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1. 发明公开

EP3374470A1 METHOD TO REMOVE METALS FROM PETROLEUM 有权
公开(公告)号：EP3374470A1
公开(公告)日：2018-09-19
申请号：EP16784718.5
申请日：2016-10-12
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , SHAFEI, Emad, N. , PUNETHA, Ashok, K. , LEE, Joo-Hyeong , ALABDULLAH, Mohammad, A.
IPC分类号： C10G31/08 , C10G21/08 , C10G31/06 , C10G31/10
摘要： A method to remove a metals impurity from a petroleum feedstock for use in a power generating process is provided. The method comprising the steps of mixing a heated feedstock with a heated water stream in a mixing device to produce a mixed stream; introducing the mixed stream to a supercritical water reactor in the absence of externally provided hydrogen and externally provided oxidizing agent to produce a reactor effluent comprising a refined petroleum portion; cooling the reactor effluent to produce a cooled stream; feeding the cooled stream to a rejecter configured to separate a sludge fraction to produce a de-sludged stream; reducing the pressure of the de-sludged stream to produce a depressurized product; separating the depressurized product to produce a gas phase product and a liquid product; separating the liquid product to produce a petroleum product, having a reduced asphaltene content, reduced concentration of metals impurity, and reduced sulfur.

2. 发明公开

EP3224333A1 PROCESS FOR HEAVY OIL UPGRADING IN A DOUBLE-WALL REACTOR 有权
标题翻译：双壁反应器中重油改质的过程
公开(公告)号：EP3224333A1
公开(公告)日：2017-10-04
申请号：EP15804655.7
申请日：2015-11-19
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , LEE, Joo-Hyeong , ALABDULHADI, Abdullah T.
IPC分类号： C10G31/08 , C10G45/26 , C10G49/18 , C10G1/06 , B01J19/24 , B01J3/00
摘要： A process for reducing coke formation during hydrocarbon upgrading reactions using a double-wall reactor comprising the steps of feeding a heated feed water to a shell-side volume of the double-wall reactor to produce a heat transfer stream, the double-wall reactor comprising an exterior wall and an interior wall, a reaction section volume, a heating element configured to heat the heat transfer stream, wherein heat is transferred from the heat transfer stream to the reaction section volume, feeding the hot water return exiting the shell-side volume through a filter; mixing the filtered water stream with a heated hydrocarbon feedstock; feeding the mixed stream to the reaction section volume in a configuration counter-current to the heat transfer stream; reacting the reaction flow stream at a reaction temperature, wherein the heat transferred to the reaction section volume is operable to maintain the reaction temperature above the critical temperature of water.
摘要翻译：一种使用双壁反应器在烃改质反应过程中减少焦炭形成的方法，该方法包括以下步骤：将加热的给水加入到双壁反应器的壳侧体积中以产生传热流，所述双壁反应器包含外壁和内壁，反应部分体积，加热元件，其被构造成加热传热流，其中热量从传热流传递到反应部分体积，将离开壳侧体积的热水返回通过过滤器; 将过滤的水流与加热的烃原料混合; 以与传热流逆流的构造将混合物流供入反应区体积; 在反应温度下使反应流动物流反应，其中转移到反应区段体积的热量可操作以保持反应温度高于水的临界温度。

3. 发明授权

EP3567089B1 APPARATUS TO REMOVE METALS FROM PETROLEUM 有权
公开(公告)号：EP3567089B1
公开(公告)日：2020-07-22
申请号：EP19183019.9
申请日：2016-10-12
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , SHAFEI, Emad, N. , PUNETHA, Ashok, K , LEE, Joo-Hyeong , ALABDULAH, Mohammad, A.
IPC分类号： C10G31/08 , C10G21/08 , C10G31/06 , C10G31/10 , C10G55/02 , C10G9/00

4. 发明授权

EP2588569B1 REMOVAL OF SULFUR COMPOUNDS FROM PETROLEUM STREAM 有权
标题翻译：从石油流中除去硫化合物
公开(公告)号：EP2588569B1
公开(公告)日：2017-11-22
申请号：EP11729845.5
申请日：2011-06-22
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , ALJISHI, Mohammad, Fuad , PUNETHA, Ashok, K. , AL-DOSSARY, Mohammed, R. , LEE, Joo-Hyeong , AL-OTAIBI, Bader, M.
IPC分类号： C10G9/00 , C10G19/02 , C10G21/08 , C10G55/04 , B01D11/04 , B01J3/00 , C10G21/02 , C10G31/08
CPC分类号： C10G9/00 , C10G19/02 , C10G21/02 , C10G21/08 , C10G31/08 , C10G55/04 , C10G2300/1033 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/308 , C10G2300/4081 , C10G2300/44 , C10G2300/805

5. 发明公开

EP3143103A1 PROCESS TO PRODUCE AROMATICS FROM CRUDE OIL 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG VON AROMATEN AUSROHÖL
公开(公告)号：EP3143103A1
公开(公告)日：2017-03-22
申请号：EP15723818.9
申请日：2015-05-12
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , LEE, Joo-Hyeong , SHAFEI, Emad N. , AL-FAQEER, Faisal M.
IPC分类号： C10G33/00 , B01J3/00 , C10G55/04 , C10G9/00 , C10G21/00
CPC分类号： C07C4/04 , C07C7/005 , C07C7/10 , C10G9/00 , C10G9/002 , C10G21/00 , C10G33/00 , C10G55/04 , C10G2300/4006 , C10G2300/4012 , C10G2400/30
摘要： A process for producing aromatics from a hydrocarbon source in the presence of supercritical water comprising the steps of mixing a pressurized, pre-heated water stream with a pressurized, pre-heated petroleum feedstock, the pressurized, pre-heated water stream at a pressure above the critical pressure of water and a temperature above the critical temperature of water, feeding the combined stream to a supercritical water reactor to create a modified stream, cooling and depressurizing the modified stream, separating the depressurized stream in a vapor-liquid separator, condensing the vapor stream, separating the condensed stream into a water recovery stream and a light product recovery stream, extracting the aromatics from the light product recovery stream, depressurizing the liquid stream, separating the depressurized liquid stream in a heavy separator into an upgraded product stream, and recycling part of the upgraded product stream to the pressurized, pre-heated petroleum feedstock as a product recycle.
摘要翻译：在超临界水存在下从烃源生产芳族化合物的方法，包括以下步骤：将加压的预热水流与加压的预加热的石油原料混合，加压的预热水流以上述压力水的临界压力和高于水临界温度的温度，将组合的料流输送到超临界水反应器以产生改性流，冷却和减压改性流，将气 - 液分离器中的减压流分离，冷凝将冷凝物流分离成水回收物流和轻质产物回收物流，从轻质产物回收物流中萃取芳族化合物，使液体物流减压，将重质分离器中的减压液体物流分离成升级产物流，以及将部分升级后的产品流再循环到加压预热的石油原料中产品回收。

6. 发明公开

EP3390583A1 SUPERCRITICAL WATER PROCESSES FOR UPGRADING A PETROLEUM-BASED COMPOSITION WHILE DECREASING PLUGGING 有权
公开(公告)号：EP3390583A1
公开(公告)日：2018-10-24
申请号：EP16829159.9
申请日：2016-12-12
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , ALQARZOUH, Muneef F. , LEE, Joo-Hyeong , AL-OTAIBI, Bader M. , ALABDULHADI, Abdullah T.
IPC分类号： C10G75/00 , C10G31/08 , C10G45/26 , C10G49/00 , C10G47/32 , C10G9/16 , C10G45/72 , C10L10/04
CPC分类号： C10G75/00 , C10G9/00 , C10G9/16 , C10G31/08 , C10G45/26 , C10G45/72 , C10G47/32 , C10G49/005 , C10G49/007 , C10G75/04 , C10G2300/1011 , C10G2300/1037 , C10G2300/4006 , C10G2300/4012 , C10L10/04 , C10L2290/58 , Y02P30/20
摘要： Embodiments of processes for upgrading a petroleum-based composition while decreasing plugging comprise mixing a supercritical water stream with a pressurized, heated petroleum-based composition in a mixing device to create a combined feed stream, and introducing to a supercritical upgrading reactor system are provided. The processes also comprise cooling the upgraded product in a cooling device, and decreasing the pressure of the cooled upgraded product in a pressure reducer. To reduce plugging, the processes also comprises injecting plug remover solution into one or more of the following injection locations: an injection port on a process line connecting the mixing device with the upgrading reactor system; an injection port on a process line connecting the upgrading reactor system with the cooling device; or an injection port on a process line connecting the cooling device with the pressure reducer.

7. 发明公开

EP2964731A1 PROCESS TO UPGRADE AND DESULFURIZE CRUDE OIL BY SUPERCRITICAL WATER 有权
标题翻译：程序进行处理和原油脱硫BY超临界水
公开(公告)号：EP2964731A1
公开(公告)日：2016-01-13
申请号：EP14714007.3
申请日：2014-03-05
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , LEE, Joo-Hyeong , GARHOUSH, Mohammad, S.
IPC分类号： C10G31/09 , C10G31/08 , B01D11/02 , B01J3/00 , B01D29/00
摘要： This present invention generally relates to a process for upgrading and desulfurizing crude oil using supercritical water. In general, the invention provides a process for removal of contaminants from a crude oil stream by mixing the crude oil stream with supercritical water and then filtering out the precipitated solid compounds that result from mixing the crude oil stream with supercritical water.

8. 发明授权

EP2964731B1 PROCESS TO UPGRADE AND DESULFURIZE CRUDE OIL BY SUPERCRITICAL WATER 有权
公开(公告)号：EP2964731B1
公开(公告)日：2020-04-22
申请号：EP14714007.3
申请日：2014-03-05
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , LEE, Joo-Hyeong , GARHOUSH, Mohammad, S.
IPC分类号： C10G31/09 , C10G31/08 , B01D11/02 , B01J3/00 , B01D29/00 , C10G53/02 , C10G45/26 , B01D11/04

9. 发明公开

EP3567089A1 METHOD TO REMOVE METALS FROM PETROLEUM 有权
公开(公告)号：EP3567089A1
公开(公告)日：2019-11-13
申请号：EP19183019.9
申请日：2016-10-12
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , SHAFEI, Emad, N. , PUNETHA, Ashok, K , LEE, Joo-Hyeong , ALABDULAH, Mohammad, A.
IPC分类号： C10G31/08 , C10G21/08 , C10G31/06 , C10G31/10 , C10G55/02 , C10G9/00
摘要： A method to remove a metals impurity from a petroleum feedstock for use in a power generating process is provided. The method comprising the steps of mixing a heated feedstock with a heated water stream in a mixing device to produce a mixed stream; introducing the mixed stream to a supercritical water reactor in the absence of externally provided hydrogen and externally provided oxidizing agent to produce a reactor effluent comprising a refined petroleum portion; cooling the reactor effluent to produce a cooled stream; feeding the cooled stream to a rejecter configured to separate a sludge fraction to produce a de-sludged stream; reducing the pressure of the de-sludged stream to produce a depressurized product; separating the depressurized product to produce a gas phase product and a liquid product; separating the liquid product to produce a petroleum product, having a reduced asphaltene content, reduced concentration of metals impurity, and reduced sulfur.

10. 发明授权

EP3224333B1 PROCESS AND APPARATUS FOR HEAVY OIL UPGRADING IN A DOUBLE-WALL REACTOR 有权
公开(公告)号：EP3224333B1
公开(公告)日：2019-11-13
申请号：EP15804655.7
申请日：2015-11-19
申请人： Saudi Arabian Oil Company
发明人： CHOI, Ki-Hyouk , LEE, Joo-Hyeong , ALABDULHADI, Abdullah T.
IPC分类号： C10G31/08 , C10G45/26 , C10G49/18 , C10G1/06 , B01J19/24 , B01J3/00

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