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    • 6. 发明公开
    • PROCESS FOR CONVERTING LEVULINIC ACID INTO PENTANOIC ACID
    • 用于将戊二酸转化为戊酸的方法
    • EP2155647A1
    • 2010-02-24
    • EP08759894.2
    • 2008-05-21
    • Shell Internationale Research Maatschappij B.V.
    • AYOUB, Paul MarieLANGE, Jean-Paul
    • C07C51/36C07C53/126
    • C07C51/36C07C53/126
    • A process for converting levulinic acid into pentanoic acid, the process comprising the following steps: (a) contacting a feedstock comprising levulinic acid under hydrogenating conditions, in the presence of hydrogen, with a non-acidic heterogeneous hydrogenation catalyst comprising a hydrogenation metal supported on a solid catalyst carrier to obtain a first effluent comprising gamma valerolactone; (b) contacting at least part of the first effluent under hydrogenating conditions, in the presence of hydrogen, with a strongly acidic catalyst and a hydrogenation metal to obtain a second effluent comprising pentanoic acid, wherein step (b) is operated at a conversion per pass of at most 70 wt% to obtain the second effluent comprising pentanoic acid and unconverted gamma valerolactone, and wherein part of the unconverted gamma valerolactone is recycled to step (a) and/or step (b).
    • 一种将乙酰丙酸转化为戊酸的方法,该方法包括以下步骤:(a)使包含乙酰丙酸的原料在氢气存在下在氢存在下与非酸性非均相加氢催化剂接触,所述非均相加氢催化剂包含负载在 固体催化剂载体以获得包含γ-戊内酯的第一流出物; (b)在氢气存在下,在氢气存在下,使至少部分第一流出物与强酸性催化剂和氢化金属接触以获得包含戊酸的第二流出物,其中步骤(b)以转化率 以获得包含戊酸和未转化的γ-戊内酯的第二流出物,并且其中部分未转化的γ-戊内酯被循环至步骤(a)和/或步骤(b)。