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    • 2. 发明公开
    • PROCESS FOR PRODUCTION OF SULFONIC ACID ESTER
    • 生产磺酸酯的方法
    • EP2067770A1
    • 2009-06-10
    • EP07742042.0
    • 2007-04-20
    • Wako Pure Chemical Industries, Ltd.
    • OKAMOTO, KuniakiWATAHIKI, TsutomuSUMINO, MotoshigeSHIBASAKI, Takao
    • C07C303/26C07D327/10
    • C07C303/26C07D327/00C07C309/65C07C309/66C07C309/73C07C309/76C07C309/67
    • The present invention provides a method for producing a sulfonate ester efficiently and in high yield.
      The present invention is an invention of a method for producing a sulfonate ester compound, which comprising reacting:
      (a) a compound having a sulfo group (-SO 3 H); and
      (b) a compound having a group represented by the general formula [1]:

              -OR 1      [1]

      [wherein, R 1 represents a sulfonyl group represented by the general formula [2]:

              -SO-R 2      [2]

      (wherein, R 2 represents a halogen atom, a haloalkyl group, an alkoxy group, or an optionally substituted alkyl group or an optionally substituted aryl group) or an acyl group represented by the general formula [3]:

      (wherein, R 3 represents an optionally substituted alkyl group or an optionally substituted aryl group)];
      in the presence of an organic base which is capable of forming a salt with said sulfo group.
    • 本发明提供一种有效且高收率地制造磺酸酯的方法。 本发明是磺酸酯化合物的制造方法的发明,其特征在于,使具有磺基(-SO 3 H)的化合物与(a) (b)具有通式[1]所示基团的化合物:-OR1 [1] [其中,R1表示由通式[2]表示的磺酰基:-SO-R2 [2] R2表示卤素原子,卤代烷基,烷氧基或任选取代的烷基或任选取代的芳基)或由通式[3]表示的酰基:(其中,R3表示任选取代的烷基 或任选取代的芳基)]; 在能够与所述磺基形成盐的有机碱存在下进行。