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    • 5. 发明公开
    • (METH)ACRYLIC ESTER COMPOUND AND USE THEREOF
    • (甲基)丙烯酸酯化合物及其用途
    • EP1627867A1
    • 2006-02-22
    • EP04734424.7
    • 2004-05-21
    • Mitsui Chemicals, Inc.
    • OTSUJI, AtsuoTAKAGI, MasatoshiHIGUCHI, ChojiroNAGATOMO, AkinoriSUESUGI, KoujiTOIDA, TetsuyaHONDA, Narimichi
    • C07C69/54C07C43/23C07C69/63C07C323/20C07C317/22C08F20/30A61C13/087G02B1/04
    • C08F22/105C07C69/54C07C317/22C07C323/20G02B1/04C08L33/14
    • A (meth)acrylic ester compound represented by the general formula (1) and a dental material containing the compound,

      wherein, in the formula, R 11 represents a divalent aromatic group; R 12 represents a hydrogen atom or a methyl group; R 13 represents an aryl group; R 14 represents a hydrogen atom or a methyl group; and X 11 represents an oxygen atom or a sulfur atom.
      The dental material and the dental composition which each contains the compound represented by the general formula (1) according to the present invention are useful because they are superior in curability and also combine transparency, X-ray contrast property, and low polymerization shrinkage while retaining various properties required for dental materials (for example, flexural strength and the like).
      Furthermore, a polymerizable composition containing the (meth)acrylic ester compound represented by the general formula (1) which can be polymerized and molded within a short period of time by photopolymerization. It gives a cured resin which is excellent in the transparency, optical properties (refractive index and Abbe's number), heat resistance, mechanical properties and the like. Also provided is an optical part obtained by polymerizing the polymerizable composition.
    • 由通式(1)表示的(甲基)丙烯酸酯化合物和含有该化合物的牙科材料,其中在式中,R 11表示二价芳族基团; R12表示氢原子或甲基; R13表示芳基; R14代表氢原子或甲基; X11表示氧原子或硫原子。 含有本发明的通式(1)表示的化合物的牙科材料和牙科用组合物是有用的,因为它们具有优异的固化性,并且还兼具透明性,X射线造影性和低聚合收缩率,同时保留 牙科材料所需的各种特性(例如弯曲强度等)。 此外,含有通式(1)表示的(甲基)丙烯酸酯化合物的可聚合组合物可通过光聚合在短时间内聚合和模塑。 得到透明性,光学特性(折射率和阿贝数),耐热性,机械特性等优异的固化树脂。 还提供了通过聚合可聚合组合物而获得的光学部件。