专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明公开

EP1332196A1 BLENDS OF QUINONE ALKIDE AND NITROXYL COMPOUNDS AS POLYMERIZATION INHIBITORS 审中-公开
标题翻译： QUINONALKIDE和用作聚合抑制剂MIXTURES硝酰基
公开(公告)号：EP1332196A1
公开(公告)日：2003-08-06
申请号：EP01981357.5
申请日：2001-10-02
申请人： Uniroyal Chemical Company, Inc.
发明人： BENAGE, Brigitte
IPC分类号： C09K15/30 , C09K15/08 , C07C51/50 , C07C7/20 , C07C15/46 , C07C67/62 , C07C50/00 , C07B63/04 , G03F7/027 , C08F2/38
CPC分类号： C09K15/30 , C07B63/04 , C07C7/20 , C07C17/42 , C07C59/82 , C07C67/62 , C08F4/40 , C09K15/08 , G03F7/027 , C07C21/21 , C07C69/54
摘要： Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of: A) at least one nitroxyl compound, and B) at least one quinone alkide compound having an electron-withdrawing group at the 7-position. Additionally, a composition is disclosed that comprises: A) at least one nitroxyl compound, and B) at least one quinone alkide compound having an electron-withdrawing group at the 7-position.

2. 发明公开

EP1438277A2 RECYCLE OF NITROXYL-CONTAINING STREAMS AT LOW TEMPERATURE 有权
标题翻译： RECOVERING含硝酰氧基STREAMS低温
公开(公告)号：EP1438277A2
公开(公告)日：2004-07-21
申请号：EP01954786.8
申请日：2001-07-19
申请人： Uniroyal Chemical Company, Inc.
发明人： BENAGE, Brigitte , ABRUSCATO, Gerald, J. , EISENSTEIN, Andrew, J. , SCHLUP, Kirk, A. , GREWAL, Ruben, S. , GEELAN, Brendan
IPC分类号： C07C7/20 , C07C15/46 , C07B63/04 , C09K15/30
CPC分类号： C09K15/30 , C07B63/04 , C07C7/04 , C07C7/20 , C07C15/46
摘要： An improved process for the production and purification of unsaturated monomers employing nitroxyl-containing inhibitors wherein process streams containing the inhibitor are recycled is disclosed, wherein the improvement comprises recycling said streams at a reboiler temperature no higher than about 110 °C.

3. 发明公开

EP1278712A2 NITROAROMATIC SOLUBILIZER FOR NITROXYLS IN AROMATIC SOLVENTS 有权
标题翻译：硝基芳烃增溶剂芳族溶剂硝酰基
公开(公告)号：EP1278712A2
公开(公告)日：2003-01-29
申请号：EP01924585.1
申请日：2001-04-03
申请人： Uniroyal Chemical Company, Inc.
发明人： GEELAN, Brendan, J. , BENAGE, Brigitte , ABRUSCATO, Gerald, J. , SCHLUP, Kirk, A. , GREWAL, Ruben, S. , EISENSTEIN, Andrew, J.
IPC分类号： C07B63/04 , C08F4/04
CPC分类号： C07D295/24 , C07B63/04 , C07C291/02 , C07D211/94
摘要： Disclosed herein is a method for increasing the solubility of a compound having the structural formula (I), in an aromatic hydrocarbon solvent comprising adding to said solvent a nitroaromatic compound having the structure (II) wherein, in formula (II), R25, R26, R27, R28, R29 and R30 are independently selected from the group consisting of hydrogen, alkyl, aryl, cycloalkyl, heterocyclic, substituted alkyl, substituted aryl, OR11, NR11R12, SR11, NO2, NO, CN, COR11, COOR11, CONR11R12, NR11COR12, halogen, and/or any two adjacent groups can be taken together to form ring structures(s) of five to seven members, provided that at least one of R25, R26, R27, R28, R29 and R30 is NO2, and R11 and R12 are independently selected from the group consisting of hydrogen, alkyl, aryl, benzyl, cyclic, heterocyclic, and substituted alkyl or aryl where the substituents are C, O, N, S, or P, or R11 and R12 can be taken together to form a ring structure of five to seven members and, in formula (I), R1 and R4 are independently selected from the group consisting of hydrogen, alkyl, and heteroatom-substituted alkyl and R2 and R3 are independently selected from the group consisting of alkyl and heteroatom-substituted alkyl; and X1 and X2 (1) are independently selected from the group consisting of halogen, cyano, COOR7, -S-COR7, -OCOR7, (wherein R7 is alkyl or aryl), amido, -S-C6H5, carbonyl, alkenyl, or alkyl of 1 to 15 carbon atoms, or (2) taken together, form a ring structure of five to seven members with the nitrogen.

4. 发明公开

EP1248757A1 INHIBITION OF POLYMERIZATION OF UNSATURATED MONOMERS 有权
标题翻译：不饱和单体聚合的抑制
公开(公告)号：EP1248757A1
公开(公告)日：2002-10-16
申请号：EP00983901.0
申请日：2000-12-05
申请人： Uniroyal Chemical Company, Inc.
发明人： BENAGE, Brigitte , EISENSTEIN, Andrew, J.
IPC分类号： C07B63/04 , C07C7/20 , C07C15/46 , C09K15/30
CPC分类号： C07B63/04 , C07C7/20 , C07C15/46
摘要： Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of: A) at least one stable hindered nitroxyl compound having the structural formula (I) wherein R1 and R4 are independently selected from the group consisting of hydrogen, alkyl, and heteroatom-substituted alkyl and R2 and R3 are independently selected from the group consisting of alkyl and heteroatom-substituted alkyl; and X1 and X2 (1) are independently selected from the group consisting of halogen, cyano, COOR7, -S-COR7, -OCOR7, (wherein R7 is alkyl or aryl), amido, -S-C6H5, carbonyl, alkenyl, or alkyl of 1 to 15 carbon atoms, or (2) taken together, form a ring structure with the nitrogen; and B) at least one phenylenediamine, and, optionally, C) at least one nitroaromatic compound.
摘要翻译：本文公开了抑制烯键式不饱和单体过早聚合的方法，其包括向所述单体中加入有效量的：A）至少一种具有结构式（I）的稳定的位阻硝酰基化合物，其中R 1和R 4独立地选自由氢，烷基和杂原子取代的烷基组成并且R 2和R 3独立地选自由烷基和杂原子取代的烷基组成的组; 和X1和X2（1）独立地选自卤素，氰基，COOR7，-S-COR7，-OCOR7（其中R7为烷基或芳基），酰氨基，-S-C6H5，羰基，烯基或 1-15个碳原子的烷基，或（2）一起与氮形成环结构; 和B）至少一种苯二胺，以及任选的C）至少一种硝基芳族化合物。

5. 发明公开

EP1190247A1 TEST METHOD FOR EVALUATING SOLUBLE POLYMER GROWTH WHEN RECYCLING INHIBITOR STREAMS 有权
标题翻译：评估的试验方法可溶性聚合物增长领导抑制剂流的BACK
公开(公告)号：EP1190247A1
公开(公告)日：2002-03-27
申请号：EP00936362.3
申请日：2000-05-26
申请人： UNIROYAL CHEMICAL COMPANY, Inc.
发明人： BENAGE, Brigitte , GEELAN, Brendan, J. , ABRUSCATO, Gerald, J.
IPC分类号： G01N33/44 , C08F2/00 , C08F12/08
CPC分类号： G01N33/442 , C08F2/00
摘要： An improvement in a method for evaluating the efficiency of polymerization inhibitors is disclosed, wherein the improvement comprises: A) producing dissolved polymer in a solution comprising monomer and at least one inhibitor by means of any test known in the art to be useful for evaluating polymerization inhibitors, B) collecting the polymer-containing solution, C) measuring the degree of polymerization of the monomer in the collected solution, and D) re-subjecting the polymer-containing solution to the test conditions of A).

6. 发明授权

EP1438277B1 RECYCLE OF NITROXYL-CONTAINING STREAMS AT LOW TEMPERATURE 有权
标题翻译： RECOVERING含硝酰氧基STREAMS低温
公开(公告)号：EP1438277B1
公开(公告)日：2007-03-07
申请号：EP01954786.8
申请日：2001-07-19
申请人： UNIROYAL CHEMICAL COMPANY, Inc.
发明人： BENAGE, Brigitte , ABRUSCATO, Gerald, J. , EISENSTEIN, Andrew, J. , SCHLUP, Kirk, A. , GREWAL, Ruben, S. , GEELAN, Brendan
IPC分类号： C07C7/20 , C07C15/46 , C07B63/04 , C09K15/30
CPC分类号： C09K15/30 , C07B63/04 , C07C7/04 , C07C7/20 , C07C15/46
摘要： An improved process for the production and purification of unsaturated monomers employing nitroxyl-containing inhibitors wherein process streams containing the inhibitor are recycled is disclosed, wherein the improvement comprises recycling said streams at a reboiler temperature no higher than about 110 °C.

7. 发明公开

EP1206507A1 INHIBITION OF POLYMERIZATION OF ETHYLENICALLY UNSATURATED MONOMERS 有权
标题翻译：防止烯不饱和单体的聚合
公开(公告)号：EP1206507A1
公开(公告)日：2002-05-22
申请号：EP00952395.2
申请日：2000-08-02
申请人： Uniroyal Chemical Company, Inc.
发明人： BENAGE, Brigitte , EDWARDS, Angela M. , KOSOVER, Vilen , WANG, Gan , GENTILE, Anthony , FABIAN, Jesus R. , ABRUSCATO, Gerald J.
IPC分类号： C09K15/20 , C07B63/04 , C07C7/20
CPC分类号： C09K15/20
摘要： Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of an inhibitor having structural formula (I) wherein R1 and R4 are independently selected from the group consisting of hydrogen, alkyl, and heteroatom-substituted alkyl and R2 and R3 are independently selected from the group consisting of alkyl and heteroatom-substituted alkyl and the portion (II) represents the atoms necessary to form a five-, or six-,seven-membered heterocyclic ring, at least one of said atoms being a carbon atom substituted with a primary, secondary, or tertiary amino group.

8. 发明授权

EP1235885B1 COMPOSITION AND METHOD FOR INHIBITING POLYMERIZATION AND POLYMER GROWTH 有权
标题翻译：组合物和用于抑制聚合及聚合物生长
公开(公告)号：EP1235885B1
公开(公告)日：2007-08-15
申请号：EP00978566.8
申请日：2000-11-13
申请人： UNIROYAL CHEMICAL COMPANY, Inc.
发明人： BENAGE, Brigitte , ABRUSCATO, Gerald, J. , SIKORA, David, J. , GREWAL, Ruben, S.
IPC分类号： C09K15/04 , C07C7/20
CPC分类号： C08F2/40 , C09K15/04 , Y10S585/95
摘要： A method for inhibiting the premature polymerization and the polymer growth of ethylenically unsaturated monomers is disclosed wherein the method comprises adding to said monomers an effective amount of at least one hydrogen donor or electron acceptor. In a preferred embodiment, the hydrogen donor or electron acceptor is used in combination with a stable nitroxyl free radical.

9. 发明授权

EP1326943B1 C-NITROSOANILINE COMPOUNDS AND THEIR BLENDS AS POLYMERIZATION INHIBITORS 有权
标题翻译： C-亚硝基苯胺及其混合物作为聚合抑制剂
公开(公告)号：EP1326943B1
公开(公告)日：2006-01-25
申请号：EP01987785.1
申请日：2001-10-11
申请人： UNIROYAL CHEMICAL COMPANY, Inc.
发明人： BENAGE, Brigitte , ABRUSCATO, Gerald, J. , EISENSTEIN, Andrew, J.
IPC分类号： C09K15/20 , C09K15/30 , C07B63/04
CPC分类号： B01D3/34 , C07C7/04 , C07C7/20 , C07C51/50 , C07C67/62 , C07C253/32 , Y10S585/95 , C07C15/46 , C07C15/42 , C07C11/167 , C07C11/18 , C07C255/06 , C07C69/54 , C07C57/04
摘要： Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine compounds. Also disclosed is a composition of matter comprising: A) an ethylenically unsaturated monomer and B) an effective inhibiting amount, sufficient to prevent premature polymerization during distillation or purification of said ethylenically unsaturated monomer, of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine oxime compounds used together with an effective amount of oxygen or air to enhance the inhibiting activity of said inhibitor.

10. 发明公开

EP1235885A1 COMPOSITION AND METHOD FOR INHIBITING POLYMERIZATION AND POLYMER GROWTH 有权
标题翻译：组合物和用于抑制聚合及聚合物生长
公开(公告)号：EP1235885A1
公开(公告)日：2002-09-04
申请号：EP00978566.8
申请日：2000-11-13
申请人： Uniroyal Chemical Company, Inc.
发明人： BENAGE, Brigitte , ABRUSCATO, Gerald, J. , SIKORA, David, J. , GREWAL, Ruben, S.
IPC分类号： C09K15/04 , C07C7/20
CPC分类号： C08F2/40 , C09K15/04 , Y10S585/95
摘要： A method for inhibiting the premature polymerization and the polymer growth of ethylenically unsaturated monomers is disclosed wherein the method comprises adding to said monomers an effective amount of at least one hydrogen donor or electron acceptor. In a preferred embodiment, the hydrogen donor or electron acceptor is used in combination with a stable nitroxyl free radical.

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式