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1. 发明公开

EP0578384A1 Process for the oxidation of methane to methanol using chromia on metal oxide catalysts 失效
标题翻译：一种用于甲烷的氧化工艺，以甲醇对含有金属氧化物的催化剂使用三氧化二铬。
公开(公告)号：EP0578384A1
公开(公告)日：1994-01-12
申请号：EP93304560.1
申请日：1993-06-11
申请人： SUN COMPANY, INC. (R&M)
发明人： Lyons, James E. , Durante, Vincent A. , Walker, Darrell W.
IPC分类号： C07C29/50 , C07C31/04
CPC分类号： C07C29/50 , Y02P20/52 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： A process for the direct catalytic oxidation of methane to methanol comprises chromium chemically bound to the oxygen of a metal oxide catalytic support surface. The support may comprise silica, alumina, magnesia, titania, or zirconia.
摘要翻译：一种用于甲烷的直接催化氧化工艺，以甲醇包括铬化学地结合到金属氧化物催化剂载体表面的氧。支撑件可以包括二氧化硅，氧化铝，氧化镁，二氧化钛，或氧化锆。

2. 发明公开

EP0503190A1 Dimerization of propane or butanes with barium peroxide 失效转让
标题翻译：枸橼酸二甲酯。
公开(公告)号：EP0503190A1
公开(公告)日：1992-09-16
申请号：EP91307484.5
申请日：1991-08-13
申请人： SUN COMPANY, INC. (R&M)
发明人： Durante, Vincent A. , Lyons, James E.
IPC分类号： C07C2/82 , C07C9/16
CPC分类号： C07C2/82 , C07C9/00
摘要： The invention relates to a process for preparing branched-chain paraffins which comprises contacting a C₃ or C₄ hydrocarbon with a barium peroxide oxidizer in a reaction zone at a temperature of 200-450°C, sufficient to oxidatively dimerize said hydrocarbon, recovering a branched-chain dimer of said hydrocarbon and barium oxide from the reaction zone, and regenerating said oxidizer by oxidizing said barium oxide to barium peroxide.
摘要翻译：本发明涉及一种制备支链烷烃的方法，该方法包括使C3或C4烃与过氧化钡氧化剂在反应区中在200-450℃的温度下接触，足以将所述烃氧化二聚，所述烃和氧化钡的双链二聚体，并且通过将所述氧化钡氧化成过氧化钡来再生所述氧化剂。

3. 发明授权

EP0578383B1 Dimerization and/or dehydrogenation of alkanes 失效
标题翻译：二聚化和/或链烷烃的脱氢
公开(公告)号：EP0578383B1
公开(公告)日：1997-02-05
申请号：EP93304559.3
申请日：1993-06-11
申请人： SUN COMPANY, INC. (R&M)
发明人： Durante, Vincent A. , Lyons, James E.
IPC分类号： C07C2/82 , C07C5/48 , C07C9/16
CPC分类号： C07C5/42 , C07C2/82 , C07C9/00

4. 发明授权

EP0527634B1 Hydrocarbon reforming process using a zirconium oxide supported catalyst doped with tantalum 失效
标题翻译：掺杂有钽催化基于氧化锆的重整用催化剂的烃的方法，
公开(公告)号：EP0527634B1
公开(公告)日：1997-01-02
申请号：EP92307321.7
申请日：1992-08-11
申请人： SUN COMPANY, INC. (R&M)
发明人： Durante, Vincent A. , Macris, Aristides , Pitchai, Rangasamy , Verykios, Xenophon E.
IPC分类号： C10G35/09 , B01J23/20 , B01J23/64 , B01J23/84 , B01J32/00
CPC分类号： B01J32/00 , B01J23/20 , B01J23/6486 , B01J23/8476 , C10G35/09

5. 发明授权

EP0564254B1 Polycyclic aromatic ring cleavage (parc) process 失效
标题翻译：多环芳环裂解方法
公开(公告)号：EP0564254B1
公开(公告)日：1996-09-11
申请号：EP93302495.2
申请日：1993-03-30
申请人： SUN COMPANY, INC. (R&M)
发明人： Durante, Vincent A.
IPC分类号： C10G27/10 , C07C4/00
CPC分类号： C10G67/12 , C07C46/04 , C07C49/675 , C07C49/747 , C07C50/16 , C07C50/18 , C07C51/313 , C07D303/06 , Y10S210/909 , C07C63/331

6. 发明公开

EP0644174A1 A new manganese catalyst for light alkane oxidation 失效
标题翻译：爱因斯坦神经生物学家zur氧化leichter阿尔坎恩。
公开(公告)号：EP0644174A1
公开(公告)日：1995-03-22
申请号：EP94306267.9
申请日：1994-08-25
申请人： SUN COMPANY, INC. (R&M)
发明人： Durante, Vincent A. , Lyons, James E. , Walker, Darrell W. , Marcus, Bonita K.
IPC分类号： C07C29/50 , C07C31/04
CPC分类号： C07C29/50 , B01J29/84 , C07C27/14 , Y02P20/52 , C07C31/08 , C07C31/04
摘要： Aluminophosphates containing manganese in the structural framework are employed for the oxidation of alkanes, for example the vapor phase oxidation of methane to methanol.
摘要翻译：直接氧化的轻质烷烃通过在氧化剂存在下与包含Mn和结晶铝磷酸盐结构骨架的催化剂接触而进行，其中加入了至少一部分Mn。阿姆特的催化剂中的Mn为3-13重量％。轻质烷烃选自甲烷（pref。），乙烷，丙烷，天然气和混合物。这些。氧化物在200-450（30-400）℃和400-1200（800）psig下进行。

7. 发明公开

EP0568303A3 Process and catalyst for dehydrogenation of organic compounds 失效
标题翻译：用于脱氢有机化合物的方法和催化剂
公开(公告)号：EP0568303A3
公开(公告)日：1994-07-13
申请号：EP93303257.5
申请日：1993-04-27
申请人： SUN COMPANY, INC. (R&M)
发明人： Durante, Vincent A. , Resasco, Daniel E. , Walker, Darrell W. , Haller, Gary L. , Coggins, Eugene L.
IPC分类号： C07B35/04 , B01J23/76 , B01J23/89 , C07C5/32 , C07C5/48 , C07C11/08
CPC分类号： C07B35/04 , B01J8/0453 , B01J23/755 , B01J27/1813 , B01J27/1815 , B01J2208/00274 , C07C5/3335 , Y02P20/128 , C07C11/08
摘要： Alkanes are dehydrogenated in one embodiment by passage through alternating dehydrogenation zones and selective oxidation zone(s) , in which latter zone(s) hydrogen produced in the preceding endothermic dehydrogenation reaction is selectively oxidized to generate heat for the succeeding dehydrogenation reaction. In one embodiment, dehydrogenation is carried out without limitation to particular flow sequence, using a catalyst comprising an alloy or combination of nickel with copper, tin, lead or indium on non-acidic supports. In another embodiment, new catalyst compositions, active for dehydrogenation of alkanes, are prepared comprising reduced and sulfided nickel crystallites on siliceous supports which have been treated with chromium compounds and oxidized to provide surface-anchored chromyl species. In another embodiment, new catalyst compositions, active for dehydrogenation of alkanes, are prepared comprising nickel supported on a non-acidic form of zeolite L. In another embodiment, new catalyst compositions are prepared by sulfiding nickel-containing compositions with carbonaceous sulfur compounds such as dialkylsulfoxides. Another embodiment of the invention is catalyst and dehydrogenation therewith, in which pores having radius of 50 to 200 Angstroms occupy pore volume from 0.30 to 1.50 ml per gram of the support, and pores having radius of 20 to 50 Angstroms occupy pore volume less than 0.1 ml per gram of the support. In another embodiment, alkanes are dehydrogenated using as catalyst a metal or metal compound having dehydrogenating activity supported on alkali-treated alumina. In other embodiments, reaction of dehydrogenating metal, nickel for example, with a Group III oxide or hydroxide, alumina for example, support during catalyst preparation by forming a layer of a Group IV metal oxide or hydroxide, zirconia or titania for example, on the support prior to applying the dehydrogenating metal to the support, or by reacting another metal, for example copper, prior to applying the dehydrogenating metal, for example nickel, to the support. Another embodiment of the invention is catalyst preparation wherein a dehydrogenating metal, for example nickel, is selectively deposited in the larger pores of a catalyst support by previously contacting the support with a liquid organic compound, a glycol for example, whereby said compound selectively enters or remains in the smaller pores of the support, and the catalyst thereby obtained. In another embodiment, catalyst is prepared by impregnating a porous support, alumina for example, with a dehydrogenating metal, for example nickel, calcining the support at a first temperature sufficiently high to react metal with the support, reimpregnating the support with the same, or a different, metal and calcining the support at a second temperature, 200°C. for example, lower than the temperature of the first calcining, 500°C. for example. In another embodiment, dehydrogenation catalyst is prepared by forming a carbonaceous layer on a noncarbonaceous porous support, alumina for example, the carbonaceous layer being formed by precoking of the support, prior to depositing a dehydrogenating metal, nickel for example, on the support; the resulting catalyst containing carbon filaments between dehydrogenating metal particles and the support.

8. 发明公开

EP0578474A1 Sulfur tolerant bimetallic zeolitic reforming catalysts 失效
标题翻译： GegenüberSchwefel宽容双金属仪器Zeolith-Katalysator zur Reformierung。
公开(公告)号：EP0578474A1
公开(公告)日：1994-01-12
申请号：EP93305286.2
申请日：1993-07-06
申请人： SUN COMPANY, INC. (R&M) , YALE UNIVERSITY
发明人： Larsen, Gustavo , Haller, Gary L. , Resasco, Daniel E. , Durante, Vincent A.
IPC分类号： B01J29/34 , C01B33/34 , C10G45/64 , C10G45/70
CPC分类号： C10G35/095 , B01J29/62 , B01J29/63
摘要： New compositions of matter comprise a metal from the group consisting of platinum, rhodium and palladium, a metal from the first row of Group VIII of the Periodic Table and a nonacidic L-zeolite. A preferred composition is Pt-Ni/KL-zeolite. Such catalysts are prepared by coimpregnation of the zeolite with the metals. Methods of using the catalysts in reforming, aromatization or dehydrogenation are provided.
摘要翻译：物质的新组合物包括来自铂，铑和钯的金属，来自元素周期表第Ⅷ族的第一排的金属和非酸的L-沸石。优选的组成是Pt-Ni / KL-沸石。这样的催化剂通过将沸石与金属共浸渍来制备。提供了在重整，芳构化或脱氢中使用催化剂的方法。

9. 发明公开

EP0578383A1 Dimerization and/or dehydrogenation of alkanes 失效
标题翻译： Dimerisierung und / oder Dehydrierung von Alkanen。
公开(公告)号：EP0578383A1
公开(公告)日：1994-01-12
申请号：EP93304559.3
申请日：1993-06-11
申请人： SUN COMPANY, INC. (R&M)
发明人： Durante, Vincent A. , Lyons, James E.
IPC分类号： C07C2/82 , C07C5/48 , C07C9/16
CPC分类号： C07C5/42 , C07C2/82 , C07C9/00
摘要： Barium peroxide oxidizer, together with a transition metal from Group I, III, IV, V, VII or VIII or compound thereof is used as stoichiometric reagent in the oxidative dimerization of hydrocarbons having three or four carbon atoms. Barium peroxide oxidizer, together with a transition metal from Group I, III, IV, V, VI, VII or VIII or compound thereof is used as stoichiometric reagent in the dehydrogenation of hydrocarbons having three or four carbon atoms.
摘要翻译：二氧化碳氧化剂与来自组I，III，IV，V，VII或VIII的过渡金属或其化合物一起用作具有三或四个碳原子的烃的氧化二聚化学计量试剂。过氧化二氧化钡与来自组I，III，IV，V，VI，VII或VIII的过渡金属或其化合物一起用作具有三个或四个碳原子的烃的脱氢中的化学计量试剂。

10. 发明授权

EP0644174B1 A new manganese catalyst for light alkane oxidation 失效
标题翻译：对于轻质烷烃氧化的新锰催化剂
公开(公告)号：EP0644174B1
公开(公告)日：1997-10-15
申请号：EP94306267.9
申请日：1994-08-25
申请人： SUN COMPANY, INC. (R&M)
发明人： Durante, Vincent A. , Lyons, James E. , Walker, Darrell W. , Marcus, Bonita K.
IPC分类号： C07C29/50 , C07C31/04
CPC分类号： C07C29/50 , B01J29/84 , C07C27/14 , Y02P20/52 , C07C31/08 , C07C31/04

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