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    • 4. 发明公开
    • Method for recovery of cerium oxide
    • Verfahren zur Wiedergewinnung eines Ceroxids
    • EP2607445A2
    • 2013-06-26
    • EP12197351.5
    • 2012-12-14
    • Shin-Etsu Chemical Co., Ltd.
    • MATSUI, HarunobuHARADA, DaijitsuTAKEUCHI, Masaki
    • C09K3/14
    • C09K3/1409C01F17/0043C09G1/02
    • A method for recovery of cerium oxide from the abrasive waste composed mainly of cerium oxide arising from the polishing of glass substrates, said method including the steps of (i) adding to the abrasive waste an aqueous solution of a basic substance; (ii) adding to the resulting solution a precipitant, thereby forming precipitates composed mainly of cerium oxide, and removing the supernatant liquid; (iii) adding to the resulting precipitates a solution of an acid substance, thereby making said precipitate slightly acid to neutral; (iv) washing the precipitates with an organic solvent; and (v) drying and crushing the precipitates.
      The method makes it possible to recycle abrasive waste into a pure abrasive composed mainly of cerium oxide which can be reused to polish synthetic quartz glass substrates for state-of-the-art semiconductor technology relating to photomasks and reticles.
    • 一种从由玻璃基板抛光产生的主要由氧化铈组成的磨料废料回收氧化铈的方法,所述方法包括以下步骤:(i)向研磨废料中加入碱性物质的水溶液; (ii)向所得溶液中加入沉淀剂,从而形成主要由氧化铈组成的析出物,除去上清液; (iii)向所得沉淀中加入酸性物质的溶液,从而使所述沉淀物略微酸中性; (iv)用有机溶剂洗涤沉淀物; 和(v)干燥并粉碎沉淀物。 该方法可以将磨料废料回收成主要由氧化铈组成的纯磨料,这可以重复使用以抛光合成石英玻璃基底,用于与光掩模和掩模版有关的最先进的半导体技术。