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    • 5. 发明公开
    • PROCESS AND APPARATUS FOR PRODUCING PRESSURIZED GASEOUS NITROGEN BY CRYOGENIC SEPARATION OF AIR
    • 通过低温空气分离生产加压气态氮的方法和设备
    • EP3196574A1
    • 2017-07-26
    • EP17020002.6
    • 2017-01-02
    • Linde Aktiengesellschaft
    • IGRA, Robert Michael
    • F25J3/04
    • F25J3/0443F25J3/0257F25J3/04018F25J3/04163F25J3/04187F25J3/04254F25J3/04278F25J3/0429F25J3/04309F25J3/04412F25J3/04496F25J3/04884F25J3/0489F25J2200/04F25J2200/54F25J2200/72F25J2205/84F25J2210/06F25J2210/42F25J2215/42F25J2235/42F25J2240/10F25J2245/40F25J2245/42F25J2270/908
    • The process and the apparatus serve for producing pressurized gaseous nitrogen by cryogenic separation of air in a distillation column system comprising a high pressure column (4), a medium pressure column (5), a main condenser (6) and a medium pressure column top condenser (7) both in the form of condenser-evaporators. A compressed and purified feed air stream (1) is introduced into under a first pressure and cooled in the main heat exchanger (2). At least a portion (3) of the air (1) cooled in a main heat exchanger (2) is introduced into the distillation column system. A first gaseous nitrogen stream (8) from the top the high pressure column (4) is condensed in the main condenser (6). Bottom liquid (16, 19, 21, 25) of the medium pressure column (5) is evaporated and gaseous nitrogen (30) from the top the medium pressure column (5) is condensed in the medium pressure column top condenser (7). Liquid nitrogen (53) from the medium pressure column (5) is pressurized (33) to a pressure which is at least equal to the high pressure column pressure and at least partially (36) introduced into the high pressure column (4). A second gaseous nitrogen stream (40) from the top the high pressure column (4) is recovered as pressurized gaseous nitrogen product. A portion (turbine stream 43) of the compressed and purified feed air stream (1) is workexpanded in an expansion machine (42) from the first pressure to a second pressure and afterwards is warmed in the main heat exchanger (2).
    • 该方法和设备用于通过在包括高压塔(4),中压塔(5),主冷凝器(6)和中压塔顶的蒸馏塔系统中通过低温分离空气来产生加压气态氮 冷凝器(7)均为冷凝器 - 蒸发器的形式。 压缩和净化的进料空气流(1)在第一压力下引入并在主热交换器(2)中冷却。 在主热交换器(2)中冷却的空气(1)的至少一部分(3)被引入蒸馏塔系统。 来自高压塔(4)顶部的第一气态氮流(8)在主冷凝器(6)中冷凝。 中压塔(5)的底部液体(16,19,21,25)被蒸发,并且中压塔(5)顶部的气态氮(30)在中压塔顶冷凝器(7)中冷凝。 来自中压塔(5)的液氮(53)被加压(33)至至少等于高压塔压的压力并且至少部分地(36)引入高压塔(4)。 来自高压塔(4)顶部的第二气态氮流(40)作为加压气态氮产物被回收。 压缩并净化的进料空气流(1)的一部分(涡轮流43)在膨胀机(42)中从第一压力运行膨胀至第二压力,然后在主热交换器(2)中加热。
    • 6. 发明公开
    • Method and device for completely condensing a process gas by cryocondensation
    • 维尔芬和Vorrichtung zuvollständigenKondensation eines Prozessgases mittels Kryokdownensation
    • EP3026379A1
    • 2016-06-01
    • EP14194689.7
    • 2014-11-25
    • L'AIR LIQUIDE, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeAir Liquide Deutschland GmbH
    • Brouns, MarcelBöckling, Matthias
    • F25J1/00F25J1/02B01D5/00
    • F25J1/0072F25J1/0222F25J1/0244F25J2210/42F25J2230/08F25J2230/42F25J2245/42
    • The present invention relates to a method and a device for completely condensing a process gas (P) by cryocondensation, comprising the following steps: cooling a gaseous cooling medium circulating in a cooling loop (10) by a liquid cooling medium in a main heat exchanger (11), whereby vaporizing the liquid cooling medium, feeding the vaporized cooling medium into the cooling loop (10) upstream of the main heat exchanger (11), cooling heat exchange surfaces (5) in a condenser (3) by the gaseous cooling medium circulating in the cooling loop (10), feeding the process gas (P) to be condensed into the condenser (3) to bring it into contact with the heat exchange surfaces (5) in the condenser (3), collecting the condensed process gas (P) as liquid product (LP) in a product container (8), and extracting gaseous cooling medium by an extractor (16) from the cooling loop (10) and guiding it through a pre-cooler (2) for pre-cooling the process gas (P) before feeding it into the condenser (3). The invention allows to completely condensate a process gas (P) by using the cold of a liquid cooling medium in three steps. In a main heat exchanger (11) the phase transfer from liquid to gas is used. In a second step the still very cold gas is introduced into the cooling loop (10), and in a final step the temperature difference between the cooling loop (10) after the heat exchange surfaces (5) in the condenser (3) compared to the environment (25) is mostly used in a pre-cooler (2). This highly efficient use of the cold allows using the process and the device according to the invention on an industrial scale for completely condensing a process gas (P).
    • 本发明涉及一种用于通过冷冻冷凝来完全冷凝工艺气体(P)的方法和装置,包括以下步骤:通过主热交换器中的液体冷却介质冷却在冷却回路(10)中循环的气态冷却介质 (11),其中使液体冷却介质汽化,将蒸发的冷却介质供给到主热交换器(11)上游的冷却回路(10)中,通过气体冷却冷却冷凝器(3)中的热交换表面(5) 介质在冷却回路(10)中循环,将要冷凝的工艺气体(P)供给冷凝器(3)以使其与冷凝器(3)中的热交换表面(5)接触,收集冷凝过程 气体(P)作为产品容器(8)中的液体产物(LP),以及通过提取器(16)从冷却回路(10)提取气态冷却介质,并将其引导通过预冷器(2) 在将工艺气体(P)送入冷凝器(3)之前先冷却。 本发明允许通过三步使用液体冷却介质的冷来完全冷凝工艺气体(P)。 在主热交换器(11)中,使用从液体到气体的相转移。 在第二步骤中,仍然非常冷的气体被引入到冷却回路(10)中,并且在最后的步骤中,冷凝器(3)中的热交换表面(5)之后的冷却回路(10)之间的温度差与 环境(25)主要用于预冷器(2)。 冷却的这种高效的使用允许根据本发明的工艺和装置以工业规模使得完全冷凝工艺气体(P)。