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    • 4. 发明公开
    • PROCESS FOR PRODUCTION OF SULFONIC ACID ESTER
    • 生产磺酸酯的方法
    • EP2067770A1
    • 2009-06-10
    • EP07742042.0
    • 2007-04-20
    • Wako Pure Chemical Industries, Ltd.
    • OKAMOTO, KuniakiWATAHIKI, TsutomuSUMINO, MotoshigeSHIBASAKI, Takao
    • C07C303/26C07D327/10
    • C07C303/26C07D327/00C07C309/65C07C309/66C07C309/73C07C309/76C07C309/67
    • The present invention provides a method for producing a sulfonate ester efficiently and in high yield.
      The present invention is an invention of a method for producing a sulfonate ester compound, which comprising reacting:
      (a) a compound having a sulfo group (-SO 3 H); and
      (b) a compound having a group represented by the general formula [1]:

              -OR 1      [1]

      [wherein, R 1 represents a sulfonyl group represented by the general formula [2]:

              -SO-R 2      [2]

      (wherein, R 2 represents a halogen atom, a haloalkyl group, an alkoxy group, or an optionally substituted alkyl group or an optionally substituted aryl group) or an acyl group represented by the general formula [3]:

      (wherein, R 3 represents an optionally substituted alkyl group or an optionally substituted aryl group)];
      in the presence of an organic base which is capable of forming a salt with said sulfo group.
    • 本发明提供一种有效且高收率地制造磺酸酯的方法。 本发明是磺酸酯化合物的制造方法的发明,其特征在于,使具有磺基(-SO 3 H)的化合物与(a) (b)具有通式[1]所示基团的化合物:-OR1 [1] [其中,R1表示由通式[2]表示的磺酰基:-SO-R2 [2] R2表示卤素原子,卤代烷基,烷氧基或任选取代的烷基或任选取代的芳基)或由通式[3]表示的酰基:(其中,R3表示任选取代的烷基 或任选取代的芳基)]; 在能够与所述磺基形成盐的有机碱存在下进行。
    • 7. 发明公开
    • DEUTERATED POLYIMIDES AND DERIVATIVES THEREOF
    • DEUTERIERTE POLYIMIDE UND DERIVATE DAVON
    • EP1754739A1
    • 2007-02-21
    • EP05741155.5
    • 2005-05-17
    • Wako Pure Chemical Industries, Ltd.
    • MUTO, KazushigeMAESAWA, TsuneakiITO, NobuhiroWATAHIKI, TsutomuHIROTA, KosakuSAJIKI, Hironao
    • C08G73/10G02B6/12
    • C07D487/04C07D209/48C08G73/10C08G73/1007G02B6/1221
    • The object of the present invention is to provide a polyimide compound useful as a raw material of a polymer for an optical waveguide that has excellent transparency and heat resistance, low moisture absorption, a small optical transmission loss, a high refractive index and good adhesion to a base material or a substrate. The present invention is inventions of a method for producing a deuterated polyamic acid compound represented by the general formula [2]:

      wherein R 1 indicates a tetravalent alicyclic hydrocarbon group or a tetravalent aromatic hydrocarbon group, which may have a heavy hydrogen atom; R 2 indicates a divalent aromatic hydrocarbon group having a heavy hydrogen atom; and m indicates an integer not less than 1,
      which comprises reacting an acid anhydride represented by the general formula [3]:

      wherein R 1 has the same meaning as above, with a deuterated diamine compound represented by the general formula [4]:

              H 2 N-R 2 -NH 2      [4]

      wherein R 2 has the same meaning as above; a method for producing a deuterated polyimide compound represented by the general formula [1]:

      wherein R 1 indicates a tetravalent alicyclic hydrocarbon group or a tetravalent aromatic hydrocarbon group, which may have a heavy hydrogen atom; R 2 indicates a divalent aromatic hydrocarbon group having a heavy hydrogen atom; and n indicates an integer not less than 1, which comprises subjecting thus obtained deuterated polyamic acid compound to a ring closure reaction; a method for producing a deuterated polyimide compound represented by the general formula [1] which comprises reacting an acid anhydride represented by the above general formula [3] with a deuterated diamine compound represented by the above general formula [4] and then subjecting the reaction product to a ring closure reaction; use of a deuterated polyimide compound obtained by the above production methods as a raw material polymer for an optical waveguide; a film for an optical waveguide containing said deuterated polyimide compound; a deuterated polyimide compound; and a deuterated polyamic acid compound.
    • 本发明的目的是提供一种可用作光波导聚合物的原料的聚酰亚胺化合物,其具有优异的透明性和耐热性,低吸湿性,小的光学透射损失,高折射率和对 基材或基材。 本发明是由通式[2]表示的氘代聚酰胺酸化合物的制造方法的发明:其中R 1表示可能具有重氢原子的四价脂环族烃基或四价芳香族烃基; R 2表示具有重氢原子的二价芳香族烃基; m表示不小于1的整数,其包括使通式[3]表示的酸酐与通式[4]表示的氘化二胺化合物反应:其中R 1具有与上述相同的含义。 ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒH2 NR 2 -NH 2€ƒ€ƒ€ƒ€ƒ[4]其中R 2具有与上述相同的含义; 用于制备由通式[1]表示的氘代聚酰亚胺化合物的方法:其中R 1表示可具有重的氢原子的四价脂环族烃基或四价芳族烃基; R 2表示具有重氢原子的二价芳香族烃基; n表示1以上的整数,其包括如此得到的氘代聚酰胺酸化合物进行闭环反应; 一种制备由通式[1]表示的氘代聚酰亚胺化合物的方法,包括使由上述通式[3]表示的酸酐与由上述通式[4]表示的氘化二胺化合物反应,然后使反应 产品进行闭环反应; 使用通过上述制备方法获得的氘代聚酰亚胺化合物作为光波导的原料聚合物; 用于包含所述氘代聚酰亚胺化合物的光波导的膜; 氘代聚酰亚胺化合物; 和氘代聚酰胺酸化合物。