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1. 发明公开

EP1293837A2 Electrophotographic organophotoreceptors 有权
标题翻译：电子照相机组织器光感受器
公开(公告)号：EP1293837A2
公开(公告)日：2003-03-19
申请号：EP02256280.5
申请日：2002-09-11
申请人： SAMSUNG ELECTRONICS CO., LTD.
发明人： Law, Kam W. , Jubran, Nusrallah , Tokarski, Zbigniew , Katritzky, Alan R. , Jain, Ritu , Maimait, Rexiat , Vakulenko, Anatoliv V.
IPC分类号： G03G5/06
CPC分类号： G03G5/0612 , G03G5/0616
摘要： An organophotoreceptor that includes (a) a charge transport material having the formula
wherein A is selected from heterocyclic groups, naphthyl group, (9H-fluoren-9-ylidene)benzyl group, alkylsulfonylphenyl, or stilbenyl, B is selected from hydrogen, alkyl group, and an aryl group, with the proviso that when A is naphthyl, B is naphthyl; and wherein R 1 is selected from the group consisting of N-pyrrolyl, N-pyrazolyl, N-tetrazolyl, N-indolyl, N-carbazolyl, N-triazolyl, N-imidazolyl, N-benzimidazolyl, N-indazolyl, and N-benzotriazolyl group, and R 3 is a 9-fluorenone group, (b) a charge generating compound, and (c) an electrically conductive substrate. Therefore, an organophotoreceptor having good mechanical and electrostatic properties can be obtained by using a charge transport material including 9H-fluoren-9-one hydrazino substituted compounds and derivatives thereof. Also, an electrophotographic imaging apparatus for obtaining high quality image even after repeated cycles can be attained by employing the organophotoreceptor.
摘要翻译：一种有机光感受器，其包括（a）具有式CHEM的电荷传输材料，其中A选自杂环基，萘基，（9H-芴-9-亚基）苄基，烷基磺酰基苯基或茋基，B选自氢，烷基和芳基，条件是当A为萘基时，B为萘基; 并且其中R 1选自N-吡咯基，N-吡唑基，N-四唑基，N-吲哚基，N-咔唑基，N-三唑基，N-咪唑基，N-苯并咪唑基，N-吲唑基和N-苯并三唑基基团，R3是9-芴酮基团，（b）电荷产生化合物，和（c）导电基材。因此，通过使用包含9H-芴-9-酮肼取代的化合物及其衍生物的电荷输送材料，可以获得具有良好机械和静电特性的有机光感受器。此外，即使在重复循环之后获得高质量图像的电子照相成像装置也可以通过使用有机光感受器来实现。

2. 发明公开

EP1283448A3 Electrophotographic organophotoreceptors with charge transport compounds 有权
标题翻译：具有电荷转移化合物的电子照相有机感光体
公开(公告)号：EP1283448A3
公开(公告)日：2003-05-02
申请号：EP02255547.8
申请日：2002-08-08
申请人： Samsung Electronics Co., Ltd.
发明人： Law, Kam W. , Jubran, Nusrallah , Tokarski, Zbigniew , Katritzky, Alan R. , Jain, Ritu , Maimait, Rexiat
IPC分类号： G03G5/06 , C07D209/86 , C07D409/12 , C07D403/12
CPC分类号： C07D403/12 , C07D209/86 , C07D409/12 , G03G5/06 , G03G5/0614 , G03G5/0616 , G03G5/062 , G03G5/0627 , G03G5/0629 , G03G5/0631 , G03G5/0633 , G03G5/0642
摘要： A novel charge transport compound, a novel process using that novel compound and an organophotoreceptor includes (a) a novel charge transport compound having the formula where R 1 and R 2 are selected so that R 1 and R 2 form, with the included nitrogen atom, a group selected from the group consisting of heterocyclic rings, aromatic rings, and dinaphthylamine; or R 1 comprises an C5-C40 aryl group and R 2 comprises a group selected from the group consisting of sulfolanyl, 4-(9H-fluoren-9-ylidene)benzyl, pyrrolyl, pyrazolyl, benzotriazolyl, stilbenyl, tetrazolyl; or R 1 comprises hydrogen, C1-C30 alkyl group, C5-C40 aryl group and R 2 comprises sulfonylphenyl, R 3 is hydrogen, C1-C30 alkyl group, C5-C40 aryl group, heterocyclic group or a hydrocarbon group; and Q is a 3-carbazole group; (b) a charge generating compound; and (c) an electrically conductive substrate.
摘要翻译：新型电荷输送化合物，使用该新型化合物和有机光感受器的新型方法包括（a）具有下式的新型电荷输送化合物其中R 1和R 2选择为使得R 1和R 2与所包含的氮原子一起形成选择的基团选自杂环，芳环和二萘胺; 或R1包含C5-C40芳基并且R2包含选自环丁砜基，4-（9H-芴-9-亚基）苄基，吡咯基，吡唑基，苯并三唑基，芪基，四唑基的基团; 或R1包含氢，C1-C30烷基，C5-C40芳基和R2包含磺酰基苯基，R3为氢，C1-C30烷基，C5-C40芳基，杂环基或烃基; Q是3-咔唑基团; （b）电荷产生化合物; 和（c）导电基材。

3. 发明授权

EP1293837B1 Electrophotographic organophotoreceptors 有权
标题翻译：一种电子照相有机感光体
公开(公告)号：EP1293837B1
公开(公告)日：2008-10-08
申请号：EP02256280.5
申请日：2002-09-11
申请人： SAMSUNG ELECTRONICS CO., LTD.
发明人： Law, Kam W. , Jubran, Nusrallah , Tokarski, Zbigniew , Katritzky, Alan R. , Jain, Ritu , Maimait, Rexiat , Vakulenko, Anatoliy V.
IPC分类号： G03G5/06 , C07D333/48 , C07D207/34 , C07C251/84 , C07D257/06 , C07D249/18 , C07C317/34 , C07D231/38
CPC分类号： G03G5/0612 , G03G5/0616

4. 发明公开

EP1283448A2 Electrophotographic organophotoreceptors with charge transport compounds 有权
标题翻译：具有电荷转移剂的电子照相有机感光体
公开(公告)号：EP1283448A2
公开(公告)日：2003-02-12
申请号：EP02255547.8
申请日：2002-08-08
申请人： Samsung Electronics Co., Ltd.
发明人： Law, Kam W. , Jubran, Nusrallah , Tokarski, Zbigniew , Katritzky, Alan R. , Jain, Ritu , Maimait, Rexiat
IPC分类号： G03G5/06
CPC分类号： C07D403/12 , C07D209/86 , C07D409/12 , G03G5/06 , G03G5/0614 , G03G5/0616 , G03G5/062 , G03G5/0627 , G03G5/0629 , G03G5/0631 , G03G5/0633 , G03G5/0642
摘要： A novel charge transport compound, a novel process using that novel compound and an organophotoreceptor includes (a) a novel charge transport compound having the formula
where R 1 and R 2 are selected so that R 1 and R 2 form, with the included nitrogen atom, a group selected from the group consisting of heterocyclic rings, aromatic rings, and dinaphthylamine; or R 1 comprises an C5-C40 aryl group and R 2 comprises a group selected from the group consisting of sulfolanyl, 4-(9H-fluoren-9-ylidene)benzyl, pyrrolyl, pyrazolyl, benzotriazolyl, stilbenyl, tetrazolyl; or R 1 comprises hydrogen, C1-C30 alkyl group, C5-C40 aryl group and R 2 comprises sulfonylphenyl, R 3 is hydrogen, C1-C30 alkyl group, C5-C40 aryl group, heterocyclic group or a hydrocarbon group; and Q is a 3-carbazole group; (b) a charge generating compound; and (c) an electrically conductive substrate.

5. 发明授权

EP1283448B1 Electrophotographic organophotoreceptors with charge transport compounds 有权
标题翻译：具有电荷转移剂的电子照相有机感光体
公开(公告)号：EP1283448B1
公开(公告)日：2008-11-05
申请号：EP02255547.8
申请日：2002-08-08
申请人： SAMSUNG ELECTRONICS CO., LTD.
发明人： Law, Kam W. , Jubran, Nusrallah , Tokarski, Zbigniew , Katritzky, Alan R. , Jain, Ritu , Maimait, Rexiat
IPC分类号： G03G5/06 , C07D209/86 , C07D409/12 , C07D403/12
CPC分类号： C07D403/12 , C07D209/86 , C07D409/12 , G03G5/06 , G03G5/0614 , G03G5/0616 , G03G5/062 , G03G5/0627 , G03G5/0629 , G03G5/0631 , G03G5/0633 , G03G5/0642

6. 发明公开

EP1293837A3 Electrophotographic organophotoreceptors 有权
标题翻译：一种电子照相有机感光体
公开(公告)号：EP1293837A3
公开(公告)日：2004-03-03
申请号：EP02256280.5
申请日：2002-09-11
申请人： SAMSUNG ELECTRONICS CO., LTD.
发明人： Law, Kam W. , Jubran, Nusrallah , Tokarski, Zbigniew , Katritzky, Alan R. , Jain, Ritu , Maimait, Rexiat , Vakulenko, Anatoliy V.
IPC分类号： G03G5/06 , C07D333/48 , C07D207/34 , C07C251/84 , C07D257/06 , C07D249/18 , C07C317/34 , C07D231/38
CPC分类号： G03G5/0612 , G03G5/0616
摘要： An organophotoreceptor that includes (a) a charge transport material having the formula wherein A is selected from heterocyclic groups, naphthyl group, (9H-fluoren-9-ylidene)benzyl group, alkylsulfonylphenyl, or stilbenyl, B is selected from hydrogen, alkyl group, and an aryl group, with the proviso that when A is naphthyl, B is naphthyl; and wherein R 1 is selected from the group consisting of N-pyrrolyl, N-pyrazolyl, N-tetrazolyl, N-indolyl, N-carbazolyl, N-triazolyl, N-imidazolyl, N-benzimidazolyl, N-indazolyl, and N-benzotriazolyl group, and R 3 is a 9-fluorenone group, (b) a charge generating compound, and (c) an electrically conductive substrate. Therefore, an organophotoreceptor having good mechanical and electrostatic properties can be obtained by using a charge transport material including 9H-fluoren-9-one hydrazino substituted compounds and derivatives thereof. Also, an electrophotographic imaging apparatus for obtaining high quality image even after repeated cycles can be attained by employing the organophotoreceptor.

7. 发明公开

EP1335250A1 Electrophotographic organophotoreceptors with novel charge transport materials 审中-公开
标题翻译： Elektrophotographische organische Photoleiter，neue Ladungstransportmaterialien enthaltend
公开(公告)号：EP1335250A1
公开(公告)日：2003-08-13
申请号：EP03250767.5
申请日：2003-02-06
申请人： SAMSUNG ELECTRONICS CO., LTD.
发明人： Law, Kam W. , Jubran, Nusrallah , Tokarski, Zbigniew , Katritzky, Alan R. , Jain, Ritu , Maimait, Rexiat
IPC分类号： G03G5/06 , C07D333/48 , C07C251/84 , C07C317/34 , C07D249/18 , C07D231/38 , C07D257/06 , C07D207/34
CPC分类号： C07D231/38 , C07C251/84 , C07C317/34 , C07C2603/18 , C07D207/34 , C07D249/18 , C07D257/06 , C07D333/48 , G03G5/0616 , G03G5/0618 , G03G5/062 , G03G5/0661
摘要： This invention relates to a novel organophotoreceptor comprising:

(a) at least one charge transport material comprising a fluorenone hydrazone having a combination of groups thereon, the combination of groups being selected from the group consisting of a) at least two fluorenone alkylsulfonylphenylhydrazone groups, b) at least two fluorenone pyrrolylhydrazone groups, c) at least two fluorenone benzotriazolylhydrazone groups, d) at least two fluorenone sulfolanylhydrazone groups, e) at least two fluorenone pyrazolylhydrazone groups, f) at least two fluorenone naphthylhydrazone groups, g) at least two fluorenone tetrazolylhydrazone groups, h) at least two fluorenone stilbenylhydrazone groups, and i) at least two fluorenone (9H-fluoren-9-ylidene)benzylhydrazone groups. Some of these fluorenones may be represented by the formula
where n is an integer between 2 and 6, inclusive; R 1 is hydrogen, an alkyl group, or an aryl group (e.g., phenyl, naphthyl, stilbenyl, benzyl, or tolanyl group); R 2 is an alkylsulfonylphenyl or one of its derivatives; X is a linking group having the formula -(CH 2 ) m -, branched or linear. The compounds may form electrostatic imaging systems in combination with
(b) a charge generating compound; and
(c) an electrically conductive substrate.
摘要翻译：本发明涉及一种新的有机光感受器，其包含：（a）至少一种电荷传输材料，其包含其上具有基团的组合的芴酮腙，所述组合选自a）至少两个芴酮烷基磺酰基苯基腙基团，b ）至少两个芴酮吡咯基腙基团，c）至少两个芴酮苯并三唑基腙基团，d）至少两个芴酮砜基腙基团，e）至少两个芴酮吡唑基腙基团，f）至少两个芴酮萘基腙基团，g）至少两个芴酮四唑基腙基，h）至少两个芴酮二苯乙烯基腙基，和i）至少两个芴酮（9H-芴-9-亚基）苄腙基团。这些芴酮中的一些可以由式CHEM表示，其中n是2和6之间的整数，包括0和6; R1是氢，烷基或芳基（例如苯基，萘基，茋基，苄基或甲苯酰基）; R2是烷基磺酰基苯基或其衍生物之一; X是具有式 - （CH 2）m - ，支链或直链的连接基团。所述化合物可以与（b）产生电荷的化合物组合形成静电成像系统; 和（c）导电基板。

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