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1. 发明公开

EP2003158A9 DENDRITIC POLYESTER, METHOD FOR PRODUCING THE SAME, AND THERMOPLASTIC RESIN COMPOSITION 有权
标题翻译：树枝状聚酯，工艺用于生产和热塑性树脂组合物
公开(公告)号：EP2003158A9
公开(公告)日：2009-05-06
申请号：EP07740502.5
申请日：2007-03-30
申请人： TORAY INDUSTRIES, INC.
发明人： TACHIKAWA, Koji , YOKOE, Makito , HAMAGUCHI, Mitsushige , SAITO, Makiko , MATSUOKA, Hideo , YAMANAKA, Toru
IPC分类号： C08G63/60
CPC分类号： C08G63/605 , C08G63/914 , C08G83/005 , C08L63/00 , C08L67/00 , C08L77/00 , C08L101/005 , C08L2205/02 , C08L2666/18 , C08L2666/02
摘要： The present invention is directed to a hyperbranched-polyester comprising at least one kind of a structural unit selected from an aromatic oxycarbonyl unit (P), aromatic and/or aliphatic dioxy units (Q), and an aromatic dicarboxy unit (R), and a trifunctional or higher polyfunctional organic residue (B), wherein the content of B is within a range from 7.5 to 50 mol% based on entire monomers constituting the hyperbranched-polyester. The present invention provides a hyperbranched-polyester which can remarkably improve thin-wall flowability, stiffness and gas barrier property by blending with a thermoplastic resin, and a thermoplastic resin composition blended with the same.

2. 发明授权

EP1270671B1 RESIN STRUCTURE AND USE THEREOF 有权
标题翻译：树脂结构及其用途
公开(公告)号：EP1270671B1
公开(公告)日：2006-04-19
申请号：EP00964717.3
申请日：2000-10-06
申请人： TORAY INDUSTRIES, INC. , Mitsui Chemicals, Inc.
发明人： MATSUOKA, Hideo , HAMAGUCHI, Mitsushige , KOBAYASHI, Kazuhiko , TODO, Akira , KODA, Taku
IPC分类号： C08L81/02 , C08L23/00 , B32B27/32 , B32B27/00 , C08J5/00
CPC分类号： B32B27/08 , B32B27/32 , B32B2307/7242 , B32B2307/7265 , B32B2323/04 , B32B2323/10 , B32B2355/02 , B32B2369/00 , B32B2377/00 , B32B2439/00 , B32B2439/70 , B32B2439/80 , B32B2597/00 , C08L23/02 , C08L81/02 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31757 , Y10T428/31797 , Y10T428/31913 , Y10T428/31917 , C08L81/00 , C08L2666/04
摘要： A thermoplastic resin structure characterized in that it comprises a resin composition consisting substantially of 5 to 80 vol.% polyolefin resin (a) and 95 to 20 vol.% polyphenylene sulfide resin (b) and, when examined with an electron microscope, shows separated resin phases in which the polyphenylene sulfide resin (b) constitutes a matrix phase (continuous phase) and the polyolefin resin (a) constitutes a dispersed phase. This thermoplastic resin structure gives plastic containers, tubular objects, and accessories of these which each is excellent in barrier properties, strength, durability, and moldability.
摘要翻译：一种热塑性树脂结构体，其特征在于它包含基本上由5至80体积％聚烯烃树脂（a）和95至20体积％聚苯硫醚树脂（b）组成的树脂组合物，并且当用电子显微镜检查时显示出分离其中聚苯硫醚树脂（b）构成基质相（连续相）和聚烯烃树脂（a）的树脂相构成分散相。该热塑性树脂结构体赋予了阻隔性，强度，耐久性，成型性优异的塑料容器，管状物及其附件。

3. 发明授权

EP3398748B1 METHOD FOR MANUFACTURING COMPOSITE MOLDED BODY 有权
公开(公告)号：EP3398748B1
公开(公告)日：2020-09-23
申请号：EP16881629.6
申请日：2016-12-14
申请人： Toray Industries, Inc.
发明人： HATTORI, Kimihiko , SUGAMORI, Masato , NAKANO, Kazuyoshi , KURODA, Yoshito , MATSUOKA, Hideo , ONODERA, Tomoyuki , HONDA, Yoshiyuki , SHIMIZU, Nobuhiko
IPC分类号： B29C45/14 , B29C33/12 , B29C33/34 , B29C70/54 , B29K105/08

4. 发明授权

EP2415801B1 POLYAMIDE RESIN, POLYAMIDE RESIN COMPOSITION, AND MOLDED ARTICLE COMPRISING SAME 有权
公开(公告)号：EP2415801B1
公开(公告)日：2018-06-06
申请号：EP10758509.3
申请日：2010-03-25
申请人： Toray Industries, Inc.
发明人： KATO, Koya , MASUNAGA, Atsushi , MATSUOKA, Hideo
IPC分类号： C08G69/26 , C08K7/04 , C08L77/06
CPC分类号： C08G69/26 , C08K7/14 , C08L77/06 , C08K7/06
摘要： A polyamide resin obtained by heating and condensation-polymerizing ingredients mainly comprising pentamethylenediamine having a total content of 2,3,4,5-tetrahydropyridine and piperidine of 0.10 wt.% or lower and an aliphatic dicarboxylic acid having 7 or more carbon atoms, a 0.01 g/mL solution of the polyamide resin in 98% sulfuric acid having a relative viscosity at 25 °C of 1.8-4.5. The polyamide resin has excellent heat resistance, extremely low water absorption, and excellent melt residence stability and is hence suitable for use as long molded articles represented by automotive radiator tanks, etc.

5. 发明公开

EP2402385A1 METHOD FOR PRODUCING POLYAMIDE RESIN 有权
标题翻译： VERFAHREN ZUR POLYAMIDKUNSTHARZHERSTELLUNG
公开(公告)号：EP2402385A1
公开(公告)日：2012-01-04
申请号：EP10746215.2
申请日：2010-02-24
申请人： Toray Industries, Inc.
发明人： KATO, Koya , MASUNAGA, Atsushi , MATSUOKA, Hideo
IPC分类号： C08G69/28 , C08G69/26 , C08K3/00 , C08L77/06
摘要： A method for producing a polyamide resin characterized by comprising thermally polycondension of tetramethylene diamine and either an aliphatic dicarboxylic acid having 7 or more carbon atoms or a salt thereof, and then being melt-polymerized at a temperature equal to or higher than the melting point thereof until the relative viscosity of a 0.01 g/ml solution thereof in 98% sulfuric acid solution with a 0.01 g/ml content at 25 °C becomes 2.2-5.0.
摘要翻译：一种聚酰胺树脂的制造方法，其特征在于，含有四亚甲基二胺和碳原子数7以上的脂肪族二羧酸的热聚缩醛或其盐，然后在等于或高于其熔点的温度下进行熔融聚合直到在25℃下0.01g / ml含量的98％硫酸溶液中的0.01g / ml溶液的相对粘度为2.2-5.0。

6. 发明公开

EP2003158A2 DENDRITIC POLYESTER, METHOD FOR PRODUCING THE SAME, AND THERMOPLASTIC RESIN COMPOSITION 有权
标题翻译： DENDRITISCHER POLYESTER，HERSTELLUNGSVERFAHRENDAFÜRUND THERMOPLASTHARZZUSAMMENSETZUNG
公开(公告)号：EP2003158A2
公开(公告)日：2008-12-17
申请号：EP07740502.5
申请日：2007-03-30
申请人： TORAY INDUSTRIES, INC.
发明人： TACHIKAWA, Koji , YOKOE, Makito , HAMAGUCHI, Mitsushige , SAITO, Makiko , MATSUOKA, Hideo , YAMANAKA, Toru
IPC分类号： C08G63/60
CPC分类号： C08G63/605 , C08G63/914 , C08G83/005 , C08L63/00 , C08L67/00 , C08L77/00 , C08L101/005 , C08L2205/02 , C08L2666/18 , C08L2666/02
摘要： The present invention is directed to a hyperbranched-polyester comprising at least one kind of a structural unit selected from an aromatic oxycarbonyl unit (P), aromatic and/or aliphatic dioxy units (Q), and an aromatic dicarboxy unit (R), and a trifunctional or higher polyfunctional organic residue (B), wherein the content of B is within a range from 7.5 to 50 mol% based on entire monomers constituting the hyperbranched-polyester. The present invention provides a hyperbranched-polyester which can remarkably improve thin-wall flowability, stiffness and gas barrier property by blending with a thermoplastic resin, and a thermoplastic resin composition blended with the same.
摘要翻译：本发明涉及包含选自芳族氧羰基单元（P），芳族和/或脂族二氧单元（Q）和芳族二羧单元（R）中的至少一种结构单元的超支化聚酯，以及三官能以上的多官能性有机残基（B），其中B的含量相对于构成超支化聚酯的全部单体为7.5〜50摩尔％。本发明提供一种超支化聚酯，其可以通过与热塑性树脂共混和与其共混的热塑性树脂组合物显着提高薄壁流动性，刚度和阻气性。

7. 发明授权

EP2402385B1 METHOD FOR PRODUCING POLYAMIDE RESIN 有权
公开(公告)号：EP2402385B1
公开(公告)日：2019-12-25
申请号：EP10746215.2
申请日：2010-02-24
申请人： Toray Industries, Inc.
发明人： KATO, Koya , MASUNAGA, Atsushi , MATSUOKA, Hideo
IPC分类号： C08G69/28 , C08G69/26 , C08L77/06

8. 发明授权

EP2305735B1 POLYAMIDE RESIN, COMPOSITION CONTAINING THE POLYAMIDE RESIN, AND MOLDED ARTICLES OF THE POLYAMIDE RESIN AND THE COMPOSITION 有权
标题翻译：聚酰胺树脂，含有聚酰胺树脂的组合物，以及聚酰胺树脂的成型制品和组合物
公开(公告)号：EP2305735B1
公开(公告)日：2017-09-06
申请号：EP09773424.8
申请日：2009-06-29
申请人： Toray Industries, Inc.
发明人： KATO, Koya , AKITA, Masaru , MATSUOKA, Hideo
IPC分类号： C08G69/00 , C08K3/00 , C08K9/04 , C08L77/00
CPC分类号： C08G69/265 , C08G69/36 , C08K7/28 , C08L77/06
摘要： Disclosed is a polyamide resin which is produced by the polycondensation of (A) pentamethylenediamin, (B) terephthalic acid and/or a derivative thereof, and (C) at least one member selected from adipic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, isophthalic acid, 1,9-diaminononane, 1,10-diaminodecane, 1,12-diaminododecane,caprolactam, undecalactam,laurolactam, aminocaproic acid, 11-aminoundecanoic acid, 12-aminododecanoic acid, and derivatives of these compounds. In the polyamide resin, the ratio of a repeating unit derived from the component (C) is 10 to 50 wt% (inclusive) relative to the total weight of the polymer. A solution of the polyamide resin in 98 % sulfuric acid, which contains the polyamide resin at a concentration of 0.01 g/ml, has a relative viscosity of 1.5 to 4.5 at 25°C.
摘要翻译：（A）五亚甲基二胺，（B）对苯二甲酸和/或其衍生物，和（C）选自己二酸，癸二酸，十一烷二酸，十二烷二酸的至少一种的缩聚制得的聚酰胺树脂，间苯二甲酸，1,9-二氨基壬烷，1,10-二氨基癸烷，1,12-二氨基十二烷，己内酰胺，十一内酰胺，月桂内酰胺，氨基己酸，11-氨基十一烷酸，12-氨基十二烷酸以及这些化合物的衍生物。在聚酰胺树脂中，相对于聚合物的总重量，源自组分（C）的重复单元的比例为10至50重量％（包括端值）。含有浓度为0.01g / ml的聚酰胺树脂的98％硫酸中的聚酰胺树脂溶液在25℃时的相对粘度为1.5〜4.5。

9. 发明公开

EP2746315A1 METHOD FOR MANUFACTURING CRYSTALLINE POLYAMIDE RESIN 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG EINES KRISTALLINEN POLYAMIDHARZES
公开(公告)号：EP2746315A1
公开(公告)日：2014-06-25
申请号：EP12823636.1
申请日：2012-08-13
申请人： Toray Industries, Inc.
发明人： KATO, Koya , MASUNAGA, Atsushi , HATANO, Eri , MATSUOKA, Hideo
IPC分类号： C08G69/28 , C08G69/26 , C08K3/00 , C08K5/00 , C08L77/06
CPC分类号： C08G69/28 , C08G69/265 , C08G69/36 , C08K5/005 , C08K7/06 , C08K7/14 , C08L77/06
摘要： There is provided a production method of a crystalline polyamide resin by thermal polycondensation of a mixture including at least a diamine component, a dicarboxylic acid component and water as a starting material, wherein the diamine component includes (A) pentamethylene diamine at a ratio that is equal to or greater than 10 mol% and less than 80 mol% relative to a gross amount of the diamine component; and the dicarboxylic acid component includes (B) at least one selected from the group consisting of an aromatic dicarboxylic acid, an alicyclic dicarboxylic acid and dialkyl ester derivatives thereof at a ratio that is equal to or greater than 76 mol% and equal to or less than 100 mol% relative to a gross amount of the dicarboxylic acid component, the production method comprising: a first step that heats the above mixture, which has a water content equal to or less than 30% by weight, at a temperature equal to or higher than 200°C under a pressure of 1.8 to 3.5 MPa to perform polycondensation with distillation of water; a second step that releases pressure to an atmospheric pressure level, subsequent to the first step; and a third step that continues thermal polycondensation subsequent to the second step, so as to obtain the crystalline polyamide resin, the third step performing high-degree melt polymerization at a temperature that is equal to or higher than a melting point of the crystalline polyamide resin until a relative viscosity at 25°C of a solution prepared by dissolving the obtained crystalline polyamide resin at a concentration of 0.01 mg/mL in 98% sulfuric acid reaches between 1.8 and 3.5.
摘要翻译：提供了结晶性聚酰胺树脂的制造方法，其中通过以至少二胺成分，二羧酸成分和水为原料的混合物进行热缩聚而得到的结晶性聚酰胺树脂，其中二胺成分包含（A）五亚甲基二胺，相对于二胺成分的总量为10摩尔％以上且小于80摩尔％并且所述二羧酸成分包含（B）选自芳族二羧酸，脂环族二羧酸及其二烷基酯衍生物中的至少一种，其比例等于或大于76摩尔％且等于或小于相对于二羧酸成分的总量为100摩尔％以下的制造方法，其特征在于，包括：在等于或等于或等于30℃的温度下加热上述混合物的水含量等于或小于30重量％的第一步骤，在1.8〜3.5MPa的压力下高于200℃进行水蒸馏缩聚; 在第一步骤之后将压力释放到大气压力水平的第二步骤; 以及第三步骤，继续第二步骤之后的热缩聚，得到结晶性聚酰胺树脂，第三步骤在结晶性聚酰胺树脂的熔点以上的温度下进行高度熔融聚合直到通过将得到的结晶性聚酰胺树脂以0.01mg / mL的浓度溶解在98％硫酸中而制备的溶液在25℃下的相对粘度达到1.8〜3.5。

10. 发明授权

EP0835904B1 FLAME-RETARDANT RESIN COMPOSITION AND MOLDINGS 失效
标题翻译：隔爆树脂组合物和模塑料
公开(公告)号：EP0835904B1
公开(公告)日：2003-07-09
申请号：EP97919660.7
申请日：1997-04-23
申请人： TORAY INDUSTRIES, INC.
发明人： MATSUOKA, Hideo , YAMAUCHI, Kouji , INOUE, Toshihide
IPC分类号： C08K5/3477 , C08K3/32 , C08K7/16 , C08L101/00 , C08L67/00 , C08K5/13 , C08K3/02 , C08K5/3492
CPC分类号： C08K3/32 , C08K5/34928
摘要： A flame-retardant resin composition comprising: (A) 100 parts by weight of a thermoplastic resin and, blended therewith; (B) 0.1 to 100 parts by weight of red phosphorus; and (C) 0.5 to 100 parts by weight of a salt comprising a triazine compound and cyanuric or isocyanuric acid, wherein the number-average diameter of dispersed particles of red phosphorus in the resin composition is 50 to 0.01 mu m, and that of dispersed particles of the salt is 100 to 0.01 mu m. This composition has an excellent flame retardancy and maintains the properties inherent in the resin and, hence, is suitable for mechanical mechanism parts, electric components, electronic components, automobile parts, or the like.

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