE, PREPARATION METHOD THEREFOR AND HYDROGENATION CATALYST CONTAINING SAME 有权转让
标题翻译： BETAMOLEKULARSIEB，HERSTELLUNGSVERFAHRENDAFÜRUND HYDRIERUNGSKATALYSATOR DAMIT
公开(公告)号：EP3056272A4
公开(公告)日：2017-07-05
申请号：EP14865118
申请日：2014-10-28
申请人： CHINA PETROLEUM & CHEM CORP , FUSHUN RES INST OF PETROLEUM AND PETROCHEMICALS SINOPEC CORP
发明人： LIU CHANG , WANG FENGLAI , WANG KEQI , DU YANZE , ZHAO HONG , GUAN MINGHUA
IPC分类号： B01J29/076 , B01J29/06 , B01J29/80 , B01J35/00 , C01B39/02 , C10G47/16 , C10G47/20
CPC分类号： B01J29/7815 , B01J29/7007 , B01J29/7615 , B01J35/002 , B01J2229/16 , B01J2229/186 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C01B39/026 , C01B39/46 , C01P2006/12 , C01P2006/14 , C10G47/16 , C10G47/20 , C10G2400/04
摘要： Disclosed are a beta molecular sieve, a preparation method therefor, and a hydrogenation catalyst containing same. The properties of the beta molecular sieve are as follows: the molar ratio of SiO 2 /Al 2 O 3 is 30-150, the non-framework aluminium accounts for not more than 2% of the total aluminium, and the silicon atoms coordinated in a Si(0Al) structure account for not less than 95% of the silicon atoms in the framework structure. The preparation method comprises: contacting the raw material powder of the beta molecular sieve with normal pressure and dynamic water vapour, and then with ammonium fluosilicate. The beta molecular sieve of the present invention has the features of a uniform skeleton structure of silicon and aluminium, an appropriate acidity, and a reasonable pore structure, and is suitable as an acidic component of a hydro-upgrading catalyst and a hydro-cracking catalyst for diesel oil.
摘要翻译：本发明公开了一种β分子筛及其制备方法和包含其的氢化催化剂。 β分子筛的性质如下：SiO 2 / Al 2 O 3的摩尔比为30-150，非骨架铝不超过总铝的2％，硅原子配位在 Si（OAl）结构占框架结构中不少于95％的硅原子。该制备方法包括：将β分子筛的原料粉末与常压，动态水蒸气接触，然后与氟硅酸铵接触。本发明的β分子筛具有硅，铝骨架结构均匀，酸度适宜，孔结构合理的特点，适合作为加氢改质催化剂和加氢裂化催化剂的酸性组分用于柴油。

4. 发明公开

EP3153490A1 METHOD FOR PREPARING PARAXYLENE WITH CO-PRODUCTION OF PROPYLENE WITH HIGH SELECTIVITY 有权
标题翻译：用于生产对二甲苯具有高选择性的丙烯同时生产
公开(公告)号：EP3153490A1
公开(公告)日：2017-04-12
申请号：EP14894165.1
申请日：2014-06-04
申请人： Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences
发明人： XU, Lei , LIU, Zhongmin , ZHANG, Xinzhi
IPC分类号： C07C15/08 , C07C11/06 , C07C2/88
CPC分类号： C07C2/864 , B01J29/40 , B01J29/90 , B01J38/12 , B01J2229/32 , C07C2/865 , C07C2529/40 , C07C2529/80 , Y02P20/52 , Y02P20/584 , C07C11/06 , C07C15/08
摘要： This invention relates to a method for preparing p-xylene and co-producing propylene with a high selectivity. Toluene and methanol and/or dimethyl ether as raw materials are brought into contact with a catalyst in a reaction system for reaction, and after the resultant product is separated via a separation system, an ethylene-enriched C 2 - component (hydrocarbons having carbon number less than or equal to 2, CO, CO 2 , and H 2 ) therein is returned to the reaction system for further reaction, a C 6 + component (aromatic hydrocarbons having carbon number greater than or equal to 6) is subjected to further separation to obtain p-xylene, and a C 3 component (propylene and propane having a carbon number equal to 3) is subjected to further separation to obtain propylene. This method prepares p-xylene and co-produces propylene with a high selectivity, by coupling two reaction processes, an alkylation reaction of toluene with methanol and/or dimethyl ether and an alkylation reaction of ethylene with methanol and/or dimethyl ether, recycling an ethylene-enriched C 2 - component in reaction byproducts of alkylation of toluene and methanol and/or dimethyl ether, and performing alkylation reaction with methanol and/or dimethyl ether in the presence of catalysts.
摘要翻译：本发明涉及用于制备对二甲苯和共同生产丙烯以高选择性的方法。甲苯和甲醇和/或二甲醚作为原料引入与在用于反应的反应系统中的催化剂接触，将得到的产物通过一个分离系统中分离后，以乙烯 - 富集的C 2 - 组分（具有碳数的烃小于或等于2，CO，CO 2，和H 2）。其中返回到用于进一步反应的反应系统中，C 6 +组分（芳烃具有碳原子数大于或等于6）进行进一步的分离以获得对二甲苯，和（具有等于3个碳原子数的丙烯和丙烷）一个C 3组分进行进一步分离，得到丙烯。这种方法准备的对二甲苯和共可生产丙烯以高选择性，通过耦合两个反应流程，用甲醇和/或二甲醚，并在与甲醇和/或二甲醚，回收乙烯的烷基化反应的甲苯的烷基化反应乙烯 - 富集的C 2 - 在甲苯和甲醇和/或二甲醚的烷基化反应副产物成分，在催化剂存在下与甲醇和/或二甲醚进行烷基化反应。

5. 发明公开

EP2978528A1 PASSIVIERUNG EINES ZEOLITH-KATALYSATORS IN EINER WIRBELSCHICHT 审中-公开
标题翻译：钝化沸石催化剂在流化床
公开(公告)号：EP2978528A1
公开(公告)日：2016-02-03
申请号：EP14706827.4
申请日：2014-02-26
申请人： BASF SE
发明人： FEYEN, Mathias , SCHAACK, Bernd Bastian , MÜLLER, Ulrich , HEIDEMANN, Thomas , WILL, Veronika , SENK, Rainer
IPC分类号： B01J37/02 , B01J37/18 , B01J29/48 , C07C2/76 , C07C15/04
CPC分类号： C07C2/76 , B01J29/405 , B01J29/42 , B01J29/46 , B01J29/48 , B01J29/90 , B01J33/00 , B01J38/10 , B01J2229/123 , B01J2229/186 , B01J2229/32 , C07C2527/24 , C07C2529/46 , C07C2529/48 , Y02P20/52 , Y02P20/584 , C07C15/04
摘要： The invention concerns a method of producing a passivated catalyst containing a zeolite and at least one active metal, characterized in that the catalyst is held in a fluidized bed where it is passivated with a silicon compound.

6. 发明公开

EP2878590A1 CRESOL PRODUCING METHOD THROUGH PHENOL METHANOL GAS-PHASE ALKYLATION 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG VON KRESOL DURCH PHENOL-METHANOL-GASPHASENALKYLIERUNG
公开(公告)号：EP2878590A1
公开(公告)日：2015-06-03
申请号：EP12881816.8
申请日：2012-07-24
申请人： Dalian Institute Of Chemical Physics, Chinese Academy of Sciences
发明人： WANG, Kunyuan , XU, Yunpeng , LIU, Zhongmin
IPC分类号： C07C37/16 , B01J29/00 , C07C39/07
CPC分类号： C07C37/11 , B01J29/00 , B01J29/40 , B01J29/46 , B01J29/7007 , B01J29/7038 , B01J29/7615 , B01J29/7676 , B01J37/28 , B01J2229/186 , B01J2229/32 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C37/16 , Y02P20/52 , C07C39/07
摘要： The present invention relates to a method for producing cresol from phenol and methanol via gas phase alkylation, in which phenol and methanol are preheated and mixed with diluent gas, then the mixture continuously go through a catalyst bed comprising the catalyst for alkylation of phenol with methanol, to produce cresol by gas phase reaction at the reaction temperature of 200∼500°C and the weight hourly space velocity of 0.5∼20h -1 . The catalyst for alkylation of phenol with methanol is obtained by modification steps and using ZSM-5 zeolite, MCM-22 zeolite or Beta zeolite as an active composition. Using phenol and methanol as feedstock, the cresol selectivity can reach to 90%, and the p-cresol selectivity can reach to 58%. The catalyst is environmental friendly and non-corrosive to the equipment with a good stability and a broad prospect in industrial application.
摘要翻译：本发明涉及一种通过气相烷基化从苯酚和甲醇生产甲酚的方法，其中苯酚和甲醇被预热并与稀释气体混合，然后将混合物连续通过催化剂床，该催化剂床包含用甲醇烷基化苯酚的催化剂在200〜500℃的反应温度下，通过气相反应生成甲酚，重时空速为0.5¼20h-1。用甲醇烷基化苯酚的催化剂是通过改性步骤和使用ZSM-5沸石，MCM-22沸石或β沸石作为活性组合物得到的。以苯酚和甲醇为原料，甲酚选择性可达90％，对甲酚选择性可达58％。催化剂环保，无腐蚀性，具有良好的稳定性和广泛的工业应用前景。

7. 发明公开

EP2258658A3 Process for preparing zeolites 有权
标题翻译：一种沸石的制备过程
公开(公告)号：EP2258658A3
公开(公告)日：2011-12-14
申请号：EP10179898.1
申请日：1998-09-19
申请人： Polimeri Europa S.p.A.
发明人： Carati, Angela , Bellussi, Giuseppe , Mantegazza, Mariangela , Petrini, Guido
IPC分类号： C01B37/00 , C01B37/02
CPC分类号： C01B37/005 , B01J29/06 , B01J29/40 , B01J2229/32 , C01B37/02 , C01B39/40 , Y10S423/22 , Y10S423/29
摘要： A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.

8. 发明授权

EP2006019B1 Metallhaltiger Katalysator 有权
标题翻译：催化剂含有金属的
公开(公告)号：EP2006019B1
公开(公告)日：2010-11-24
申请号：EP08165320.6
申请日：2004-11-04
申请人： Carl von Ossietzky Universität Oldenburg
发明人： Rößner, Frank , Kuhlmann, Arne , Schwieger, Wilhelm
IPC分类号： B01J29/04 , B01J29/50 , B01J23/42 , C10G45/64
CPC分类号： B01J37/08 , B01J21/16 , B01J23/42 , B01J23/44 , B01J29/005 , B01J29/049 , B01J29/22 , B01J29/44 , B01J29/50 , B01J37/0036 , B01J37/009 , B01J2229/32 , B01J2229/42 , C10G49/02 , C10G49/08

9. 发明公开

EP2140939A1 METHOD OF REGENERATING LOWER HYDROCARBON AROMATIZING CATALYST 审中-公开
标题翻译：方法催化剂的调味低碳烃类再生
公开(公告)号：EP2140939A1
公开(公告)日：2010-01-06
申请号：EP08722278.2
申请日：2008-03-17
申请人： Meidensha Corporation
发明人： MA, Hongtao , OGAWA, Yuji
IPC分类号： B01J29/90 , B01J29/48 , B01J38/10 , B01J38/12 , C10G35/04
CPC分类号： B01J29/48 , B01J27/22 , B01J27/28 , B01J29/90 , B01J37/0009 , B01J38/10 , B01J38/12 , B01J2229/12 , B01J2229/123 , B01J2229/18 , B01J2229/32 , B01J2229/42 , C07C2/76 , Y02P20/584 , C07C15/00
摘要： To improve stability of catalytic performance, an aromatizing catalyst for converting lower hydrocarbons into aromatic compounds is regenerated. A regeneration process of the aromatizing catalyst according to the present invention includes the steps of: (a) reacting the aromatizing catalyst with a hydrogen gas in an atmosphere containing the hydrogen gas after using the aromatizing catalyst in an aromatizing reaction for converting lower hydrocarbons into aromatic compounds; (b) decreasing a temperature of the atmosphere containing the hydrogen gas reacted with the aromatizing catalyst, by supplying one of an inert gas and a reducing gas to the atmosphere; (c) reacting the aromatizing catalyst reacted with this inert gas, with an oxidizing gas; and (d) reacting the aromatizing catalyst reacted with the oxidizing gas, with a reducing gas. The reaction step between the aromatizing catalyst and hydrogen gas is conducted in a temperature region that is the same as the temperature of the aromatizing reaction. In the temperature decreasing step, an inert gas is supplied such that the temperature of the aromatizing catalyst becomes 400°C-550°C. In the step of reacting the aromatizing catalyst with an oxidizing gas, the temperature of an atmosphere, in which the aromatizing catalyst is reacted with the oxidizing gas, is set at 450°C-500°C.

10. 发明公开

EP2006019A1 Metallhaltiger Katalysator 有权
公开(公告)号：EP2006019A1
公开(公告)日：2008-12-24
申请号：EP08165320.6
申请日：2004-11-04
申请人： Carl von Ossietzky Universität Oldenburg
发明人： Rößner, Frank , Kuhlmann, Arne , Schwieger, Wilhelm
IPC分类号： B01J29/04 , B01J29/50 , B01J23/42 , C10G45/64
CPC分类号： B01J37/08 , B01J21/16 , B01J23/42 , B01J23/44 , B01J29/005 , B01J29/049 , B01J29/22 , B01J29/44 , B01J29/50 , B01J37/0036 , B01J37/009 , B01J2229/32 , B01J2229/42 , C10G49/02 , C10G49/08
摘要： Erfindungsgemäß ist vorgesehen, dass ein Komposit-Katalysator zur Umsetzung von Kohlenwasserstoffen verwendet wird, der ein metallhaltiges Schichtsilikat in Mischung mit einem sauren SiO 2 -Festkörper, beispielsweise H-Erionit enthält. Durch thermische Verkapselung wird eine Beständigkeit gegen Katalysatorgifte erzielt.
Die erfindungsgemäßen Komposit-Katalysatoren werden besonders bevorzugt für die Umwandlung von Kohlenwasserstoffen eingesetzt, um längerkettige Paraffine und/oder Olefine zu kürzerkettigen, wahlweise gesättigten Kohlenwasserstoffen umzusetzen.
摘要翻译：用于转化烃的催化剂包括含金属的硅酸盐组分，其是含金属的硅酸盐层，其中纳入第VIII族金属的纳米分散金属颗粒，并且含有基于具有酸中心，功能性混合物; 催化剂是复合催化剂。包括用于制备催化剂的独立权利要求，包括将亚组VIII的金属离子施加到层状硅酸盐中，加热含金属离子的层状硅酸盐以从金属离子生产金属并制备具有固体材料的功能性混合物具有酸中心。

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