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    • 5. 发明公开
    • TERMINAL-MODIFIED POLYAMIDE RESIN, METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING MOLDED ARTICLES
    • 末端改性的聚酰胺树脂,用于生产及其制造方法形状的物体
    • EP3150654A1
    • 2017-04-05
    • EP15800376.4
    • 2015-05-28
    • Toray Industries, Inc.
    • OKUBO, TakuroTANAKA, TsuyoshiKATO, Koya
    • C08G69/40C08L77/00
    • C08G69/40B29C45/0001B29K2077/00B29K2995/0037
    • The present invention addresses the problem of providing a high molecular weight, terminal modified polyamide resin having a low melt viscosity and excellent molding processability.
      The problem is solved by a terminal modified polyamide resin having a relative viscosity (ηr), as measured at 25°C in a 98% sulfuric acid solution at a resin concentration of 0.01 g/ml, of 2.1 to 10, the resin comprising 0.05 to 4.5% by mass of a terminal structure represented by general formula (I):

              -X-(R 1 -O) n -R 2      (I)

      wherein n ranges from 2 to 100; R 1 represents a hydrocarbon group of 2 to 10 carbon atoms; R 2 represents a hydrocarbon group of 1 to 30 carbon atoms; -X- represents - NH- or -N(CH 3 )-; and n R 1 s in the general formula (I) may be the same or different.
    • 本发明解决了这个问题,提供的高分子量,具有低熔融粘度和优异的模塑加工性末端改性聚酰胺树脂。 麻烦的是由具有相对粘度(* R)末端改性聚酰胺树脂解决了,在98%的硫酸溶液在0.01克的树脂浓度在25℃下所测量/ ml时,为2.1〜10中,树脂包括 0点05分至4.5%的由通式(I)所示的末端结构的质量:€€ƒƒƒ€€€ƒƒƒ€€€ƒƒ-X-(R 1 -O)N -R 2€ƒ€ ƒƒ€€€ƒƒ(I)worin n的范围为2至100; R 1表示的含2-10个碳原子的烃基; R 2 darstellt的烃基的1〜30个碳原子; -X- darstellt - NH-或-N(CH 3) - ; 和n个R 1的通式(I)中可以是相同的或不同的。