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1. 发明公开

EP0552912A3 Method for producing 2,6-dihydroxybenzoic acid 失效
标题翻译： 2,6-二羟基苯甲酸的制备方法
公开(公告)号：EP0552912A3
公开(公告)日：1995-02-01
申请号：EP93300316.2
申请日：1993-01-19
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , SUMIKA FINE CHEMICALS Co., Ltd.
发明人： Nakamatsu, Toshio , Nishida, Yasuhiro , Kometani, Norio
IPC分类号： C07C65/03 , C07C51/43 , C07C51/487 , C07C65/05
CPC分类号： C07C51/487 , C07C65/05
摘要： A method for producing 2,6-dihydroxybenzoic acid from an aqueous solution which contains a mixture of 2,6-dihydroxybenzoic acid and 2,4-dihydroxybenzoic acid, preferably of concentration 5 to 30 wt%, e.g. obtained by carboxylation of resorcin in water and/or an organic solvent, by adjusting the pH value to 4 or more, preferably 4 to 9, and heating the mixture to selectively decompose 2,4-dihydroxybenzoic acid, and separating 2,6-dihydroxybenzoic acid from the decomposition reaction mixture, e.g. by acid-precipitation and filtration. The product is obtained in high purity, e.g. at least 98 wt%, and is useful as a starting material in industrial synthesis.
摘要翻译：从含有2,6-二羟基苯甲酸和2,4-二羟基苯甲酸的混合物的水溶液中制备2,6-二羟基苯甲酸的方法，优选浓度为5〜30重量％。通过将pH值调节至4以上，优选为4〜9，通过在水和/或有机溶剂中羧化的间苯二酚获得，并加热该混合物以选择性分解2,4-二羟基苯甲酸，分离2,6-二羟基苯甲酸酸从分解反应混合物，例如通过酸沉淀和过滤。产物以高纯度获得，例如。至少98重量％，可用作工业合成中的原料。

2. 发明授权

EP0552019B1 Method of producing 1,4-dihydroxy-2-naphthoic acid 失效
标题翻译：一种用于1,4-二羟基-2-萘甲酸的制备方法
公开(公告)号：EP0552019B1
公开(公告)日：1996-06-12
申请号：EP93300190.1
申请日：1993-01-13
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , SUMIKA FINE CHEMICALS Co., Ltd.
发明人： Nakamatsu, Toshio , Nishida, Yasuhiro , Watanabe, Shinichi , Kometani, Norio
IPC分类号： C07C65/11 , C07C51/15
CPC分类号： C07C51/15 , C07C65/11

3. 发明公开

EP0552019A3 Method of producing 1,4-dihydroxy-2-naphthoic acid 失效
标题翻译：生产1,4-二羟基-2-萘甲酸的方法
公开(公告)号：EP0552019A3
公开(公告)日：1993-11-18
申请号：EP93300190.1
申请日：1993-01-13
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , SUMIKA FINE CHEMICALS Co., Ltd.
发明人： Nakamatsu, Toshio , Nishida, Yasuhiro , Watanabe, Shinichi , Kometani, Norio
IPC分类号： C07C65/11 , C07C51/15
CPC分类号： C07C51/15 , C07C65/11
摘要： A method of producing 1,4-dihydroxy-2-naphthoic acid comprises: subjecting 1,4-dihydroxynaphthalene to alkali metal salt formation reaction at a temperature of 110°C or more in an organic medium capable of dissolving 1,4-dihydroxynaphthalene, preferably selected from ketones, esters, monoalcohols, polyhydric alcohols and derivatives thereof and aromatic hydrocarbons using an alkali metal alcoholate, preferably of a Cl-4 alcohol; and subjecting the salt formation reaction mixture to carboxylation using carbon dioxide gas under atmospheric or increased pressure and preferably with an excess of CO₂ of 1.5 mols or more per mol of the dihydroxynaphthalene. The product is obtained easily and in a high yield, e.g of 80 to 92% and in high purity, and is useful as an intermediate for dyes, pigments and photographic agents.

4. 发明公开

EP0552912A2 Method for producing 2,6-dihydroxybenzoic acid 失效
标题翻译： Verfahren zur Herstellung von 2,6-Dihydroxybenzosäure。
公开(公告)号：EP0552912A2
公开(公告)日：1993-07-28
申请号：EP93300316.2
申请日：1993-01-19
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , SUMIKA FINE CHEMICALS Co., Ltd.
发明人： Nakamatsu, Toshio , Nishida, Yasuhiro , Kometani, Norio
IPC分类号： C07C65/03 , C07C51/43 , C07C51/487 , C07C65/05
CPC分类号： C07C51/487 , C07C65/05
摘要： A method for producing 2,6-dihydroxybenzoic acid from an aqueous solution which contains a mixture of 2,6-dihydroxybenzoic acid and 2,4-dihydroxybenzoic acid, preferably of concentration 5 to 30 wt%, e.g. obtained by carboxylation of resorcin in water and/or an organic solvent, by adjusting the pH value to 4 or more, preferably 4 to 9, and heating the mixture to selectively decompose 2,4-dihydroxybenzoic acid, and separating 2,6-dihydroxybenzoic acid from the decomposition reaction mixture, e.g. by acid-precipitation and filtration.
The product is obtained in high purity, e.g. at least 98 wt%, and is useful as a starting material in industrial synthesis.
摘要翻译：从含有2,6-二羟基苯甲酸和2,4-二羟基苯甲酸的混合物的水溶液中制备2,6-二羟基苯甲酸的方法，优选浓度为5〜30重量％。通过将pH值调节至4以上，优选为4〜9，通过在水和/或有机溶剂中羧化的间苯二酚获得，并加热该混合物以选择性分解2,4-二羟基苯甲酸，分离2,6-二羟基苯甲酸酸从分解反应混合物，例如通过酸沉淀和过滤。产物以高纯度获得，例如。至少98重量％，可用作工业合成中的原料。

5. 发明公开

EP0552019A2 Method of producing 1,4-dihydroxy-2-naphthoic acid 失效
标题翻译： Verfahren zur Herstellung von 1,4-Dihydroxy-2-Naphthalin-Carbonsaure。
公开(公告)号：EP0552019A2
公开(公告)日：1993-07-21
申请号：EP93300190.1
申请日：1993-01-13
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , SUMIKA FINE CHEMICALS Co., Ltd.
发明人： Nakamatsu, Toshio , Nishida, Yasuhiro , Watanabe, Shinichi , Kometani, Norio
IPC分类号： C07C65/11 , C07C51/15
CPC分类号： C07C51/15 , C07C65/11
摘要： A method of producing 1,4-dihydroxy-2-naphthoic acid comprises: subjecting 1,4-dihydroxynaphthalene to alkali metal salt formation reaction at a temperature of 110°C or more in an organic medium capable of dissolving 1,4-dihydroxynaphthalene, preferably selected from ketones, esters, monoalcohols, polyhydric alcohols and derivatives thereof and aromatic hydrocarbons using an alkali metal alcoholate, preferably of a Cl-4 alcohol; and subjecting the salt formation reaction mixture to carboxylation using carbon dioxide gas under atmospheric or increased pressure and preferably with an excess of CO₂ of 1.5 mols or more per mol of the dihydroxynaphthalene.
The product is obtained easily and in a high yield, e.g of 80 to 92% and in high purity, and is useful as an intermediate for dyes, pigments and photographic agents.
摘要翻译： 1,4-二羟基-2-萘甲酸的制造方法包括：在能够溶解1,4-二羟基萘的有机介质中，使1,4-二羟基萘在110℃以上的温度下进行碱金属盐形成反应，优选选自酮，酯，一元醇，多元醇及其衍生物和使用碱金属醇盐，优选Cl-4醇的芳烃; 并且在大气压或增压下使用二氧化碳气体使盐形成反应混合物进行羧化，优选每摩尔二羟基萘过量的CO 2为1.5摩尔或更多。该产品容易且以高产率例如80-92％和高纯度获得，并且可用作染料，颜料和照相剂的中间体。

6. 发明公开

EP0529517A3 Process for producing 2-methyl-1,3-cyclohexanedione and 2-methylresorcinol 失效
标题翻译： 2-甲基-1,3-环己基和2-甲基吡咯烷酮的制备方法
公开(公告)号：EP0529517A3
公开(公告)日：1993-05-12
申请号：EP92114239.4
申请日：1992-08-20
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , SUMIKA FINE CHEMICALS Co., Ltd.
发明人： Nakamatsu, Toshio , Nishida, Yasuhiro , Kometani, Norio
IPC分类号： C07C49/403 , C07C45/67 , C07C225/12 , C07C37/07
CPC分类号： C07C211/00 , C07C37/07 , C07C45/673 , C07C2601/14 , C07C49/403 , C07C39/08
摘要： A process for producing 2-methyl-1,3-cyclohexanedione which comprises subjecting 1,3-cyclohexanedione, formaldehyde and a dialkylamine to Mannich reaction to obtain a 2-dialkylaminomethyl-1,3-cyclohexanedione, and subjecting the 2-dialkylaminomethyl to hydrogenolysis, and a process for producing 2-methylresorcinol which comprises aromatizing 2-methyl-1,3-cyclohexanedione obtained. According to these processes, it is possible to produce high-purity 2-methylresorcinol and 2-methyl-1,3-cyclohexanedione commercially easily and advantageously.
摘要翻译：一种2-甲基-1,3-环己二酮的制备方法，其包括使1,3-环己二酮，甲醛和二烷基胺进行曼尼希反应，得到2-二烷基氨基甲基-1,3-环己二酮，并使2-二烷基氨基甲基进行氢解，以及制备2-甲基间苯二酚的方法，其包括使得到的2-甲基-1,3-环己二酮芳构化。根据这些方法，可以容易且有利地生产高纯度2-甲基间苯二酚和2-甲基-1,3-环己二酮。

7. 发明公开

EP0529517A2 Process for producing 2-methyl-1,3-cyclohexanedione and 2-methylresorcinol 失效
标题翻译：一种用于2-甲基-1,3-环己二酮，和2-甲基间苯二酚的制备方法。
公开(公告)号：EP0529517A2
公开(公告)日：1993-03-03
申请号：EP92114239.4
申请日：1992-08-20
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , SUMIKA FINE CHEMICALS Co., Ltd.
发明人： Nakamatsu, Toshio , Nishida, Yasuhiro , Kometani, Norio
IPC分类号： C07C49/403 , C07C45/67 , C07C225/12 , C07C37/07
CPC分类号： C07C211/00 , C07C37/07 , C07C45/673 , C07C2601/14 , C07C49/403 , C07C39/08
摘要： A process for producing 2-methyl-1,3-cyclohexanedione which comprises subjecting 1,3-cyclohexanedione, formaldehyde and a dialkylamine to Mannich reaction to obtain a 2-dialkylaminomethyl-1,3-cyclohexanedione, and subjecting the 2-dialkylaminomethyl to hydrogenolysis, and a process for producing 2-methylresorcinol which comprises aromatizing 2-methyl-1,3-cyclohexanedione obtained. According to these processes, it is possible to produce high-purity 2-methylresorcinol and 2-methyl-1,3-cyclohexanedione commercially easily and advantageously.

8. 发明授权

EP0529517B1 Process for producing 2-methyl-1,3-cyclohexanedione and 2-methylresorcinol 失效
标题翻译： Verfahren zur Herstellung von 2-甲基-1,3-环己基和2-甲基间苯二酚。
公开(公告)号：EP0529517B1
公开(公告)日：1995-11-22
申请号：EP92114239.4
申请日：1992-08-20
申请人： SUMITOMO CHEMICAL COMPANY LIMITED , SUMIKA FINE CHEMICALS Co., Ltd.
发明人： Nakamatsu, Toshio , Nishida, Yasuhiro , Kometani, Norio
IPC分类号： C07C49/403 , C07C45/67 , C07C225/12 , C07C37/07
CPC分类号： C07C211/00 , C07C37/07 , C07C45/673 , C07C2601/14 , C07C49/403 , C07C39/08

9. 发明公开

EP0270306A2 Anthrapyridone compounds, their production process and their use 失效
标题翻译： Anthrapyridon-Verbindungen，ihre Herstellung und ihre Verwendung。
公开(公告)号：EP0270306A2
公开(公告)日：1988-06-08
申请号：EP87310447.5
申请日：1987-11-26
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , DAIEI CHEMICAL COMPANY, LIMITED
发明人： Nakamatsu, Toshio , Egashira, Yoshitugu , Suzuki, Yasuyuki
IPC分类号： C09B5/14 , C08J3/20
CPC分类号： C08K5/3437 , C09B5/14
摘要： An anthrapyridone compound of the following formula (I) and which is useful for coloring resins:
wherein X¹ is hydrogen, -NHCOR¹, -CONR²R³, -COR⁴, -SO₂R⁵ or -SO₂NR⁶R⁷, in which R¹ and R⁴ are each C 1-4 alkyl, R² and R³ are each hydrogen or C 1-4 alkyl, R⁵ is C 1-4 alkyl or hydroxyethyl, R⁶ and R⁷ are each hydrogen or C 1-4 alkyl,
X² is hydrogen or imidomethyl of the formula (II):
wherein n is a number of 1 to 2, X⁴ is hydrogen or carboxylic acid C 1-4 alkyl-ester,
X³ is hydrogen, halogen, hydroxyl, C 1-4 alkyl or C 1-4 alkoxyl,
with the proviso that X¹ is -NHCOR¹, -CONR²R³, -COR⁴, -SO₂R⁵ or -SO₂NR⁶R⁷ when X² is hydrogen,
X² is the imidomethyl of the formula (II) when X¹ the hydrogen, is provided, which is prepared by allowing an α-haloanthraquinone compound with an acylated primary aromatic amine compound in a nonaqueous medium in the presence of metallic copper or a copper compound.
摘要翻译：下式（I）的蒽并吡啶酮化合物，其可用于着色树脂：其中X 1为氢，-NHCOR 1，-CONR 2 R 3，-COR 4，，-SO 2 R 5或-SO 2 NR 6 R 7，其中R 1和R 4各自为C 1-4烷基，R 2和R 3各自为氢或C1- 4烷基，R 5为C 1-4烷基或羟乙基，R 6和R 7各自为氢或C 1-4烷基，X 2为氢或式（II）的亚氨基甲基：其中n为1至2的数，X 4为氢或羧酸C 1-4烷基酯，X 3为氢，卤素，羟基，C 1-4烷基或C 1-4烷氧基，其中条件是X 1为-NHCOR 1，-CONR 2 R 3，-COR 4，-SO 2 R 5或-SO 2 NR 6 R 7时，X 2为氢，X 2是当X 1为氢时提供式（II）的亚氨基甲基，其通过在非水介质中使酰化伯芳族胺化合物与α-卤代蒽醌化合物在非水介质中的存在的金属铜或铜化合物。

10. 发明公开

EP0198198A2 Reactive dye composition 失效
标题翻译：活性染料组合物。
公开(公告)号：EP0198198A2
公开(公告)日：1986-10-22
申请号：EP86102947.8
申请日：1986-03-06
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Nakamatsu, Toshio , Miyamoto, Tetsuya , Imada, Kunihiko
IPC分类号： C09B67/22 , C09B62/10 , C09B62/517 , D06P1/38
CPC分类号： C09B67/0035 , C09B62/10 , C09B67/0072 , Y10S8/918
摘要： A reactive blue dye composition, which comprises a phthalocyanine dye represented by a free acid of the following formula (I),
wherein CuPc is a copper phthalocyanine nucleus, W is a C 2 -C 4 alkylene group or a 1,3- or 1,4-phenylene group having one or two sulfo groups, R 1 and R 2 are independently a hydrogen atom or a lower alkyl group, 1 is a number of 1 to 3, m is a number of 0 to 2, and n is a number of 1 to 3, provided that the total number of 1, m and n is 4 or less, and a phthalocyanine dye represented by a free acid of the following formula (II),
wherein CuPc, 1, m and n are as defined above, Y 1 and Y 2 are independently a hydrogen atom or a methyl, methoxy or sulfo group, R 3 is a hydrogen atom or a lower alkyl group, and Q is -S0 2 CH=CH 2 or -S0 2 CH 2 CH 2 Z in which Z is a splittable group by the action of an alkali, the mixing weight ratio of the dyes (I) to (II) in terms of a copper content being from 80 through 20 to from 20 through 80, which is useful for dyeing or printing fiber materials also in a blend with other color dyes such as yellow and red dyes to give dyed or printed products of a brilliant color excellent in fastness properties with high reproducibility.

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