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1. 发明授权

EP0331608B1 Organothioethyl alcohol segmers as antidegradant synergists 失效
标题翻译： Organothioäthylalkohole增效剂的抗降解剂。
公开(公告)号：EP0331608B1
公开(公告)日：1995-01-18
申请号：EP89630042.3
申请日：1989-03-03
申请人： THE GOODYEAR TIRE & RUBBER COMPANY
发明人： Cottmann, Kirkwood Storer
IPC分类号： C08K5/00 , C08L101/00 , C10M135/24 , C10M151/02
CPC分类号： C09K15/28 , C07C323/12 , C08C19/06 , C08C19/40 , C08K5/372

2. 发明公开

EP0446554A1 Preparation of a N-substituted phenylenediamine 失效
标题翻译： Herstellung eine N-取代的苯基。
公开(公告)号：EP0446554A1
公开(公告)日：1991-09-18
申请号：EP90630234.4
申请日：1990-12-18
申请人： THE GOODYEAR TIRE & RUBBER COMPANY
发明人： Cottmann, Kirkwood Storer
IPC分类号： C07C209/24 , C07C213/02 , C07C217/08 , C07C211/55
CPC分类号： C07C209/24 , C07C249/02
摘要： The present invention relates to a process for the preparation of a N-substituted phenylenediamine of the formula:

comprising reacting N-phenylquinoneimine of the formula:

with a primary amine of the formula:

R-NH₂ (III)

,

wherein the molar ratio of II to III in the reaction mixture ranges from about 1:1 to 1:10; and wherein R is selected from the group of radicals consisting of alkyls having 1 to 20 carbon atoms, cycloalkyls having 6 to 8 carbon atoms and radicals of the structural formula:

wherein R² may be the same or different and is independently selected from the group of radicals consisting of hydrogen and an alkyl having 1 carbon atom, R³ is selected from the group of radicals consisting of an alkyl having 1 to 12 carbon atoms and n is an integer of from 0 to 6. The present process is characterized by its excellent yields of high purity N-substituted phenylenediamines.
摘要翻译：本发明涉及制备下式的N-取代苯二胺的方法：包括使下式的N-苯基醌亚胺与下式的伯胺反应：式中：R-NH 2（III），其中反应混合物中II与III的摩尔比为约1:1至1:10; 并且其中R选自具有1至20个碳原子的烷基，具有6至8个碳原子的环烷基和具有以下结构式的基团的基团：CHEM，其中R 2可以相同或不同，并且为独立地选自氢和具有1个碳原子的烷基组成的基团，R 3选自由具有1至12个碳原子的烷基和n是0至6的整数组成的基团。本发明方法的特征在于其高纯度N-取代苯二胺的优异产率。

3. 发明授权

EP0446554B1 Preparation of a N-substituted phenylenediamine 失效
标题翻译： N-取代的苯乙烯胺的制备
公开(公告)号：EP0446554B1
公开(公告)日：1993-10-13
申请号：EP90630234.4
申请日：1990-12-18
申请人： THE GOODYEAR TIRE & RUBBER COMPANY
发明人： Cottmann, Kirkwood Storer
IPC分类号： C07C209/24 , C07C213/02 , C07C217/08 , C07C211/55
CPC分类号： C07C209/24 , C07C249/02

4. 发明公开

EP0331608A1 Organothioethyl alcohol segmers as antidegradant synergists 失效
标题翻译：有机硫代酸钠协同助剂。
公开(公告)号：EP0331608A1
公开(公告)日：1989-09-06
申请号：EP89630042.3
申请日：1989-03-03
申请人： THE GOODYEAR TIRE & RUBBER COMPANY
发明人： Cottmann, Kirkwood Storer
IPC分类号： C08K5/00 , C08L101/00 , C10M135/24 , C10M151/02
CPC分类号： C09K15/28 , C07C323/12 , C08C19/06 , C08C19/40 , C08K5/372
摘要： This invention is concerned with the stabilization of organic materials subject to oxidative degradation. The synergists of this invention possess organothioethyl alcohol segmers or moieties which enhance the antioxidative activity of phenolic and amine stabilizers. The invention is also concerned with compounds that contain an organothioethyl alcohol moiety and their use in oxidizable materials in combination with polymerizable and/or conventional antidegradants.
摘要翻译：本发明涉及经历氧化降解的有机材料的稳定化。本发明的增效剂具有提高酚和胺稳定剂的抗氧化活性的有机硫代乙醇分子或部分。本发明还涉及含有有机硫醇部分的化合物及其在可氧化材料中与可聚合和/或常规抗降解剂组合的用途。

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