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    • 9. 发明公开
    • VANADIUM PENTOXIDE PURIFYING SYSTEM AND METHOD
    • 钒氧化物净化系统和方法
    • EP3243799A1
    • 2017-11-15
    • EP16742780.6
    • 2016-01-28
    • Institute of Process Engineering, Chinese Academy of SciencesBeijing Zhongkaihongde Technology Co., Ltd.
    • ZHU, QingshanFAN, ChuanlinMU, WenhengLIU, JibinWANG, CunhuBAN, Qixun
    • C01G31/02
    • C01G31/02B01D3/14B01D19/0057B01J8/24C01G31/04C01P2006/80
    • The present invention provides a system and method for purifying vanadium pentoxide. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to plasma oxidation, thereby obtaining a high-purity vanadium pentoxide product and chlorine gas. The chlorine gas is returned for low temperature chlorination. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality and so on.
    • 本发明提供了用于纯化五氧化钒的系统和方法。 通过低温流化氯化将工业级五氧化二钒转化为三氯氧化钒,其中通过流化气体与氯化烟气之间的热交换预热氯化气体,并加入适量的空气以使一部分碳粉燃烧 在氯化过程中实现均衡供热,从而提高氯化效率并确保低温氯化中的良好选择性。 通过精馏纯化三氯氧化钒,然后进行等离子体氧化,由此获得高纯度五氧化二钒产品和氯气。 氯气返回低温氯化。 该系统和方法具有对原料适应性好,污染废水不排放,生产能耗低,耗氯量少,产品质量稳定等优点。