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    • 4. 发明公开
    • Nitrogen generation
    • 氮生成
    • EP0183446A2
    • 1986-06-04
    • EP85308312.9
    • 1985-11-14
    • UNION CARBIDE CORPORATION
    • Cheung, Harry
    • F25J3/04
    • F25J3/04193F25J3/04296F25J3/044F25J2200/50F25J2200/72F25J2290/10
    • The present invention provides a process for the production of nitrogen at relatively high yield and purity by cryogenic rectifiction of feed air characterized by

      (1) introducing the major portion of the feed air into a rectification column which is operating at a pressure in the range of from 241 to 1000 kPa (from 35 to 145 psia), and wherein feed air is separated into nitrogen-rich vapour and oxygen-enriched liquid;
      (2) condensing a minor portion of the feed air, at a pressure greater than that at which the column is operating, by indirect heat exchange with oxygen-enriched liquid;
      (3) introducing the resulting condensed minor portion of the feed air into the column at a point at least one tray above the point where the major portion of the feed air is introduced into the column;
      (4) condensing a first portion of the nitrogen-rich vapour by indirect heat exchange with vapourizing oxygen-enriched liquid;
      (5) passing at least some of the resulting condensed nitrogen-rich portion to the column at a point at least one tray above the point where the minor portion of the feed air is introduced into the column; and
      (6) recovering substantially the entire remaining second portion of the nitrogen-rich vapour as product nitrogen.
    • 本发明提供了一种通过进料空气的低温精馏生产相对高产率和纯度的氮的方法,其特征在于(1)将大部分进料空气引入精馏塔,该精馏塔在压力范围为 从241到1000kPa(从35到145psia),并且其中进料空气被分离成富氮蒸气和富氧液体; (2)通过与富氧液体进行间接热交换,在比柱运行时更高的压力下冷凝少部分进料空气; (3)将进料空气的所得缩合次要部分在大部分进料空气引入塔的点上方的至少一个塔盘处引入塔中; (4)通过与汽化富氧液体间接热交换冷凝第一部分富氮蒸汽; (5)将至少一些所得到的冷凝的富氮部分在小部分进料空气引入塔的点上方的至少一个塔盘处传送至塔; 和(6)基本上将所有剩余的第二部分富氮蒸气作为产物氮回收。
    • 5. 发明公开
    • Air separation process
    • Lufttrennungsverfahren。
    • EP0169679A2
    • 1986-01-29
    • EP85304797.5
    • 1985-07-05
    • UNION CARBIDE CORPORATION
    • Beddome, Robert ArthurCheung, Harry
    • F25J3/04
    • F25J3/04103F25J3/0409F25J3/04206F25J3/04303F25J3/04412F25J2250/40F25J2250/50
    • The present invention provides a process for the separation of feed air by countercurrent liquid vapor contact in a higher pressure column and a lower pressure column which are in heat exchange relation at a region where vapor from the higher pressure column cools to warm liquid from the lower pressure column characterised in that:

      (A) liquid is withdrawn from the region of heat exchange relation;
      (B) the withdrawn liquid is vaporized by indirect heat exchange with the major portion of feed air, which is at a pressure substantially the same as that of the higher pressure column, at an elevation lower than the region of heat exchange relation, to partially condense the feed air;
      (C) at least some of the vapor portion of the partially condensed major portion of the feed air is introduced Into the higher pressure column, and
      (D) at least some of the vapor formed in step (B) is recovered at a pressure which exceeds that of the lower pressure column.
    • 本发明提供了一种在较高压力塔和低压塔中通过逆流液相接触分离进料空气的方法,所述高压塔和低压塔在来自高压塔的蒸气冷却至来自下部的温液体的区域处于热交换关系 压力塔,其特征在于:(A)液体从热交换关系的区域中排出;(B)通过与进料空气的主要部分进行间接热交换而将排出的液体汽化,其中压力基本相同 与较高压力塔相比,在高于热交换关系区域的高度处,使进料空气部分冷凝;(C)进料空气的部分冷凝主要部分的至少一些蒸气部分被引入 进入高压塔,并且(D)在超过低压塔的压力的压力下回收步骤(B)中形成的至少一些蒸气。
    • 10. 发明公开
    • Nitrogen generation
    • 氮生成
    • EP0182620A3
    • 1987-04-29
    • EP85308313
    • 1985-11-14
    • UNION CARBIDE CORPORATION
    • Cheung, Harry
    • F25J03/04
    • F25J3/0443F25J3/04212F25J3/04303F25J2200/54F25J2200/92F25J2215/44F25J2290/10
    • The present invention provides a process for the production of nitrogen at relatively high yield and purity by cryogenic rectification of feed air characterized by:
      (1) introducing the major portion of the feed air into a main rectification column which is operating at a pressure in the range of from 241 to 1000 kPa (from 35 to 145 psia), and wherein feed is separated into nitrogen-rich vapor and oxygen-enriched liquid; (2) introducing a minor portion of the feed air into a prefractionation zone at a pressure greater than that at which the main column is operating, and wherein the minor portion is separated into a nitrogen-enriched vapor fraction and an oxygen-enriched liquid fraction; (3) condensing at least some of the nitrogen-enriched vapor fraction by indirect heat exchange with the oxygen-enriched liquid produced in the main column; (4) introducing at least some of the resulting condensed nitrogen-enriched fraction, as reflux liquid and additional feed, into the main column at a point at least one tray above the point where the major portion of the feed air is introduced into the main column; (5) condensing a first portion of the nitrogen-rich vapor by indirect heat exchange with vaporizing oxygen-enriched liquid; (6) passing at leat some of the resulting condensed nitrogen-rich first portion to the main column at a point at least one tray above the point where the condensed nitrogen-enriched fraction is introduced into the main column; and (7) recovering a second portion of the nitrogen-rich vapor as product nitrogen.